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21. 发明授权

US5756575A Ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition 失效
公开(公告)号：US5756575A
公开(公告)日：1998-05-26
申请号：US661989
申请日：1996-06-12
申请人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
发明人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
IPC分类号： C08L23/02 , C08L23/16 , C08L23/26
CPC分类号： C08L23/02 , C08L23/16 , C08L2207/04
摘要： The ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition of the present invention comprises in specified proportions a crystalline polyolefin resin (A) and an ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) composed of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms and a specific branched chain polyene compound. The molar ratio of ethylene units to .alpha.-olefin units, iodine value and intrinsic viscosity �.eta.! of the ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) are within respective specified ranges. This rubber composition is excellent in low temperature properties. When the above olefinic thermoplastic elastomer composition is partially or entirely crosslinked, a molding can be provided which is superior to the conventional vulcanized rubbers in low temperature properties, tensile strength, elongation at break and rubber properties.

22. 发明授权

US5733983A Heat-resistant rubber composition 失效
标题翻译：耐热橡胶组合物
公开(公告)号：US5733983A
公开(公告)日：1998-03-31
申请号：US750821
申请日：1996-12-10
申请人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
发明人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
IPC分类号： C08K5/00 , C08K5/14 , C08L23/08 , C08F8/00
CPC分类号： C08K5/14 , C08K5/0025 , C08L23/0815 , C08L2312/00
摘要： A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an .alpha.-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
摘要翻译： PCT No.PCT / JP96 / 00991 Sec。 371日期1996年12月10日第 102（e）日期1996年12月10日PCT 1996年4月11日PCT PCT。出版物WO96 / 32442 日期1996年10月17日本发明的耐热橡胶组合物是包含特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和有机过氧化物（B）的可硫化组合物。该耐热组合物具有由有机过氧化物和高模量赋予的高交联效率，并且可以提供耐环境劣化如耐热老化性优异的耐硫化橡胶模制产品。本发明的另一种耐热橡胶组合物是一种可硫化组合物，其包含100重量份由乙烯，α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和作为含有乙烯基端基的降冰片烯化合物的非共轭多烯，0.2〜5重量份的胺型防老化剂（C）和/或受阻酚型抗老化剂（D），1〜10重量份的硫型防老化剂（E）和有机过氧化物（B）。该耐热橡胶组合物可以提供硫化橡胶模制产品，其不仅具有优异的机械性能和电性能，而且显示出高显着高的耐热老化性。

23. 发明申请

US20070219320A1 Process for Producing Rubber Composition, Rubber Composition and use Thereof 审中-公开
标题翻译：生产橡胶组合物，橡胶组合物的方法及用途
公开(公告)号：US20070219320A1
公开(公告)日：2007-09-20
申请号：US11587756
申请日：2005-04-28
申请人： Kotaro Ichino , Masao Kunizane , Yuji Ishii , Kunihide Hiraoka , Masaaki Kawasaki , Hidetatsu Murakami , Keiji Okada
发明人： Kotaro Ichino , Masao Kunizane , Yuji Ishii , Kunihide Hiraoka , Masaaki Kawasaki , Hidetatsu Murakami , Keiji Okada
IPC分类号： C08F8/00
CPC分类号： C08L21/00 , B60C1/0016 , C08K5/0016 , C08L9/00 , C08L23/16 , C08L2666/06 , C08L2666/08
摘要： A process for producing a rubber composition containing a nonconjugated polyene copolymer (A), a softener (B) and a diene rubber (C), comprising: a step of mixing a copolymer composition (I), said copolymer composition (I) comprising 100 parts by weight of a nonconjugated polyene copolymer (A), said nonconjugated polyene copolymer (A) being a random copolymer containing 96 to 70 mol % of the structural units derived from α-olefin (A1) and 4 to 30 mol % of the structural units derived from nonconjugated polyene (A2) and having a glass transition temperature (Tg) of −25 to 20° C., and 1 to 100 parts by weight of the softener (B); the diene rubber (C); and optionally further the softener (B). A tire tread using the rubber composition and a tire having the tire tread.
摘要翻译：一种制备含有非共轭多烯共聚物（A），软化剂（B）和二烯橡胶（C）的橡胶组合物的方法，包括：将共聚物组合物（I），所述共聚物组合物（I）重量份的非共轭多烯共聚物（A），所述非共轭多烯共聚物（A）是含有96-70％（摩尔）衍生自α-烯烃（A1）的结构单元和4-30％（摩尔）结构衍生自非共轭多烯（A2）并且玻璃化转变温度（Tg）为-25至20℃的单元和1至100重量份的软化剂（B）; 二烯橡胶（C）; 和任选地进一步的软化剂（B）。使用橡胶组合物的轮胎胎面和具有轮胎胎面的轮胎。

24. 发明授权

US06303727B1 Linear triene compound and copolymer 失效
标题翻译：线性三烯化合物和共聚物
公开(公告)号：US06303727B1
公开(公告)日：2001-10-16
申请号：US09320838
申请日：1999-05-26
申请人： Ken Maeda , Masaaki Yasuda , Terunori Fujita , Keiji Okada , Makoto Kamimura , Kazuyuki Takimoto , Hidetatsu Murakami , Masaaki Kawasaki , Keiji Watanabe
发明人： Ken Maeda , Masaaki Yasuda , Terunori Fujita , Keiji Okada , Makoto Kamimura , Kazuyuki Takimoto , Hidetatsu Murakami , Masaaki Kawasaki , Keiji Watanabe
IPC分类号： C08F13600
CPC分类号： C08F236/22 , C07C2/04 , C07C11/21 , C07C2527/24 , C07C2531/14
摘要： A novel and useful linear triene compound represented by the following formula (1) is co-polymerized with an &agr;-olefin to obtain an ethylenically unsaturated copolymer which is superior in weather-ability, heat resitance and fastness to ozone, together with superior scorch stability and vulcanizability at high velocity in which R1, R2, R3, R4, R5 and R6 stand each, independently of each other, for hydrogen atom or an alkyl having 1-3 carbon atoms, R7 represents an alkyl having 1-3 carbon atoms and n is an integer of 0-5, with the proviso that each of R4s or of R5s may be identical with or different from each other, respectively, when n is 2 or greater.
摘要翻译：由下式（1）表示的新型有用的线性三烯化合物与α-烯烃共聚，得到耐候性，耐热性和耐臭氧性优异的烯属不饱和共聚物，以及优异的焦烧稳定性和R 1，R 2，R 3，R 4，R 5和R 6各自独立地表示氢原子或具有1-3个碳原子的烷基的高速度下的硫化性，R7表示具有1-3个碳原子的烷基，n表示是0-5的整数，条件是当n为2或更大时，R 4或R 5中的每一个可以分别彼此相同或不同。

25. 发明申请

US20080188621A1 Rubber Composition and Use Thereof 审中-公开
标题翻译：橡胶组合物及其用途
公开(公告)号：US20080188621A1
公开(公告)日：2008-08-07
申请号：US11587904
申请日：2005-04-28
申请人： Kotaro Ichino , Masao Kunizane , Yuji Ishit , Kunihide Hiraoka , Masaaki Kawasaki , Hidetatsu Murakami , Keiji Okada
发明人： Kotaro Ichino , Masao Kunizane , Yuji Ishit , Kunihide Hiraoka , Masaaki Kawasaki , Hidetatsu Murakami , Keiji Okada
IPC分类号： C08L9/02
CPC分类号： C08L21/00 , B60C1/0016 , C08L9/00 , C08L9/02 , C08L23/16 , C08L53/00 , C08L2666/02 , C08L2666/08
摘要： Provided is a rubber composition which can give a tire excellent in braking performance and fuel consumption and which is excellent in mechanical strength and fatigue resistance, and a use thereof.The rubber composition of the present invention contains a (A) 60 to 0.1 parts by weight of a nonconjugated polyene copolymer, which is a random copolymer containing 96 to 70 mol % of the structural units derived from α-olefin (A1) and 4 to 30 mol % of the structural units derived from a nonconjugated polyene (A2), and has a glass transition temperature (Tg) of −25 to 20° C., (B) 40 to 99.9 parts by weight of a diene rubber and (C) at least one selected from the group consisting of specific polymers.
摘要翻译：提供一种橡胶组合物，其能够赋予制动性能和燃料消耗优异并且机械强度和耐疲劳性优异的轮胎及其用途。本发明的橡胶组合物含有（A）60〜0.1重量份的非共轭多烯共聚物，其是含有96〜70摩尔％的来自α-烯烃（A1）的结构单元和4〜衍生自非共轭多烯（A2）的结构单元的30摩尔％，玻璃化转变温度（Tg）为-25〜20℃，（B）为40〜99.9重量份的二烯系橡胶，（C ）选自由特定聚合物组成的组中的至少一种。

26. 发明授权

US06787623B1 Unconjugated cyclopolyene copolymer, rubber composition, and use 失效
标题翻译：未结合的环戊烯共聚物，橡胶组合物及用途
公开(公告)号：US06787623B1
公开(公告)日：2004-09-07
申请号：US09787890
申请日：2001-03-26
申请人： Hidetatsu Murakami , Keiji Okada , Masaaki Kawasaki , Kotaro Ichino
发明人： Hidetatsu Murakami , Keiji Okada , Masaaki Kawasaki , Kotaro Ichino
IPC分类号： C08F23620
CPC分类号： C08L21/00 , B60C1/0016 , C08F210/02 , C08F210/18 , C08L23/08 , C08L23/0823 , Y10T152/10495 , C08L2666/06 , C08L2666/04 , C08F236/20 , C08F2500/25 , C08F2500/17 , C08F210/06
摘要： A tire provided with a tire tread made from a rubber composition comprising (A) a random copolymer based on non-conjugated cyclic polyene comprising structural units originated from one or more &agr;-olefins (A1) and originated from one or more non-conjugated cyclic polyene (A2), the said random copolymer having a content of the structural unit(s) originated from one or more &agr;-olefins (A1) in the range of 93 to 70 mole %; a content of the structural unit originated from one or more non-conjugated cyclic polyene (A2) in the range of 7 to 30 mole %; an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range of 0.01 to 20 dl/g; a glass transition temperature (Tg) of not higher than 40° C.; and an iodine value in the range of 50 to 150, and (B) a rubber based on diene, in a weight proportion of {the random copolymer based on non-conjugated cyclic polyene (A)} versus {the rubber based on diene (B)} in the range from 60/40 to 0.1/99.9 exhibits a superior braking performance and, compatible therewith, a superior driving fuel cost aspect.
摘要翻译：本发明提供一种轮胎胎面，其由橡胶组合物制成，该轮胎胎面由（A）基于非共轭环状多烯的无规共聚物构成，所述非共轭环多烯包含源自一种或多种α-烯烃（A1）的结构单元，并且源于一种或多种非共轭环多烯（A2），所述无规共聚物具有来源于一种或多种α-烯烃（A1）的结构单元的含量在93-70摩尔％范围内; 来自一种或多种7-30摩尔％的非共轭环状多烯（A2）的结构单元的含量; 在135℃的萘烷中测定的特性粘度η在0.01至20dl / g的范围内; 玻璃化转变温度（Tg）不高于40℃; 碘值在50〜150范围内，（B）基于二烯的橡胶，以{非共轭环状多烯（A）}为基准的无规共聚物）与{基于二烯的橡胶 B）}在60/40至0.1 / 99.9的范围内表现出优异的制动性能，并且与其兼容，具有优异的驱动燃料成本方面。

27. 发明申请

US20080064818A1 Nonconjugated Polyene Copolymer, Rubber Composition and Uses Thereof 审中-公开
标题翻译：非共轭多烯共聚物，橡胶组合物及其用途
公开(公告)号：US20080064818A1
公开(公告)日：2008-03-13
申请号：US11587755
申请日：2005-04-11
申请人： Hidetatsu Murakami , Keiji Okada , Kotaro Ichino , Masaaki Kawasaki , Hiroki Ebata , Yasuhiro Hasada , Shigenobu Ikenaga
发明人： Hidetatsu Murakami , Keiji Okada , Kotaro Ichino , Masaaki Kawasaki , Hiroki Ebata , Yasuhiro Hasada , Shigenobu Ikenaga
IPC分类号： C08L19/00 , C08F10/00
CPC分类号： C08F210/18 , B60C1/0016 , C08F236/20 , C08L21/00 , C08L23/145 , C08L23/16 , C08L2666/06 , C08F210/06 , C08F2500/25 , C08F2500/17
摘要： Disclosed are a conjugated polyene copolymer comprising a random copolymer having structural units derived from α-olefin (A1) of 2 to 20 carbon atoms and structural units derived from nonconjugated polyene (A2), said nonconjugated polyene copolymer having a glass transition temperature (Tg) of −25 to 20 □ and Mooney viscosity of [ML(1+4)100□] of 5 to 190; a rubber composition comprising the nonconjugated polyene copolymer and a diene-based rubber (B); a modifier for tires comprising the copolymer; a rubber material for tires comprising the rubber composition; a tire tread obtained from the rubber material for tires; and a tire having the tire tread.
摘要翻译：公开了包含具有衍生自2-20个碳原子的α-烯烃（A1）和来自非共轭多烯（A2）的结构单元的结构单元的无规共聚物的共轭多烯共聚物，所述非共轭多烯共聚物具有玻璃化转变温度（Tg） -25〜20□，门尼粘度[ML（1 + 4）100□]为5〜190; 包含非共轭多烯共聚物和二烯基橡胶（B）的橡胶组合物; 用于包含所述共聚物的轮胎的改性剂; 一种用于轮胎的橡胶材料，包括橡胶组合物; 从轮胎用橡胶材料获得的轮胎胎面; 以及具有轮胎胎面的轮胎。

28. 发明授权

US08410035B2 Viscosity modifier of lubricating oil for power transmission system and lubricating oil composition for power transmission system 有权
标题翻译：动力传动系统润滑油粘度调节剂和动力传动系统润滑油组成
公开(公告)号：US08410035B2
公开(公告)日：2013-04-02
申请号：US11886960
申请日：2006-03-24
申请人： Ryousuke Kaneshige , Akihiro Matsuda , Satoshi Ikeda , Keiji Okada , Masaaki Kawasaki
发明人： Ryousuke Kaneshige , Akihiro Matsuda , Satoshi Ikeda , Keiji Okada , Masaaki Kawasaki
IPC分类号： C10M119/02 , C08F10/06
CPC分类号： C10M169/041 , C10M107/02 , C10M143/00 , C10M2203/1006 , C10M2205/02 , C10M2205/022 , C10M2205/024 , C10M2209/084 , C10N2220/02 , C10N2220/021 , C10N2220/022 , C10N2220/032 , C10N2230/02 , C10N2230/68 , C10N2240/04 , C10N2240/042
摘要： A lubricating oil composition for a power transmission system, which is excellent in both of low-temperature viscosity property and shear stability, is provided. The viscosity modifier of a lubricating oil for a power transmission system according to the present invention comprises an ethylene/α-olefin copolymer (B) having the properties: (B1) an ethylene content in the range of 70 to 85% by mol, (B2) an intrinsic viscosity [η] in the range of 0.2 to 1.0 dl/g, (B3) Mw/Mn not more than 2.4, and (B4) a melting point, as measured by DSC, not higher than 60° C., or no melting point observed.
摘要翻译：提供了低温粘度特性和剪切稳定性优异的动力传递系统用润滑油组合物。根据本发明的用于动力传动系统的润滑油的粘度调节剂包括具有以下性质的乙烯/α-烯烃共聚物（B）：（B1）乙烯含量在70至85摩尔％的范围内（ B2）在0.2〜1.0dl / g范围内的特性粘度[（e）]，（B3）Mw / Mn不大于2.4，（B4）通过DSC测定的熔点不高于60℃ ，或没有观察到熔点。

29. 发明授权

US07622433B2 Lubricating oil composition and internal combustion engine oil 有权
标题翻译：润滑油组成和内燃机油
公开(公告)号：US07622433B2
公开(公告)日：2009-11-24
申请号：US10534580
申请日：2003-11-11
申请人： Ryousuke Kaneshige , Keiji Okada , Masaaki Kawasaki , Satoshi Ikeda
发明人： Ryousuke Kaneshige , Keiji Okada , Masaaki Kawasaki , Satoshi Ikeda
IPC分类号： C10L1/16
CPC分类号： C10M107/06 , C10M2205/022 , C10N2220/02 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2230/06 , C10N2230/08 , C10N2240/04 , C10N2240/08 , C10N2240/10 , C10M2205/024
摘要： The present invention provides a lubricating oil composition having excellent low temperature viscosity properties suitable for engine oils for automobiles and industries, gear oils, shock absorber oils, hydraulic fluids and it also provides a lubricating oil for internal-combustion engines formed from the composition.The lubricating oil composition comprises; a lubricating oil base (A) having a kinematic viscosity at 100° C. of 1 to 50 mm2/s and a viscosity index of not less than 80, an ethylene•propylene copolymer (B) having the following properties (B1) to (B4) such that (B1) the ethylene content is from 30 to 75% by weight, (B2) the intrinsic viscosity [η] is from 1.3 to 2.0 dl/g, (B3) the Mw/Mn is not more than 2.4 and (B4) the melting point as measured with DSC is not higher than 30° C., and optionally a pour point depressant (C).
摘要翻译：本发明提供一种具有优异的低温粘度性能的润滑油组合物，其适用于汽车和工业用发动机油，齿轮油，减震器油，液压油，并且还提供由该组合物形成的内燃机的润滑油。润滑油组合物包含：在100℃下的运动粘度为1〜50mm 2 / s，粘度指数为80以上的润滑油基材（A）具有以下特性的乙烯 - 丙烯共聚物（B）（B1）〜（ B4），使得（B1）乙烯含量为30〜75重量％，（B2）特性粘度η为1.3〜2.0dl / g，（B3）Mw / Mn为2.4以下，（B4）用DSC测定的熔点不高于30℃，任选地是倾点降低剂（C）。

30. 发明申请

US20090023619A1 Viscosity modifier of lubricating oil for power transmission system and lubricating oil composition for power transmission system 有权
标题翻译：动力传动系统润滑油粘度调节剂和动力传动系统润滑油组成
公开(公告)号：US20090023619A1
公开(公告)日：2009-01-22
申请号：US11886960
申请日：2006-03-24
申请人： Ryousuke Kaneshige , Akihiro Matsuda , Satoshi Ikeda , Keiji Okada , Masaaki Kawasaki
发明人： Ryousuke Kaneshige , Akihiro Matsuda , Satoshi Ikeda , Keiji Okada , Masaaki Kawasaki
IPC分类号： C10M145/14 , C08F210/02 , C10M143/02
CPC分类号： C10M169/041 , C10M107/02 , C10M143/00 , C10M2203/1006 , C10M2205/02 , C10M2205/022 , C10M2205/024 , C10M2209/084 , C10N2220/02 , C10N2220/021 , C10N2220/022 , C10N2220/032 , C10N2230/02 , C10N2230/68 , C10N2240/04 , C10N2240/042
摘要： A lubricating oil composition for a power transmission system, which is excellent in both of low-temperature viscosity property and shear stability, is provided. The viscosity modifier of a lubricating oil for a power transmission system according to the present invention comprises an ethylene/α-olefin copolymer (B) having the properties: (B1) an ethylene content in the range of 70 to 85% by mol, (B2) an intrinsic viscosity [η] in the range of 0.2 to 1.0 dl/g, (B3) Mw/Mn not more than 2.4, and (B4) a melting point, as measured by DSC, not higher than 60° C., or no melting point observed.
摘要翻译：提供了低温粘度特性和剪切稳定性优异的动力传递系统用润滑油组合物。根据本发明的用于动力传动系统的润滑油的粘度调节剂包括具有以下性质的乙烯/α-烯烃共聚物（B）：（B1）乙烯含量在70至85摩尔％范围内（ B2）特性粘度η在0.2〜1.0dl / g的范围内，（B3）Mw / Mn不大于2.4，（B4）通过DSC测定的熔点不高于60℃。，或没有观察到熔点。

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