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    • 12. 发明授权
    • Reactive dyes, processes for their preparation and their use
    • 活性染料,其制备方法及其用途
    • US06592634B1
    • 2003-07-15
    • US09521711
    • 2000-03-09
    • Hans ReichertThomas Verdugo
    • Hans ReichertThomas Verdugo
    • D06P1382
    • C09B62/4403C09B62/021C09B62/043C09B62/205Y10S8/918
    • Reactive dyes of the formula (1) in which R1, R2, R3 and R4 independently of one another are hydrogen or substituted or unsubstituted C1-C4alkyl, (R5)0-2 and (R6)0-2 independently of one another are 0 to 2 identical or different substituents from the group consisting of C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, halogen, carboxyl, sulfo, carbamoyl, N-C1-C4alkylcarbamoyl, N,N-di-C1-C4alkylcarbamoyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylsulfamoyl and N,N-di-C1-C4alkylsulfamoyl, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl or naphthyl which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C1-C4alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl, ureido or halogen, or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl, B1 is an aliphatic or aromatic bridge member, and the remaining substituents are described in the specification.
    • 其中R 1,R 2,R 3和R 4彼此独立地是式(1)的反应性染料是氢或取代或未取代的C 1 -C 4烷基,(R 5)0-2和(R 6) 2个与C1-C4烷基,C1-C4烷氧基,C2-C4烷酰基氨基,卤素,羧基,磺基,氨基甲酰基,N-C1-C4烷基氨基甲酰基,N,N-二C1-C4烷基氨基甲酰基,C1-C4烷基磺酰基, 氨磺酰基,N-C 1 -C 4烷基氨磺酰基和N,N-二-C 1 -C 4烷基氨磺酰基,A是未取代或被羟基,磺基,羧基或硫酸酯取代的C 1 -C 4烷基,未被取代或被C1- C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 4烷酰基氨基,羟基,羧基,氨基甲酰基,磺基或卤素,苯基-C 1 -C 4亚烷基,其未被取代或在苯环中被C1-C4烷基,C1-C4烷氧基,C2-C4烷酰基氨基,羟基, ,磺基,氨基甲酰基,脲基或卤素,或未被取代或被C 1 -C 4烷基取代的C 5 -C 7环烷基 ,B1是脂族或芳族桥连构件,其余的取代基在说明书中描述。
    • 13. 发明授权
    • Black-dyeing inks and their use
    • 黑染油墨及其用途
    • US06500247B1
    • 2002-12-31
    • US09495803
    • 2000-02-01
    • Urs LehmannAlthanassios TzikasMarcel Frick
    • Urs LehmannAlthanassios TzikasMarcel Frick
    • C09D1100
    • C09D11/32C09B43/16C09B62/04C09B62/4403C09B67/0041C09B67/0046C09D11/17C09D11/18C09D11/328D06P5/30
    • Black-dyeing aqueous inks having good black shades without a shade change in artificial light and outstanding lightfastness comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) the dye (B) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) and the dye (C) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formulae (V), (VI), (VII) or (VII) and one or more radicals of the formulae (I), (II), (III) or (IV), in which the substituents are as defined herein.
    • 具有良好黑色阴影的黑色染料水性墨水,人造光线下没有变化,并且具有优异的耐光性,其包含20至95重量%的至少一种染料(A),以及5-80重量%的至少一种选自 由(B)和(C)组成的组,基于油墨中染料(A),(B)和(C)的总重量,和1〜40重量%的水混溶性有机溶剂, 基于油墨的总重量,含有分子的着色部分的一种或多种式(I),(II),(III)或(IV)的染料(B )包含作为分子的着色部分的一个或多个含有磺基的单或双偶氮基或一个或多个式(V),(VI),(VII)或(VIII)的基团和染料(C )包含作为分子的着色部分的一个或多个含有磺基的单或双偶氮基或一个或多个式(Ⅴ),(Ⅵ),(Ⅶ)或(Ⅶ)的基团和一个或多个基团 的式(I),( II),(III)或(IV),其中取代基如本文所定义。
    • 16. 发明授权
    • Reactive dyes containing fluorotriazine and vinylsulfonyl radicals
    • 含有氟代三嗪和乙烯基磺酰基的活性染料
    • US5298607A
    • 1994-03-29
    • US063848
    • 1993-05-26
    • Herbert Seiler
    • Herbert Seiler
    • C09B62/44C09B62/04C09B62/06C09B62/08C09B62/10D06P1/38D06P3/66
    • C09B62/4403
    • The invention provides reactive dyes of the formula ##STR1## wherein D is a mono- or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazane, dioxazine or stilbene dye which contains sulfo groups, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, methyl or ethyl, X is a radical of the formula --SO.sub.2 CH.sub.2 CH.sub.2 Cl, --SO.sub.2 CH.dbd.CH.sub.2, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H, --SO.sub.2 CH.sub.2 CH.sub.2 OPO.sub.3 H or --N(R.sub.3)SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H, and R.sub.3 is hydrogen, methyl or ethyl, and the benzene or naphthalene radical is not further substituted or is further substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, hydroxyl, carboxyl or sulfo; the dyes are suitable for dyeing and printing a variety of materials especially cellulosic materials; they are distinguished by high reactivity and produce dyeings having good wet- and lightfastness properties; they have also good fixation properties and produce dyeings of notably high tinctorial strength.
    • 本发明提供了式(1)的活性染料,其中D是含有磺基的单或多偶氮金属络合物偶氮,蒽醌,酞菁,甲烷,二恶嗪或二苯乙烯染料,R 1是氢或C 1 -C 4烷基 ,R2是氢,甲基或乙基,X是式-SO2CH2CH2Cl,-SO2CH = CH2,-SO2CH2CH2OSO3H,-SO2CH2CH2OPO3H或-N(R3)SO2CH2CH2OSO3H的基团,R3是氢,甲基或乙基,苯或 萘基不被进一步取代或进一步被C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,硝基,羟基,羧基或磺基取代; 该染料适用于染色和印刷各种材料,特别是纤维素材料; 它们被高反应性区分,并产生具有良好的耐湿和耐光性的染色; 它们也具有良好的固色性能,并产生显着高的着色强度的染色。
    • 17. 发明授权
    • Fiber-reactive dyes containing chromophoric system bound to a bridging
member consisting of two or three triazinyl radicals
    • US4963659A
    • 1990-10-16
    • US323455
    • 1989-03-14
    • Athanassios Tzikas
    • Athanassios Tzikas
    • C09B62/503C09B62/44C09B62/505C09B62/51C09B62/513C09B62/515C09B62/517D06P3/66
    • C09B62/4403
    • Reactive dyes which are particularly suitable for the dyeing or printing of cellulose-containing fiber materials by the exhaust process or by the continuous process and give, at a high color yield, dyeings and prints having good fastness properties, having the formula ##STR1## in which D.sub.1 and D.sub.2, independently of one another, are each a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; R.sub.1, R.sub.2, B.sub.1 and B.sub.2, independently of one another, are hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; X is fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.4 alkylsulfonyl, phenylsulfonyl or carboxypyridinium, and E is a radical of the formula ##STR2## in which A.sub.1 and A.sub.2, independently of one another, are each a radical of the formula ##STR3## or X is a radical of the formula ##STR4## and E is a radical of the formula (3a), (3b), (3c) or (3d); and R.sub.3 is hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; R.sub.4 and R.sub.5, independently of one another, are 0 to 3 substituents from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo; B is a direct bond or --(CH.sub.2).sub.n --or --O--(CH2).sub.n --, n is 1 to 6; R is a radical of the formula ##STR5## Z is a .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-halogenoethyl or vinyl; alk is alkylene having 1 to 6 carbon atoms or branced isomers thereof; T is hydrogen, chlorine, bromine, fluorine, hydroxyl, sulfato, alkanoyloxy having 2 to 4 carbon atoms, cyano, carboxyl, alkoxycarbonyl having 1 to 5 carbon atoms, carbamoyl, or --SO.sub.2 --Z in which Z is as defined above;V is hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by carboxyl, sulfo, carbamoyl, N-methylcarbamoyl, N-ethylcarbamoyl, N,N-dimethylcarbamoyl, N,N-diethylcarbamoyl, cyano, acetyl, propionyl, butyryl, methoxycarbonyl, ethoxycarbonyl, propyloxycarbonyl, sulfamoyl, N-methylsulfamoyl, N-ethylsulfamoyl, N,N-dimethylsulfamoyl, N,N-diethylsulfamoyl, methylsulfonyl, ethylsulfonyl, propylsulfonyl, alkoxy having 1 or 2 carbon atoms, halogen or hydroxyl; or is ##STR6## in which Z, alk and T are as defined above; R' is hydrogen or C.sub.1 -C.sub.6 alkyl; alk', independently of one another, is polymethylene having 2 to 6 carbon atoms or branched isomers thereof; and m is 1 to 6, p is 1 to 6 and q is 1 to 6.