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    • 26. 发明授权
    • Silver halides of altered crystal habit or morphology and methods for
producing same
    • 改变晶体习惯或形态的银卤化物及其制造方法
    • US5853691A
    • 1998-12-29
    • US695784
    • 1996-08-12
    • Kenneth M. Doxsee
    • Kenneth M. Doxsee
    • B01D9/02B01D9/00B82B1/00C01F11/18C01G5/02C09K3/00C30B7/00G03C1/015G03C1/035C01B9/00
    • B01D9/00B82Y10/00B82Y30/00C01F11/183C01F11/184C01G5/02C30B29/10C30B7/00G03C1/015G03C1/035
    • Methods are disclosed in which first and second reactant salts and a complexing agent are added to a non-aqueous reaction solvent in which the complexing agent is soluble. The complexing agent is a crown ether or other cyclic or acyclic polydentate chelating agent that, in the reaction solvent, forms chelation complexes with at least one of the reactant salts. The reactant salts, which are substantially soluble and reactive with each other in water to form a first crystallite of silver halide, are present in the reaction solvent in relative amounts that are sufficient to form a desired amount of the silver halide in the reaction solvent. Reaction of the first and second reactant salts in the reaction solvent forms a second crystallite precipitate comprising crystals of silver halide having a different habit or morphology from silver halide crystals in the first crystallite that would otherwise be formable in water by reaction of similar amounts of the first and second reactant salts.
    • 公开了将第一和第二反应物盐和络合剂加入其中络合剂可溶的非水反应溶剂中的方法。 络合剂是冠醚或其它环状或无环多齿螯合剂,其在反应溶剂中与至少一种反应物盐形成螯合配合物。 基本上可溶于水的反应物盐形成卤化银的第一晶体的反应物盐以相当的量存在于反应溶剂中,其量足以在反应溶剂中形成所需量的卤化银。 第一和第二反应物盐在反应溶剂中的反应形成第二微晶沉淀,其包含具有不同习惯或形态的卤化银晶体,所述卤化银具有与第一微晶中卤化银晶体不同的习惯或形态,否则可能在水中形成水,通过相似量的 第一和第二反应物盐。
    • 27. 发明授权
    • Process for reducing the damage susceptibility in optical quality
crystals
    • 降低光学质量晶体的损伤敏感性的方法
    • US5411723A
    • 1995-05-02
    • US123662
    • 1993-09-22
    • Patricia A. Morris
    • Patricia A. Morris
    • C30B29/22C30B33/00C01B25/26C01G28/02C30B31/00
    • C30B33/00C30B29/10C30B29/14
    • A process is disclosed for treating a crystal of MTiOXO.sub.4 which has crystal structure deficiencies of M and O, wherein M is selected from the group consisting of K, Rb, Tl and NH.sub.4 and mixtures thereof and X is selected from the group consisting of P, As and mixtures thereof, which includes the step of heating said crystal in the presence of a mixture of MTiOXO.sub.4 and at least one inorganic compound of one or more monovalent cations selected from the group consisting of Rb+, K+, Cs+ and Ti+ (said inorganic compound(s) being selected to provide a source of vapor phase monovalent cation and being present in an amount sufficient to provide at least a 0.1 mole % excess of the monovalent cation in relation to the M in the MTiOXO.sub.4 in said mixture) at a temperature of from about 400.degree. C. to 950.degree. C. and a pressure of at least 14 psi, and in the presence of a gaseous source of oxygen for a time sufficient to decrease the optical damage susceptibility of said crystal.
    • 公开了一种处理具有M和O的晶体结构缺陷的MTiOXO4晶体的方法,其中M选自K,Rb,Tl和NH4及其混合物,X选自P, As及其混合物,其包括在MTiOXO4和选自Rb +,K +,Cs +和Ti +的一种或多种一价阳离子的至少一种无机化合物存在下加热所述晶体的步骤(所述无机化合物 被选择为提供气相一价阳离子源,并且以足以在所述混合物中的MTiOXO4中相对于M提供至少0.1摩尔%过量的一价阳离子的量存在),温度为 约400℃至950℃,压力至少为14psi,并且在气态氧气源的存在下,足以降低所述晶体的光学损伤敏感性的时间。
    • 29. 发明授权
    • Single cesium titanyl arsenate-type crystals, and their preparation
    • 单一铯钛酸氧钛酸盐型晶体及其制备方法
    • US5334365A
    • 1994-08-02
    • US888945
    • 1992-05-26
    • Lap K. Cheng
    • Lap K. Cheng
    • G02F1/35C30B9/00C30B9/06C30B29/22G02F1/355C01B37/14
    • C30B9/00C30B29/10C30B29/14
    • A flux process is disclosed for producing a single orthorhombic crystal of Cs.sub.1-x M.sub.x TiOAsO.sub.4 (where M is Na, K, Rb, and/or Tl and x is from 0 to 0.4) wherein the dimension of the crystal along each axis is at least about 2 mm, and wherein the product at the dimensions along the three axes is at least about 15 mm.sup.3. The process involves preparing a homogeneous melt containing the components for forming said crystal and a flux comprising oxides of Cs and As at a temperature no higher than the decomposition temperature of said orthorhombic crystal, the mole fraction of M relative to the total Cs+M in the melt being within the range of from 0 to about 0.2; introducing a seed crystal for said single crystal in the melt; activating the controlled crystallization on the seed crystal; and continuing the crystallization until formation of the single crystal is completed. Single crystals of Cs.sub.1-x M.sub.x TiOAsO.sub.4 (including crystals at least about 5 mm.times.5 mm 5 mm) are also disclosed.
    • 公开了用于制造Cs1-xMxTiOAsO4(其中M是Na,K,Rb和/或T1和x为0至0.4)的单斜晶体的焊剂工艺,其中沿着每个轴的晶体的尺寸至少约为 2mm,并且其中沿着三个轴线的尺寸的产品为至少约15mm 3。 该方法包括制备含有用于形成所述晶体的组分的均匀熔体和包含Cs和As的氧化物的焊剂,其温度不高于所述正交晶体的分解温度,M相对于总Cs + M的摩尔分数 熔体在0至约0.2的范围内; 在熔体中引入所述单晶的晶种; 激活晶种上的受控结晶; 并继续结晶,直到完成单晶的形成。 还公开了Cs1-xMxTiOAsO4的单晶(包括至少约5mm×5mm×5mm的晶体)。