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    • 8. 发明专利
    • Zn COMPLEX-CONTAINING LAYERED POLYMER AND ITS PRODUCTION METHOD, CALCIUM CARBONATE SYNTHESIS CATALYST, AND SYNTHETIC METHOD OF CALCIUM CARBONATE
    • Zn复合层状聚合物及其制备方法,碳酸钙合成催化剂及碳酸钙的合成方法
    • JP2007154037A
    • 2007-06-21
    • JP2005350945
    • 2005-12-05
    • Toyota Central Res & Dev Lab IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TANI MASAAKIFUKUSHIMA YOSHIAKIMATSUDA MASATOSHI
    • C08G77/26B01J31/22C01F11/18
    • PROBLEM TO BE SOLVED: To provide a synthesis catalyst of calcium carbonate and a synthetic method of calcium carbonate using the catalyst. SOLUTION: This Zn complex-containing layered polymer comprises a tetrahedron sheet where a plurality of tetrahedra having a silicon atom as the central atom are arranged and an octahedron sheet where a plurality of octahedra having a metal atom as the central atom are arranged, and the tetrahedron sheet is linked to the octahedron sheet through oxygen atoms. The layered polymer has a composition expressed by general formula (1): (R 1 n SiO (4-n)/2 ) x M 2/Z O(H 2 O) w , where R 1 s each independently represent a monovalent organic group; n denotes an integer of 1-3; x is a number of 0.5-2; Ms each independently represent a metal atom or an ion thereof; Z denotes 2 or 3; w denotes a number of 0-2; provided that at least a part of R 1 is a complex-forming organic group having a nitrogen-containing functional group capable of forming a complex with a Zn ion, where at least a part of the complex-forming organic group forms a complex with the Zn ion. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:使用该催化剂提供碳酸钙的合成催化剂和碳酸钙的合成方法。 解决方案:该含Zn络合物的层状聚合物包括布置有以硅原子为中心原子的多个四面体的四面体片和配置有以金属原子为中心原子的多个八面体的八面体片 ,四面体片通过氧原子与八面体片连接。 层状聚合物具有由通式(1)表示的组成:(R 1 SiO (4-n)/ 2 )SB 其中R 1 O(H 2 O) 各自独立地表示一价有机基团; n表示1-3的整数; x是0.5-2的数; Ms各自独立地表示金属原子或其离子; Z表示2或3; w表示0-2的数; 条件是R 1的至少一部分是具有能够与Zn离子形成络合物的含氮官能团的络合物形成有机基团,其中至少一部分复合物形成 有机基团与Zn离子形成复合物。 版权所有(C)2007,JPO&INPIT