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    • 11. 发明授权
    • Zinc manganese silicate containing metal particles luminescent materials and preparation methods thereof
    • 含锌锰酸锰的金属颗粒发光材料及其制备方法
    • US09115309B2
    • 2015-08-25
    • US13703342
    • 2010-06-30
    • Mingjie ZhouWenbo MaChaopu Shi
    • Mingjie ZhouWenbo MaChaopu Shi
    • C09K11/59C09K11/87C01B33/20
    • C09K11/59C01B33/20C09K11/595C09K11/87C09K11/876
    • Zinc manganese silicate containing metal particles luminescent materials and preparation methods thereof are provided. The said luminescent materials are a blend of metal M nanoparticles and Zn2-xSiO4:Mnx, wherein M is one of Ag, Au and Pt, 0.001≦x≦0.1, 0.00001≦y≦0.01, y is the molar ratio of M to Zn2-xSiO4:Mnx. The said methods include the following steps: step 1, preparing silica aerogel containing metal particles; step 2, weighing source compound of zinc, source compound of manganese and the silica aerogel in step 1 at stoichiometric ratio and mixing them to form mixture; step 3, sintering the mixture in step 2, then cooling and grinding to form the said luminescent materials with higher luminescent intensity. The said methods have simple steps, easy operation, low sintering temperature and low cost.
    • 提供了含有金属锰酸锰的发光材料及其制备方法。 所述发光材料是金属M纳米颗粒和Zn2-xSiO4:Mnx的共混物,其中M是Ag,Au和Pt之一,0.001和n1E; x和nlE; 0.1,0.00001& nlE; y≦̸ 0.01,y是M 到Zn2-xSiO4:Mnx。 所述方法包括以下步骤:步骤1,制备含有金属颗粒的二氧化硅气凝胶; 步骤2,在化学计量比下,在步骤1中称量锌源,锰源和二氧化硅气凝胶,混合形成混合物; 步骤3,在步骤2中烧结混合物,然后冷却和研磨以形成具有较高发光强度的所述发光材料。 所述方法操作简单,操作简便,烧结温度低,成本低。
    • 18. 发明授权
    • Luminescent silicon nanoparticle-polymer composites, composite wavelength converter and white LED
    • 发光硅纳米颗粒 - 聚合物复合材料,复合波长转换器和白光LED
    • US08076410B2
    • 2011-12-13
    • US12241870
    • 2008-09-30
    • Munir H. NayfehSalman A. H. Alrokayan
    • Munir H. NayfehSalman A. H. Alrokayan
    • C08F292/00C09K11/59H01J1/63
    • C09K11/02C09K11/59H01L33/502
    • An embodiment of the invention is luminescent silicon nanoparticle polymer composite that can serve as a wavelength converter or a UV absorber. The composite includes a polymer or an organosilicon compound; and within the polymer or organosilicon compound, a dispersion of luminescent silicon nanoparticles. In a preferred composite, the silicon nanoparticles have multiple Si—H termination sites, the silicon nanoparticles being linked to a C site to produce a silicon carbide bond (Si—C). In a preferred embodiment, the polymer comprises polyurethane. A composite of the invention can perform wavelength conversion. In a wavelength converted film of the invention, the silicon nanoparticles are incorporated into the polymer or organosilicon compound in a quantity sufficient for wavelength conversion but small enough to have no or an insubstantial effect on the properties of the polymer or the organosilicon compound. A white LED of the invention includes a light emitting diode having a narrow band wavelength output. A luminescent silicon wavelength converter includes a composite film as described above for converting the narrow band wavelength output into wide band wavelength output. In a preferred embodiment, the LED comprises a GaN LED, and the wavelength converter film is disposed on an active region of the LED.
    • 本发明的一个实施方案是可用作波长转换器或UV吸收剂的发光硅纳米颗粒聚合物复合材料。 复合材料包括聚合物或有机硅化合物; 并且在聚合物或有机硅化合物内,发光硅纳米颗粒的分散体。 在优选的复合材料中,硅纳米颗粒具有多个Si-H终止位点,硅纳米颗粒与C位点连接以产生碳化硅键(Si-C)。 在优选的实施方案中,聚合物包含聚氨酯。 本发明的复合物可以进行波长转换。 在本发明的波长转换膜中,将硅纳米颗粒掺入到聚合物或有机硅化合物中,其量足够于波长转换,但足够小以致对聚合物或有机硅化合物的性质没有或没有实质性的影响。 本发明的白色LED包括具有窄带波长输出的发光二极管。 发光硅波长转换器包括如上所述的用于将窄带波长输出转换成宽带波长输出的复合膜。 在优选实施例中,LED包括GaN LED,并且波长转换器膜设置在LED的有源区上。
    • 20. 发明申请
    • INORGANIC NANOPARTICLE LABELING AGENT
    • 无机纳米材料标签代理
    • US20110111233A1
    • 2011-05-12
    • US13002491
    • 2009-02-26
    • Kazuya TsukadaTakuji Aimiya
    • Kazuya TsukadaTakuji Aimiya
    • C09K11/00B05D5/00B82Y5/00B82Y15/00B82Y40/00
    • G01N33/587C09K11/02C09K11/59C09K11/592C09K11/66C09K11/661Y10T428/2991Y10T428/2993
    • An inorganic nanoparticle labeling agent having adaptability for being employed as a labeled material in the field of biology and medical science and capable of emitting fluorescence at a stable emission intensity is disclosed, comprising inorganic nanoparticles which were surface-modified with an organic compound, wherein the inorganic nanoparticles exhibit an average particle size of 1 to 10 nm, the organic compound is a compound containing a polyethylene glycol chain, the average particle size D of the inorganic nanoparticle labeling agent is from 8 to 25 nm; and an amount M (mol) of the organic compound per inorganic nanoparticle and a length L (nm) of the organic compound measured from an inorganic nanoparticle surface meet the relationship represented by the following formula (I): (M×1022)×L/D=1.0−4.5  Formula (I)
    • 公开了一种具有适用于在生物学和医学领域中用作标记材料并且能够以稳定发射强度发射荧光的适应性的无机纳米颗粒标记剂,其包括用有机化合物进行表面改性的无机纳米颗粒,其中 无机纳米粒子的平均粒径为1〜10nm,有机化合物为含有聚乙二醇链的化合物,无机纳米粒子标记剂的平均粒径D为8〜25nm, 无机纳米粒子的有机化合物的M(摩尔)和无机纳米粒子表面的有机化合物的长度L(nm)满足下式(I)所示的关系:(M×1022)×L / D = 1.0-4.5式(I)