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    • 3. 发明专利
    • Composite material of organic particles with polymetalloxane-based material and method for producing the same
    • 基于聚硅氧烷基材料的有机颗粒的复合材料及其制备方法
    • JP2007191582A
    • 2007-08-02
    • JP2006011142
    • 2006-01-19
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • WAKAYAMA HIROAKIFUKUSHIMA YOSHIAKIKAWAKAMI YUKIEIARAI YASUHIKOIWAI YOSHIOURAKAWA DAIKI
    • C08G79/00C08G77/00C12N11/08
    • Y02P20/544
    • PROBLEM TO BE SOLVED: To provide a method for producing a composite material, by which the composite material combined with a polymetalloxane-based material can be obtained, while maintaining the structure and functions of an organic compound such as a protein having a catalytic activity. SOLUTION: This method for producing the composite material of organic particles containing an organic compound with the polymetalloxane-based material is characterized by including a process for hydrolyzing and polycondensing a hydrolysable metal compound dissolved in a supercritical fluid or a semi-critical fluid in the presence of the organic particles to synthesize the polymetalloxane-based material. Since the polymetalloxane can be synthesized from the hydrolysable metal compound in the fluid as a medium, the organic particles can be combined with the polymetalloxane-based material, while reducing loads to the organic compound on its combination. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种复合材料的制造方法,通过该方法可以获得与聚氧化乙烯系材料组合的复合材料,同时保持有机化合物如具有以下成分的蛋白质的结构和功能: 催化活性。 解决方案:用于生产含有有机化合物的有机颗粒的复合材料与聚氧乙烯基材料的方法的特征在于包括将溶解在超临界流体或半临界流体中的可水解金属化合物水解和缩聚的方法 在有机颗粒存在下合成聚氧乙烯基材料。 由于聚氧乙烯可以作为介质在流体中的可水解金属化合物合成,所以有机颗粒可以与聚金属氧化物基材料组合,同时减少其组合中的有机化合物的负荷。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Three dimensional polymer complex, and porous hydrogen storage material made of same
    • 三维聚合物复合物及其多种氢储存材料
    • JP2005093181A
    • 2005-04-07
    • JP2003323522
    • 2003-09-16
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • TAKAGI HIDEKIWAKAYAMA HIROAKIFUKUSHIMA YOSHIAKIKITAGAWA SUSUMU
    • H01M8/04
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a porous hydrogen storage material having sufficiently high hydrogen storage quantity per unit weight at around room temperature, capable of storing/releasing sufficient quantity of hydrogen at low temperature, and to provide a three dimensional polymer complex useful for such a hydrogen storage material. SOLUTION: A first organic ligand expressed by formula (1), metal atom, and a second organic ligand having an atom capable of being coordinated to the metal atom capable of bidentate coordination are bonded three dimensionally to form the three dimensional polymer complex, and the porous hydrogen storage material is made of the above complex. In the formula, R denotes a heterocycle chosen from a group of tetrazene, triazine, quinoxaline, 1,5-naphthyridine, phenazine, pyridazine, pyrimidine, phthalazine, quinazoline, pyrazole, imidazole, oxazole, thiazole, quinoline, 1,9,10-Antilysin, 9a-azaphenalene, heptaazaphenalene, and perimidine, and n is an integer of 1 to 3. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供在室温附近具有足够高的每单位重量的储氢量的多孔储氢材料,能够在低温下储存/释放足量的氢,并提供三维聚合物复合物 对于这种储氢材料是有用的。 解决方案:由式(1)表示的第一有机配体,金属原子和具有能够与能够双齿配位的金属原子配位的原子的第二有机配体三维结合形成三维聚合物复合物 ,并且多孔储氢材料由上述复合物制成。 在该式中,R表示选自四嗪,三嗪,喹喔啉,1,5-萘啶,吩嗪,哒嗪,嘧啶,酞嗪,喹唑啉,吡唑,咪唑,恶唑,噻唑,喹啉,1,9,10 - 苯妥英,9a-氮杂萘林,七氮杂萘和次脒,n为1〜3的整数。版权所有(C)2005,JPO&NCIPI
    • 9. 发明专利
    • Nano-heterostructure thermoelectric material and manufacturing method of the same
    • 纳米结构热电材料及其制造方法
    • JP2013065669A
    • 2013-04-11
    • JP2011202953
    • 2011-09-16
    • Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • WAKAYAMA HIROAKIYONEKURA HIROTAKAKAWAI YASUAKI
    • H01L35/34B82Y30/00B82Y40/00H01L35/14H01L35/24H01L35/32
    • PROBLEM TO BE SOLVED: To provide a thermoelectric material having a nanostructure and excellent in thermoelectric characteristic.SOLUTION: The nano-heterostructure thermoelectric material is composed of a nano-heterostructure body, having a three-dimensional periodic structure in which an average value of a unit length of the repeated structure is 1 to 100nm, and in a matrix composed of an inorganic component selected from the group composed of a metal based thermoelectric material, a semimetal based thermoelectric material, and a metal oxide based thermoelectric material, an inorganic component selected from the group composed of the metal based thermoelectric material, the semimetal based thermoelectric material, and the metal oxide based thermoelectric material, and different from the inorganic component constituting the matrix, having a shape selected from the group composed of a spherical shape, a columnar shape, and a gyroid shaped, is arranged three-dimensionally and periodically.
    • 要解决的问题:提供具有纳米结构并且具有优异的热电特性的热电材料。 解决方案:纳米异质结构热电材料由纳米异质结构体组成,具有三维周期性结构,其中重复结构的单位长度的平均值为1〜100nm,并且在矩阵中构成 选自由金属基热电材料,半金属基热电材料和金属氧化物基热电材料组成的组中的无机组分,选自由金属基热电材料,半金属基热电材料 和金属氧化物类热电材料,并且与构成基体的无机成分不同,其具有选自球状,柱状,旋转形状的形状,三维且周期性地排列。 版权所有(C)2013,JPO&INPIT