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    • 5. 发明申请
    • Silicon-containing olefin copolymer, crosslinkable rubber composition thereof, and use thereof
    • 含硅烯烃共聚物,其可交联橡胶组合物及其用途
    • US20050038214A1
    • 2005-02-17
    • US10499122
    • 2002-12-26
    • Keiji OkadaHidetatsu MurakamiTakashi HakutaMasaaki Kawasaki
    • Keiji OkadaHidetatsu MurakamiTakashi HakutaMasaaki Kawasaki
    • C08F210/02C08F210/06C08F210/16C08F210/18C08L23/08C08F30/08
    • C08F210/18C08F210/02C08F210/06C08F210/16C08L23/0823C08L2666/02C08F232/00C08F2500/25C08F2500/17C08F2500/09C08F236/20C08F2500/03
    • The first silicon-containing olefin copolymer of the present invention comprises (a) a constituent unit derived from —CH2—CH2—, (b) a constituent unit derived from —CH2—CHR— [R is a hydrocarbon group of 1 to 18 carbon atoms], and (c) a constituent unit containing a specific silicon-containing group, and has a molar ratio [(a)/(b)] of the constituent units (a) to the constituent units (b) of from 99/1 to 30/70, a content of the constituent unit (c) of from 0.1 to 10 mol % based on 100 mol % of the total amounts of the constituent units (a), (b) and (c), and a branching index of not less than 0.70. The second silicon-containing olefin copolymer of the present invention is obtainable by copolymerizing ethylene, an α-olefin of 3 to 20 carbon atoms and a specific silicon-containing ethylene monomer, and has a molar ratio of ethylene to α-olefin of from 99/1 to 30/70, an intrinsic viscosity, as measured in decalin at 135° C., of from 0.1 to 10 dl/g, a content of the ethylene monomer of from 0.1 to 10 mol % based on 100 mol % of the total amounts of ethylene, α-olefin and the ethylene monomer. These copolymers may be cross-linked and then submitted to use, and have a high cross-linking rate, excellent productivity, heat ageing properties, weathering resistance. They, further, can provide a rubber composition capable of preparing molded articles having excellent properties such as scratch resistance, resistance to compression set, electric properties and strength. They furthermore can provide sealing materials, potting materials, coating materials and adhesives made from the composition and also provide cross-linked articles of the composition.
    • 本发明的第一含硅烯烃共聚物包含(a)衍生自-CH 2 -CH 2 - 的构成单元,(b)衍生自-CH 2 -CHR-的结构单元[R是1至18碳的烃基 原子],(c)含有特定含硅基团的构成单元,构成单元(a)与构成单元(b)的摩尔比[(a)/(b)]为99 / 1〜30/70,构成单元(c)的含量相对于构成单元(a),(b)和(c)的总量的100摩尔%为0.1〜10摩尔%,分支 指数不低于0.70。 本发明的第二含硅烯烃共聚物可通过使乙烯,3-20个碳原子的α-烯烃和特定的含硅乙烯单体共聚而获得,并且乙烯与α-烯烃的摩尔比为99 / 1〜30/70,在135℃萘烷中测定的特性粘度为0.1〜10dl / g,乙烯单体的含量相对于100摩尔%为0.1〜10摩尔% 乙烯,α-烯烃和乙烯单体的总量。 这些共聚物可以交联,然后使用,具有高的交联速度,优异的生产率,热老化性能,耐候性。 它们还可以提供能够制备具有优异性能如耐刮擦性,耐压缩变形性,电性能和强度的模制品的橡胶组合物。 它们还可以提供由组合物制成的密封材料,灌封材料,涂料和粘合剂,并且还提供组合物的交联物品。
    • 7. 再颁专利
    • Heat-resistant rubber composition
    • 耐热橡胶组合物
    • USRE37527E1
    • 2002-01-22
    • US09538790
    • 2000-03-29
    • Takashi HakutaTetsuo TojoMasaaki KawasakiMikio Hosoya
    • Takashi HakutaTetsuo TojoMasaaki KawasakiMikio Hosoya
    • C08F800
    • C08K5/14C08K5/0025C08L23/0815C08L2312/00C08L23/16C08L2666/04
    • A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
    • 本发明的耐热橡胶组合物是包含特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A)和有机过氧化物(B)的可硫化组合物。 该耐热组合物具有由有机过氧化物和高模量赋予的高交联效率,并且可以提供耐环境劣化如耐热老化性优异的耐硫化橡胶模制产品。 本发明的另一种耐热橡胶组合物是一种可硫化组合物,其包含100重量份由乙烯,α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A)和 作为含有乙烯基端基的降冰片烯化合物的非共轭多烯,0.2〜5重量份的胺型防老化剂(C)和/或受阻酚型抗老化剂(D),1〜10重量份 的硫型防老化剂(E)和有机过氧化物(B)。 该耐热橡胶组合物可以提供硫化橡胶模制产品,其不仅具有优异的机械性能和电性能,而且显示出高显着高的耐热老化性。
    • 9. 发明授权
    • Heat-resistant rubber composition
    • 耐热橡胶组合物
    • US5733983A
    • 1998-03-31
    • US750821
    • 1996-12-10
    • Takashi HakutaTetsuo TojoMasaaki KawasakiMikio Hosoya
    • Takashi HakutaTetsuo TojoMasaaki KawasakiMikio Hosoya
    • C08K5/00C08K5/14C08L23/08C08F8/00
    • C08K5/14C08K5/0025C08L23/0815C08L2312/00
    • A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an .alpha.-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
    • PCT No.PCT / JP96 / 00991 Sec。 371日期1996年12月10日第 102(e)日期1996年12月10日PCT 1996年4月11日PCT PCT。 出版物WO96 / 32442 日期1996年10月17日本发明的耐热橡胶组合物是包含特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A)和有机过氧化物(B)的可硫化组合物。 该耐热组合物具有由有机过氧化物和高模量赋予的高交联效率,并且可以提供耐环境劣化如耐热老化性优异的耐硫化橡胶模制产品。 本发明的另一种耐热橡胶组合物是一种可硫化组合物,其包含100重量份由乙烯,α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(A)和 作为含有乙烯基端基的降冰片烯化合物的非共轭多烯,0.2〜5重量份的胺型防老化剂(C)和/或受阻酚型抗老化剂(D),1〜10重量份 的硫型防老化剂(E)和有机过氧化物(B)。 该耐热橡胶组合物可以提供硫化橡胶模制产品,其不仅具有优异的机械性能和电性能,而且显示出高显着高的耐热老化性。