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1. 发明专利

JP2013060451A Catalyst for asymmetric hydrogenation reaction in homogeneous system 有权
标题翻译：催化剂在均相体系中的非对称加氢反应
公开(公告)号：JP2013060451A
公开(公告)日：2013-04-04
申请号：JP2012243030
申请日：2012-11-02
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： SHIMIZU HIDEO , IGARASHI DAISUKE , KURIYAMA WATARU , YUSA YUKINORI
IPC分类号： C07F1/08 , B01J31/24 , C07B53/00 , C07B61/00 , C07C29/145 , C07C31/125 , C07C33/18 , C07C33/20 , C07C33/22 , C07C33/40 , C07C35/08 , C07C41/20 , C07C43/23 , C07C45/62 , C07C49/403 , C07C67/303 , C07C69/24 , C07C69/612 , C07C213/00 , C07C215/68 , C07C231/12 , C07C233/47 , C07D209/12 , C07D307/44
CPC分类号： C07C29/145 , B01J31/2409 , B01J31/2452 , B01J31/2457 , B01J2231/643 , B01J2531/0266 , B01J2531/16 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C29/175 , C07C41/26 , C07C45/62 , C07C67/303 , C07C231/12 , C07C2601/14 , C07C2601/16 , C07D209/08 , C07D307/46 , C07F9/5045 , C07F9/65517 , C07C49/403 , C07C69/612 , C07C69/24 , C07C233/47 , C07C43/196 , C07C31/125 , C07C33/18 , C07C33/22 , C07C35/08 , C07C35/18
摘要： PROBLEM TO BE SOLVED: To provide: a catalyst for hydrogenation reaction in homogeneous system containing an asymmetric copper complex having an asymmetric ligand which is relatively easily available, is good in economic efficiency and workability, and is useful for hydrogenation reaction, especially asymmetric hydrogenation reaction, especially asymmetric hydrogenation reaction in a homogeneous system; and a method for producing a hydrogenation product of an unsaturated compound with good yield and optical purity, especially a method for producing an optically-active compound using the catalyst.SOLUTION: This asymmetric copper complex is expressed by general formula (61): [LLCuL]. In the formula, Lindicates a bidentate optically active phosphorus compound; Lindicates a phosphorus compound different from L; Lindicates a ligand; and n35 indicates a natural number.
摘要翻译：要解决的问题：提供：含有具有相对容易获得的不对称配位体的不对称铜络合物的均相体系中的氢化反应催化剂，经济效益和加工性良好，特别适用于氢化反应在不均匀加氢反应中，特别是不均匀系统中的不对称氢化反应; 特别是使用该催化剂制造光学活性化合物的方法，以及产率和光学纯度的不饱和化合物的氢化产物的制造方法。
解决方案：该不对称铜络合物由通式（61）表示：[L 11 L 12 CuL 13 ] n35 。在该式中，L 11 表示二齿光学活性磷化合物; L 12 表示不同于L 11 的磷化合物; L 13 表示配体; n35表示自然数。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2012067021A Method of producing alcohol and/or amine from amide compound 有权
标题翻译：从酰胺化合物生产醇和/或胺的方法
公开(公告)号：JP2012067021A
公开(公告)日：2012-04-05
申请号：JP2010211338
申请日：2010-09-21
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： OGATA TADASHI , KURIYAMA WATARU , MATSUMOTO TAKASHI
IPC分类号： C07C29/136 , C07B61/00 , C07C31/125 , C07C33/22 , C07C209/50 , C07C211/46 , C07C211/48 , C07C211/55
CPC分类号： C07C209/50 , B01J31/1805 , B01J31/189 , B01J31/20 , B01J31/24 , B01J2231/643 , B01J2531/821 , C07B41/02 , C07B43/04 , C07C29/149 , C07C29/36 , C07C209/62 , C07D295/02 , C07D295/18 , C07C211/04 , C07C211/46 , C07C211/48 , C07C211/55 , C07C31/125 , C07C33/22
摘要： PROBLEM TO BE SOLVED: To provide a method of producing an alcohol and an amine from an amide under a hydrogen atmosphere, using, as a catalyst, a ruthenium complex easy to be prepared and handled, and available relatively inexpensively.SOLUTION: The present invention relates to the method of producing the alcohol and/or the amine from the amide under the hydrogen atmosphere, using, as the catalyst, the ruthenium complex expressed by General Formula (1) RuXY(CO)(L) (1), wherein X and Y may be same or different each other and represent anionic ligands respectively, and L represents a tridentate amino diphosphine ligand having two phosphino groups and -NH- group.
摘要翻译：要解决的问题：提供一种在氢气氛下由酰胺制备醇和胺的方法，使用易于制备和处理的钌络合物作为催化剂，并且相对便宜地得到。解决方案：本发明涉及使用由通式（1）表示的钌络合物作为催化剂，在氢气氛下由酰胺制备醇和/或胺的方法RuXY（CO）（ L）（1），其中X和Y可以相同或不同，分别表示阴离子配体，L表示具有两个膦基和-NH-基团的三齿氨基二膦配体。版权所有（C）2012，JPO＆INPIT

3. 发明专利

JP2011037809A Method for producing alcohol by reducing ester or lactone with hydrogen 有权
标题翻译：通过用氢还原酯或酯来生产醇的方法
公开(公告)号：JP2011037809A
公开(公告)日：2011-02-24
申请号：JP2009197124
申请日：2009-08-27
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： KURIYAMA WATARU , INO YASUNORI , OGATA TADASHI
IPC分类号： C07C29/149 , C07B61/00 , C07C31/20 , C07C33/20 , C07C33/22 , C07C213/00 , C07C215/08 , C07C269/06 , C07C271/16 , C07D213/30 , C07D307/44
CPC分类号： C07C269/06 , C07B31/00 , C07B2200/07 , C07C29/149 , C07C213/08 , C07C2531/30 , C07D213/30 , C07D307/44 , C07C215/08 , C07C271/16 , C07C31/20 , C07C33/20 , C07C33/22 , C07C33/26
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an alcohol from an ester or a lactone with a high yield and at high catalytic efficiency under a comparatively mild condition. SOLUTION: In the method, an ester or a lactone is reduced with hydrogen without addition of a base compound to produce a corresponding alcohol by using, as a catalyst, a ruthenium complex represented by following formula (1): RuH(X)(L 1 )(L 2 ) n (wherein X represents a monovalent anionic ligand; L 1 represents a tetradentate ligand having at least one coordinating phosphino group and at least one coordinating amino group or a bidentate aminophosphine ligand having one coordinating phosphino group and one coordinating amino group; and L 2 represents a bidentate aminophosphine ligand having one coordinating phosphino group and one coordinating amino group, provided that n is 0 when L 1 is the tetradentate ligand, and n is 1 when L 1 is the bidentate ligand). COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供一种在相对温和的条件下以高产率和高催化效率从酯或内酯生产醇的方法。解决方案：在该方法中，通过使用由下式（1）表示的钌络合物作为催化剂，通过氢气还原酯或内酯而不添加碱性化合物以产生相应的醇：RuH（X ）（L 1 ）（L 2 ） n （其中X表示一价阴离子配体; L 具有至少一个配位膦基和至少一个配位氨基的四齿配位体或具有一个配位的膦基和一个配位氨基的二齿氨基膦配体; L 2 表示具有一个配位氨基的双齿氨基膦配体配位膦基和一个配位氨基，条件是当L 1时n为0时为四齿配体，当L 1为二齿配体时，n为1。版权所有（C）2011，JPO＆INPIT

4. 发明专利

JP2009096752A Method for producing alcohol 审中-公开
标题翻译：生产醇的方法
公开(公告)号：JP2009096752A
公开(公告)日：2009-05-07
申请号：JP2007269229
申请日：2007-10-16
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： INO YASUNORI , KURIYAMA WATARU
IPC分类号： C07C29/149 , C07B61/00 , C07C31/125 , C07C33/22 , C07C33/26
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an alcohol in high yield and high catalyst efficiency from an ester or a lactone, under a relatively mild condition and by using an easily synthesized catalyst. SOLUTION: This method for producing the alcohols is provided by hydrogen reduction of the ester or lactone by using the catalyst consisting of a ruthenium (Ru) compound, a monophosphine and an amine. The above reaction is preferably performed in the presence of a base or a reducing agent. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供一种在相对温和的条件下通过使用容易合成的催化剂从酯或内酯生产高产率和高催化剂效率的醇的方法。解决方案：通过使用由钌（Ru）化合物，单膦和胺组成的催化剂，通过氢还原酯或内酯来提供该醇的制备方法。上述反应优选在碱或还原剂的存在下进行。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2008169201A Novel optically biaryl phosphorus compound and method for producing the same 审中-公开
标题翻译：新型光学二元磷化合物及其生产方法
公开(公告)号：JP2008169201A
公开(公告)日：2008-07-24
申请号：JP2007316471
申请日：2007-12-07
申请人： Takasago Internatl Corp , Tokyo Univ Of Agriculture & Technology , 国立大学法人東京農工大学 , 高砂香料工業株式会社
发明人： TANAKA TAKESHI , KURIYAMA WATARU
IPC分类号： C07F9/40 , B01J31/22 , B01J31/24 , B01J37/18 , C07B53/00 , C07F7/12 , C07F9/53 , C07F9/572 , C07F9/655
CPC分类号： C07F9/5728 , C07B53/00 , C07F9/4021 , C07F9/5022 , C07F9/5325 , C07F9/65517 , Y02P20/55
摘要： PROBLEM TO BE SOLVED: To provide a novel optically active biaryl phosphorus compound which can be simply produced without an optical resolution step, which is a step almost indispensable in a conventional method. SOLUTION: An optically active phosphorus compound is provided which is produced by, for example, a preparative method shown by reaction formula (A) (wherein Z is a divalent group such as oxygen or methylene; R' is an alkyl group or the like; R" is an alkoxyl group, an alicyclic group, an aromatic group, or the like). COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种新颖的光学活性联芳基磷化合物，其可以在没有光学拆分步骤的情况下简单地制备，这是常规方法中几乎不可缺少的步骤。解决方案：提供通过例如由反应式（A）所示的制备方法（其中Z是二价基团如氧或亚甲基; R'是烷基或烷基）制备的光学活性磷化合物，类似物; R“是烷氧基，脂环族基团，芳族基团等）。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2005281144A Method for producing optically active tetrahydroisoquinolines 有权
标题翻译：生产光学活性四氢喹啉的方法
公开(公告)号：JP2005281144A
公开(公告)日：2005-10-13
申请号：JP2004093453
申请日：2004-03-26
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： KURIYAMA WATARU , CHIYOU SHIYOUYUU , TAKENAKA MOTONOBU
IPC分类号： C07D217/04 , B01J31/22
摘要： PROBLEM TO BE SOLVED: To provide a method which can produce an optically active 1-phenyl-1,2,3,4-tetrahydroisoquinoline of high optical purity or its salt at a low cost in a good yield with an industrial advantage.
SOLUTION: The method for producing the optically active 1-phenyl-1,2,3,4-tetrahydroisoquinoline represented by formula (2) (wherein * means an asymmetric carbon atom) or its salt by reacting 1-phenyl-3,4-dihydroisoquinoline represented by formula (1) or its salt with a hydrogen gas in the presence of a catalyst comprises using a ruthenium-optically active phosphine complex as the catalyst.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种能够以低成本以良好的产率生产具有高光学纯度的光学活性1-苯基-1,2,3,4-四氢异喹啉或其盐的方法，具有工业优势。解决方案：由式（2）表示的光学活性1-苯基-1,2,3,4-四氢异喹啉（其中*表示不对称碳原子）或其盐，通过使1-苯基-3 由式（1）表示的4-二氢异喹啉或其与氢气在催化剂存在下的盐包括使用钌 - 光学活性膦配合物作为催化剂。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2014114257A Method for reducing halogen-substituted benzoate ester using ruthenium carbonyl complex 审中-公开
标题翻译：使用碳酸氢钠复合物还原卤代烃取代苯甲酸酯的方法
公开(公告)号：JP2014114257A
公开(公告)日：2014-06-26
申请号：JP2012270942
申请日：2012-12-12
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： HORI KIYOTO , OGATA TADASHI , KURIYAMA WATARU
IPC分类号： C07C29/149 , C07B61/00 , C07C33/46
CPC分类号： C07C51/60 , C07C29/149 , C07C33/46
摘要： PROBLEM TO BE SOLVED: To provide a method for reducing a benzoate ester in which dehalogenation is suppressed using an easily available catalyst.SOLUTION: There is provided a method for reducing a benzoate ester in which dehalogenation is suppressed in which an ester group in a benzoate ester in which an aromatic ring is replaced by a halogen atom is reduced by hydrogen gas using an aromatic hydrocarbon as a solvent in the presence of a ruthenium complex represented by the following formula (1) to produce benzyl alcohol in which an aromatic ring is replaced by a halogen atom: RuXY(CO)(L) (1) (wherein, X and Y each represent an anionic ligand and L represents a three-dentate aminodiphosphine ligand represented by the following formula (2).) (wherein, R, R, Rand Rindividually may be the same or different and each represent an alkyl group, a cycloalkyl group, an aryl group or the like; Qand Qmay be the same or different and each represent a divalent alkylene group which may have a substituent, a divalent cycloalkylene group which may have a substituent or the like.)
摘要翻译：要解决的问题：提供一种还原苯甲酸酯的方法，其中使用容易获得的催化剂抑制脱卤。解决方案：提供一种降低苯甲酸酯的方法，其中抑制脱卤化苯甲酸酯，其中苯甲酸酯基在由下式（1）表示的钌络合物的存在下，使用芳烃作为溶剂，通过氢气使芳烃环被卤原子取代的酯被还原，得到其中芳环被取代的苯甲醇通过卤素原子：RuXY（CO）（L）（1）（其中，X和Y各自表示阴离子配体，L表示由下式（2）表示的三齿氨基二膦配体）（其中，R， R，Rand可以相同或不同，各自表示烷基，环烷基，芳基等; Q和Q可以相同或不同，表示可以具有取代基的二价亚烷基可以是可以具有取代基的二价亚环烷基等。）

8. 发明专利

JP2013063433A Catalyst for homogeneous asymmetric hydrogenation reaction 有权
标题翻译：催化剂用于均相不对称加氢反应
公开(公告)号：JP2013063433A
公开(公告)日：2013-04-11
申请号：JP2012243031
申请日：2012-11-02
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： SHIMIZU HIDEO , IGARASHI DAISUKE , KURIYAMA WATARU , YUSA YUKINORI
IPC分类号： B01J31/24 , C07B53/00 , C07B61/00 , C07C29/145 , C07C31/125 , C07C33/18 , C07C33/20 , C07C33/22 , C07C33/40 , C07C35/08 , C07C41/20 , C07C43/23 , C07C45/62 , C07C49/403 , C07C67/303 , C07C69/24 , C07C69/612 , C07C213/00 , C07C215/68 , C07C231/12 , C07C233/47 , C07D307/42 , C07F1/08
CPC分类号： C07C29/145 , B01J31/2409 , B01J31/2452 , B01J31/2457 , B01J2231/643 , B01J2531/0266 , B01J2531/16 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C29/175 , C07C41/26 , C07C45/62 , C07C67/303 , C07C231/12 , C07C2601/14 , C07C2601/16 , C07D209/08 , C07D307/46 , C07F9/5045 , C07F9/65517 , C07C49/403 , C07C69/612 , C07C69/24 , C07C233/47 , C07C43/196 , C07C31/125 , C07C33/18 , C07C33/22 , C07C35/08 , C07C35/18
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for homogeneous hydrogenation reaction, especially a catalyst for homogeneous asymmetric hydrogenation reaction, containing an asymmetric copper complex having an asymmetric ligand useful for hydrogenation reaction, especially asymmetric hydrogenation reaction, which is relatively easily obtainable having excellent economical efficiency and workability, and to provide a method for producing a hydride of an unsaturated compound, especially an optically active compound, using the catalyst in a high yield having high optical purity.SOLUTION: There is provided the catalyst for homogeneous asymmetric hydrogenation reaction containing a mixture of an asymmetric ligand and a copper compound.
摘要翻译：要解决的问题：提供均匀氢化反应的催化剂，特别是用于均相不对称氢化反应的催化剂，其含有具有不对称配位体的不对称铜配合物，其具有可用于氢化反应的非对称配体，特别是不对称氢化反应，其相对容易获得具有优异的经济效率和可加工性，并提供使用该高催化剂的具有高光学纯度的催化剂生产不饱和化合物，特别是光学活性化合物的氢化物的方法。解决方案：提供含有不对称配体和铜化合物的混合物的均相不对称氢化反应的催化剂。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2009001545A Method for producing alcohols 审中-公开
标题翻译：生产酒精的方法
公开(公告)号：JP2009001545A
公开(公告)日：2009-01-08
申请号：JP2008114075
申请日：2008-04-24
申请人： Takasago Internatl Corp , 高砂香料工業株式会社
发明人： INO YASUNORI , YOSHIDA AKIFUMI , KURIYAMA WATARU
IPC分类号： C07C29/156 , C07B41/02 , C07B53/00 , C07B61/00 , C07C31/20 , C07C33/22 , C07C41/26 , C07C43/13 , C07C215/16 , C07C269/06 , C07C271/16 , C07D207/08 , C07F7/18
摘要： PROBLEM TO BE SOLVED: To provide a method for producing alcohols from an ester or a lactone under a comparatively mild condition in high yield and in high catalytic efficiency.
SOLUTION: The method for producing the alcohols comprises reducing the ester or the lactone with hydrogen by using a complex represented by general formula (1): Ru(H)(η1-BH
4 )(L
P
1 )(L
N
2 ) (wherein, L
P
1 is a bisphosphine ligand; and L
N
2 is a diamine ligand) as a catalyst.
COPYRIGHT: (C)2009,JPO&INPIT

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