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    • 1. 发明专利
    • Method for producing semiconductor device and apparatus for processing substrate
    • 用于生产半导体器件的方法和用于处理衬底的装置
    • JP2012251212A
    • 2012-12-20
    • JP2011124728
    • 2011-06-03
    • Hitachi Kokusai Electric Inc株式会社日立国際電気
    • HORII SADAYOSHISAITO TATSUYUKI
    • C23C16/44C23C16/14H01L21/28H01L21/285
    • PROBLEM TO BE SOLVED: To provide a substrate processing technique which can form a tungsten-containing film on a substrate with good productivity even in a hot wall type substrate processing apparatus whose reaction tube is made of quartz.SOLUTION: The method comprises a step of heating a reaction tube made of quartz under the state in which a substrate is not brought into the reaction tube and feeding a titanium-containing gas and a nitrogen-containing gas into the reaction tube to precoat the inside wall of the reaction tube with a titanium nitride film, a step of bringing the substrate into the precoated reaction tube, a step of heating the inside of the reaction tube under the state in which the substrate is brought into the reaction tube and feeding a tungsten-containing gas into the reaction tube to form a tungsten-containing film on the substrate, and a step of bringing the substrate on which the tungsten film is formed out of the reaction tube.
    • 解决的问题:提供即使在其反应管由石英制成的热壁型基板处理装置中也能以高生产率在基板上形成含钨膜的基板加工技术。 解决方案:该方法包括在基板未被引入反应管的状态下加热由石英制成的反应管并将含钛气体和含氮气体进料到反应管中的步骤, 用氮化钛膜预处理反应管的内壁,使基板进入预涂反应管的步骤,在将基板带入反应管的状态下加热反应管内部的步骤;以及 将含钨气体进料到反应管中以在基板上形成含钨膜,以及将形成有钨膜的基板从反应管中引出的步骤。 版权所有(C)2013,JPO&INPIT
    • 4. 发明专利
    • Substrate processing apparatus
    • 基板加工设备
    • JP2011222677A
    • 2011-11-04
    • JP2010088955
    • 2010-04-07
    • Hitachi Kokusai Electric Inc株式会社日立国際電気
    • TAKEBAYASHI YUJISAITO TATSUYUKIYAMAMOTO TETSUOKATO TSUTOMUOKADA ITARU
    • H01L21/31C23C16/458H01L21/22
    • PROBLEM TO BE SOLVED: To improve quality of treatment and yield by preventing difference of flow rate from increasing between a processing surface and a rim of a substrate and thereby improving uniformity of deposition processing.SOLUTION: A substrate processing apparatus has a substrate holder 18 for holding a substrate 200, a reaction tube 205 which houses the substrate and the substrate holder, gas supply systems 233a, 233b, 240a and 240b which supply processing gas in a direction parallel with the surface to be processed of the substrate, and an exhaust system 231 which exhausts the atmosphere in the reaction tube. The substrate holder has a plurality of columns 113, and a flow straightening member which is placed on the column, is an annular member for mounting the substrate, and has a notch formed in a part thereof. A distance between a circumference of the flow straightening member and an inner wall face of the reaction tube is shorter than a distance between the column and the inner wall face of the reaction tube.
    • 要解决的问题:通过防止流速与基板的加工表面和边缘之间的增加的差异来提高处理质量和产量,从而提高沉积处理的均匀性。 解决方案:基板处理装置具有用于保持基板200的基板保持件18,容纳基板和基板保持件的反应管205,供给系统233a,233b,240a和240b,沿着方向 与基板的被处理面平行的排气系统231,其排出反应管内的气氛。 衬底保持器具有多个列113,并且放置在柱上的流动矫正构件是用于安装衬底的环形构件,并且在其一部分中形成有切口。 流动矫直构件的圆周与反应管的内壁面之间的距离比反应管的内壁面和内壁面的距离短。 版权所有(C)2012,JPO&INPIT
    • 5. 发明专利
    • Method for manufacturing semiconductor device, cleaning method and substrate treatment apparatus
    • 制造半导体器件的方法,清洁方法和基板处理装置
    • JP2011068984A
    • 2011-04-07
    • JP2010154278
    • 2010-07-06
    • Hitachi Kokusai Electric Inc株式会社日立国際電気
    • SAKAI MASANORIKAGA YUKINAOYOKOGAWA TAKASHISAITO TATSUYUKI
    • C23C16/44H01L21/31H01L21/318
    • B08B7/00C23C16/4404C23C16/4405H01L21/28562H01L21/67028
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a semiconductor device, which effectively removes an electroconductive film or an insulation film; a cleaning method; and a substrate treatment apparatus. SOLUTION: This manufacturing method includes setting the following first to fourth steps as one cycle and repeating the cycle a plurality of times: the first step of carrying a substrate into a treatment chamber; the second step of supplying a plurality of source gases into the treatment chamber, and forming the electroconductive film or the insulation film on the substrate; the third step of carrying the substrate after having been treated out from the treatment chamber; and the fourth step of supplying a reforming gas in the treatment chamber, and reforming the electroconductive film or the insulation film which has been deposited in the treatment chamber; and then conducting the fifth step of supplying a cleaning gas into the treatment chamber, and removing a deposit which has been deposited in the treatment chamber and includes the reformed electroconductive film or insulation film. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种有效去除导电膜或绝缘膜的半导体器件的制造方法; 清洗方法; 和基板处理装置。 解决方案:该制造方法包括将以下第一至第四步骤设置为一个周期并重复该循环多次:将衬底运送到处理室中的第一步骤; 将多个源气体供应到处理室中的第二步骤,以及在基板上形成导电膜或绝缘膜; 在从处理室处理出之后承载基板的第三步骤; 以及在所述处理室中供给重整气体的第四步骤,对已经沉积在所述处理室中的导电膜或绝缘膜进行重整; 然后进行向处理室供给清洁气体的第五步骤,以及去除沉积在处理室中并包含重整的导电膜或绝缘膜的沉积物。 版权所有(C)2011,JPO&INPIT
    • 6. 发明专利
    • Method of manufacturing semiconductor device and substrate processing apparatus
    • 制造半导体器件和衬底加工设备的方法
    • JP2011006783A
    • 2011-01-13
    • JP2010115612
    • 2010-05-19
    • Hitachi Kokusai Electric Inc株式会社日立国際電気
    • KAGA YUKINAOSAITO TATSUYUKISAKAI MASANORI
    • C23C16/455C23C16/56H01L21/285H01L21/31
    • H01L21/28562C23C16/34C23C16/45527C23C16/45544H01L21/76841
    • PROBLEM TO BE SOLVED: To provide a dense, low-resistive metal film having a smooth film surface at a low temperature in such a manner that its quality is made better compared with a titanium nitride film formed by a CVD method and the film deposition rate is made higher compared with a titanium nitride film formed by an ALD method, i.e., at high productivity.SOLUTION: The method of manufacturing a semiconductor device includes the steps of: carrying out an alternate supply process by which a first metal film is formed on a substrate placed in a processing chamber by alternately supplying at least one type of a metal compound that is an inorganic raw material and a reactant gas that has reactivity to the metal compound to the processing chamber more than once; carrying out a simultaneous supply process by which a second metal film is formed on the substrate placed in the processing chamber by simultaneously supplying at least one type of a metal compound that is an inorganic raw material and a reactant gas that has reactivity to the metal compound to the processing chamber once so that the metal compound and the reactant gas are mixed with each other; and carrying out a modification process by which at least one of the first metal film and the second metal film is modified using at least one of the reactant gas and an inert gas after at least one of the alternate supply process and the simultaneous supply process.
    • 要解决的问题:提供一种在低温下具有光滑膜表面的致密的低电阻金属膜,使得与通过CVD法形成的氮化钛膜相比,其质量更好,并且膜沉积速率 与通过ALD法形成的氮化钛膜相比具有更高的生产率。解决方案:半导体器件的制造方法包括以下步骤:进行在第一金属膜上形成的交替供给工艺 通过交替地向所述处理室供给至少一种类型的无机原料的金属化合物和与所述金属化合物具有反应性的反应物气体而放置在处理室中的基板; 通过同时供给至少一种作为无机原料的金属化合物和与金属化合物具有反应性的反应气体,进行同时供给工序,在该基板上形成第二金属膜, 一次加工到处理室,使得金属化合物和反应气体彼此混合; 并且进行至少一个第一金属膜和第二金属膜在至少一个反应气体和惰性气体中的至少一个之后进行改性的修改方法,其中至少一个在交替供给处理和同时供给处理之中。
    • 9. 发明专利
    • Manufacturing method of semiconductor device and substrate treatment apparatus
    • 半导体器件和衬底处理设备的制造方法
    • JP2011252221A
    • 2011-12-15
    • JP2010128417
    • 2010-06-04
    • Hitachi Kokusai Electric Inc株式会社日立国際電気
    • SAITO TATSUYUKISAKAI MASANORIKAGA YUKINAOYOKOGAWA TAKASHI
    • C23C16/455H01L21/285
    • C23C16/4408C23C16/34C23C16/4412C23C16/45534C23C16/45544C23C16/52H01L21/02186H01L21/02274H01L21/0228H01L21/28562H01L21/76841
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a semiconductor device for forming a metal film which is dense and has low impurity concentration caused by a raw material and further has low resistivity, and to provide a substrate treatment apparatus.SOLUTION: A film of less than one atomic layer is formed on the surface of a substrate by performing: a first step of supplying a first raw material to a treatment chamber, in which the substrate is housed, to make the surface of the substrate adsorb the first raw material; a second step of supplying a reaction gas different from the first raw material to the treatment chamber before the adsorption of the first raw material on the substrate surface is saturated, to cause to react with the first raw material adsorbed on the substrate; a third step of removing an atmosphere within the treatment chamber; and a fourth step for supplying a modifying gas for modifying the first raw material into the treatment chamber to modify the first raw material adsorbed on the substrate.
    • 要解决的问题:提供一种用于形成致密且由原料引起的低杂质浓度的金属膜的半导体器件的制造方法,并且还具有低电阻率,并且提供一种衬底处理设备。 解决方案:通过执行以下步骤,在基板的表面上形成小于一个原子层的膜:第一步骤,将第一原料供应到容纳基板的处理室中,以使第 基板吸附第一原料; 在将第一原料吸附在基板表面上之前,将不同于第一原料的反应气体供给到处理室的第二工序饱和,与吸附在基板上的第一原料反应; 除去处理室内的气氛的第三步骤; 以及第四步骤,用于将修改气体用于将第一原料改性到处理室中以改变吸附在基材上的第一原料。 版权所有(C)2012,JPO&INPIT
    • 10. 发明专利
    • Method of manufacturing semiconductor device and substrate processing apparatus
    • 制造半导体器件和衬底加工设备的方法
    • JP2011168881A
    • 2011-09-01
    • JP2010266422
    • 2010-11-30
    • Hitachi Kokusai Electric Inc株式会社日立国際電気
    • KAGA YUKINAOSAITO TATSUYUKISAKAI MASANORIYOKOGAWA TAKASHI
    • C23C16/44
    • H01L21/32051C23C16/34C23C16/45523C23C16/45574H01L21/28556H01L21/28562
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a semiconductor device and a substrate processing apparatus capable of providing a titanium nitride film that is higher in quality than a titanium nitride film formed by the conventional CVD method at a higher film-forming rate, that is, with higher productivity than a titanium nitride film formed by an ALD (Atomic Layer Deposition) method.
      SOLUTION: The method includes: a substrate loading step for loading a substrate into a processing chamber; a film forming step for forming a predetermined film on the substrate by simultaneously supplying a first processing gas and a second processing gas into the processing chamber; a removing step for stopping the supply of the first processing gas and the second processing gas and removing the first processing gas and the second processing gas remaining in the processing chamber; a modifying step for modifying the film formed on the substrate by supplying the second processing gas into the processing chamber after the removing step; and a substrate unloading step for unloading the substrate from the processing chamber. In the film forming step, a time period for supplying the second processing gas into the processing chamber is longer than a time period for supplying the first processing gas into the processing chamber.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种半导体器件的制造方法和能够提供比通过常规CVD法形成的氮化钛膜更高质量的氮化钛膜的衬底处理设备, 形成速率,即比通过ALD(原子层沉积)方法形成的氮化钛膜具有更高的生产率。 解决方案:该方法包括:将衬底加载到处理室中的衬底加载步骤; 用于通过将第一处理气体和第二处理气体同时供给到所述处理室中而在所述基板上形成规定的膜的成膜工序; 用于停止供应第一处理气体和第二处理气体并去除残留在处理室中的第一处理气体和第二处理气体的去除步骤; 修改步骤,用于通过在去除步骤之后将第二处理气体供应到处理室中来修饰形成在基板上的膜; 以及用于从所述处理室卸载所述基板的基板卸载步骤。 在成膜步骤中,用于将第二处理气体供应到处理室中的时间段比用于将第一处理气体供应到处理室的时间段长。 版权所有(C)2011,JPO&INPIT