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    • 34. 发明公开
    • 옥심 에스테르기와 트리아진기를 동시에 포함하는 광활성화합물 및 이를 포함하는 감광성 조성물
    • 包含氧化酯和TRIAZINE的光学化合物和包含它们的光敏组合物
    • KR1020080068368A
    • 2008-07-23
    • KR1020070006078
    • 2007-01-19
    • 주식회사 엘지화학
    • 김성현윤정애카르바쉬라이사이건우조창호오동궁곽상규
    • G03F7/004C07D251/14
    • C07D251/14G03F7/0045G03F7/027G03F7/028G03F7/032
    • A photoactive compound, and a photosensitive composition containing the photoactive compound are provided to improve sensitivity, residual film rate, mechanical strength, heat resistance, chemical resistance and development resistance. A photoactive compound comprises an oxime ester group and a triazine group and is represented by the formula 1, wherein R is a C1-C6 alkyl group, a C1-C6 haloalkyl group, a C1-C6 alkyl group substituted with at least one selected from NL2, OL and SL, a phenyl group substituted or unsubstituted with at least one selected from a C1-C6 alkyl group, a halogen atom, a nitrile group, OH and COOH, or a C2-C5 alkyl carboxylic acid group; L is H or a C1-C6 alkyl group; R' is H, a C1-C6 alkyl group, a nitrile group, or a phenyl group; X is a single bond, CH2, C=O, O, S, S=O, SO2, NR'', or CH=CH; R'' is H, a C1-C6 alkyl group, or a C2-C6 alkyl carboxylic acid group; and Y and Y' are independently H, a halogen atom, CN, a C1-C6 alkyl group, a C1-C6 alkoxy group, or a C1-C6 alkylthio group.
    • 提供光敏化合物和含有光敏化合物的光敏组合物以提高灵敏度,残留膜速率,机械强度,耐热性,耐化学性和显影性。 光活性化合物包含肟酯基和三嗪基,由式1表示,其中R是C1-C6烷基,C1-C6卤代烷基,被至少一个选自 NL2,OL和SL,被选自C1-C6烷基,卤素原子,腈基,OH和COOH中的至少一种取代或未取代的苯基或C2-C5烷基羧酸基团; L是H或C1-C6烷基; R'是H,C1-C6烷基,腈基或苯基; X是单键,CH2,C = O,O,S,S = O,SO2,NR“或CH = CH; R“是H,C1-C6烷基或C2-C6烷基羧酸基团; Y和Y'独立地为H,卤素原子,CN,C1-C6烷基,C1-C6烷氧基或C1-C6烷硫基。
    • 35. 发明公开
    • 옥심 에스테르를 포함하는 트리아진계 광활성 화합물을포함하는 투명한 감광성 조성물
    • 包含基于TRIAZINE的含光化合物包含氧化物的透明感光性组合物
    • KR1020070072344A
    • 2007-07-04
    • KR1020060095897
    • 2006-09-29
    • 주식회사 엘지화학
    • 이건우권일억오동궁박종현김성현윤정애이상려
    • G03F7/027G03F7/004
    • G03F7/0007G03F7/0295Y10S430/106Y10S430/114G03F7/027G03F7/0045G03F7/028
    • Provided is a transparent photosensitive composition, which uses an initiator having an oxime ester group and a triazine groups in one molecule, absorbs UV rays efficiently, and shows excellent sensitivity, residual film ratio, mechanical strength, heat resistance, chemical resistance and developing resistance. The transparent photosensitive composition comprises: (a) a triazine-based photoactive compound containing an oxime ester group represented by the following formula(1); (b) a polymerizable compound having ethylenically unsaturated bonds; (c) an alkali soluble resin binder; and (d) a solvent. In formula(1), n is 1 or 2; when n is 1, R is a substituted or non-substituted alkyl, substituted or non-substituted phenyl or alkyl carboxylic acid, and L is H or an alkyl; when n is 2, R is alkylene, phenylene or a specific divalent radical; R' is H, an alkyl, nitrile or phenyl; and X is a substituted or non-substituted arylene, substituted or non-substituted divalent heterocyclic group or a compound represented by the following formula(2). In formula(2), each of Z and Z' is CH2, O, S or CH=CH, wherein R" is H or an alkyl; each of l and m is an integer of 0-2 with the proviso that l+m is not o; A is a single bond, CpH2p, O(CH_2O)p, CH=CH, NR"', S, O, S=O, SO2 or C=O, wherein p is an integer of 1-6, and R"' is H or an alkyl, with the proviso that when l+m=1, A is not a single bond; and each of Y and Y' is H, a halogen atom, CN, alkyl, alkoxy, alkylthio or morpholino.
    • 提供一种使用具有肟酯基和三嗪基的引发剂的透明感光性组合物,能够有效地吸收紫外线,显示出优异的灵敏度,残留膜比,机械强度,耐热性,耐药品性和耐显影性。 透明感光性组合物包含:(a)含有下述式(1)表示的肟酯基的三嗪类光活性化合物。 (b)具有烯属不饱和键的聚合性化合物; (c)碱溶性树脂粘合剂; 和(d)溶剂。 在式(1)中,n为1或2; 当n为1时,R为取代或未取代的烷基,取代或未取代的苯基或烷基羧酸,L为H或烷基; 当n为2时,R为亚烷基,亚苯基或特定二价基团; R'是H,烷基,腈或苯基; X为取代或未取代的亚芳基,取代或未取代的二价杂环基或下式(2)表示的化合物。 在式(2)中,Z和Z'各自为CH 2,O,S或CH = CH,其中R“为H或烷基; l和m各自为0-2的整数,条件是l + m不为O; A为单键,CpH2p,O(CH_2O)p,CH = CH,NR“',S,O,S = O,SO2或C = O,其中p为1-6 ,R“'为H或烷基,条件是当l + m = 1时,A不是单键; Y和Y'各自为H,卤素原子,CN,烷基,烷氧基,烷硫基 或吗啉代。