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1. 发明授权

EP0446078B1 Silver halide photographic materials 失效
标题翻译：摄影术Silberhalogenidmaterial
公开(公告)号：EP0446078B1
公开(公告)日：1996-10-23
申请号：EP91302002.0
申请日：1991-03-11
申请人： KONICA CORPORATION
发明人： Onodera, Akira, c/o Konica Corporation , Usagawa, Yasushi, c/o Konica Corporation
IPC分类号： G03C1/06 , G03C1/485
CPC分类号： C07D213/77 , C07C323/60 , C07C2601/14 , C07D211/46 , C07D211/58 , C07D307/66 , C07D333/36 , C07D453/02 , G03C1/061 , G03C1/48561 , Y10S430/141

2. 发明授权

EP0278666B1 Method of making a direct positive silver halide light- sensitive photographic material 失效
标题翻译：直接正感光卤化银照相材料的制造方法。
公开(公告)号：EP0278666B1
公开(公告)日：1995-04-26
申请号：EP88300889.8
申请日：1988-02-03
申请人： KONICA CORPORATION
发明人： Ogi, Keiji , Kamitakahara, Atsushi , Sakamoto, Eiichi , Isozaki, Nariko
IPC分类号： G03C1/485
CPC分类号： G03C1/48576 , Y10S430/141

3. 发明公开

EP0634691A1 Method for making direct-positive photographic images 失效
标题翻译：用于制作直接正片照相图像的方法
公开(公告)号：EP0634691A1
公开(公告)日：1995-01-18
申请号：EP93202051.4
申请日：1993-07-12
申请人： AGFA-GEVAERT naamloze vennootschap
发明人： Dewanckele, Jean-Marie , Terrell, David , Viaene, Kris
IPC分类号： G03C1/485 , C07D487/04
CPC分类号： C07D487/04 , G03C1/48538 , G03C1/48561 , Y10S430/141
摘要： The present invention relates to a method for making direct positive photographic images by developing light-sensitive materials in the presence of development nucleators which do not cause loss of sensitivity during exposure or unevenness of development. More specifically the invention relates to the formation of direct-positive images having a high maximum density and high exposure latitude and to photographic materials for use in said formation, which is accomplished by a method for making direct-positive images comprising:

image-wise exposing a photographic light-sensitive silver halide material comprising a support and a layer of an internal latent image-type silver halide emulsion, the pAg of which has been adjusted to a pAg-value between 9.0 and 10.5 inclusive before coating, and
developing said exposed photographic silver halide material in a surface developer in the presence of a development nucleator with a group promoting adsorption to silver halide.

It has been found that in a particular embodiment of this invention a development-nucleating amount of a hydrazine compound with a 7-hydroxy-s-triazolo-[1,5-a]-pyrimidine group as group promoting adsorption to silver halide is very useful.
摘要翻译：本发明涉及一种通过在存在显影成核剂的情况下显影光敏材料来制造直接正片照相图像的方法，所述显影成核剂在曝光过程中不会引起感光度损失或显影不均匀。更具体地说，本发明涉及具有高的最大密度和高曝光宽容度的直接正像的形成以及用于所述形成的照相材料的形成，其通过用于制造直接正像的方法来实现，所述方法包括：以图像方式曝光一种照相感光卤化银材料，它包括载体和一层内部潜像型卤化银乳剂，其中pAg在涂布前已经调节到9.0和10.5之间的pAg值，并且将所述曝光照相卤化银材料在具有促进对卤化银的吸附的显影成核剂存在下的表面显影剂中。已经发现，在本发明的具体实施方案中，具有7-羟基-s-三唑并[1,5-a] - 嘧啶基团作为促进对卤化银的吸附的肼化合物的显影成核量是非常有用。

4. 发明公开

EP0401846A2 A direct positive silver halide photographic light-sensitive material and a processing method therefor 失效
标题翻译：直接正型卤化银照相感光材料及其加工方法
公开(公告)号：EP0401846A2
公开(公告)日：1990-12-12
申请号：EP90110868.8
申请日：1990-06-08
申请人： KONICA CORPORATION
发明人： Yatsuyanagi, Naoko, c/o Konica Corporation , Mitsuhashi, Tsuyoshi, c/o Konica Corporation
IPC分类号： G03C1/485 , G03C1/36
CPC分类号： G03C1/48515 , Y10S430/141 , Y10S430/164
摘要： There is disclosed a direct positive silver halide light-sensitive material which can be propcessed in ultra-rapid processing and have a higher sensitivity, a lower Dmin, an excellent antistatic property and less flactuation of the preperties in storing. The light-sensitive material contains an electron-accepting compound in a silver halide emulsion layer, and a fluorinated surfactant and/or at least one of the compounds represented by Formulas I-a to II-b in a photographic component layer:
wherein R₁ to R₄ represent independently a hydrogen atom, a lower alkyl group, an alkoxy group, a carboxy group, an alkoxycarbonyl group, a sulfo group, a halogen atom, and a nitro group, provided that at least one of R₁ and R₂ is a carboxy group, an alkoxycarbonyl group or a sulfo group.
摘要翻译：公开了一种直接正性卤化银感光材料，其可以超快速处理，并且具有更高的灵敏度，更低的Dmin，优异的抗静电性能和更低的储存性能。感光材料在照相成分层中含有在卤化银乳剂层中的受电子化合物和氟化表面活性剂和/或由式Ia-II-b表示的至少一种化合物：其中R 1至R 4代表独立地为氢原子，低级烷基，烷氧基，羧基，烷氧基羰基，磺基，卤素原子和硝基，条件是R 1和R 2中至少一个是羧基，烷氧基羰基或磺基。

5. 发明公开

EP0358170A2 Direct positive photographic materials 失效
标题翻译： Photographische Direktpositivmaterialien。
公开(公告)号：EP0358170A2
公开(公告)日：1990-03-14
申请号：EP89116391.7
申请日：1989-09-05
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Shuto, Sadanobu Fuji Photo Film Co., Ltd. , Tanemura, Hatsumi Fuji Photo Film Co., Ltd. , Hirano, Shigeo Fuji Photo Film Co., Ltd.
IPC分类号： G03C1/485
CPC分类号： G03C1/48538 , Y10S430/141
摘要： A direct positive photosensitive material composed of a support having thereon at least one silver halide light-sensitive emulsion layer containing the combination of (a) non-prefogged internal latent image silver halide grains; (b) a binder; (c) at least one compound represented by formulae (I), (II) or (III); and at least one compound represented by formula (IV):
R-SO₂S-M (I)
R-SO₂S-R¹ (II)
R-SO₂S-L m -S.O₂S-R² (III)
wherein R, R¹ and R² each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group; M represents a cation; L represents a divalent linking group; and m is 0 or 1; and
R³-SO₂-M¹ (IV)
wherein R³ represents an aliphatic group, an aromatic group or a heterocyclic group; and M¹ represents a cation. The material provides a direct positive image with high Dmax, low Dmin and high contrast.
摘要翻译：一种直接正性感光材料，其由其上具有至少一种含有（a）非预成像的内部潜像卤化银颗粒的组合的卤化银感光乳剂层组成的载体构成; （b）粘合剂; （c）至少一种由式（I），（II）或（III）表示的化合物; 和至少一种由式（Ⅳ）表示的化合物：R-SO 2 S-M（I）R-SO 2 S-R 1（II）R-SO 2 S-Lm-S 2 S-R 2（III）其中R R 1和R 2各自表示取代或未取代的脂族基，取代或未取代的芳基或取代或未取代的杂环基; M表示阳离子; L表示二价连接基团; m为0或1; 和R 3 -SO 2 -M 1（IV）其中R 3表示脂族基团，芳族基团或杂环基团; M 1表示阳离子。该材料提供具有高Dmax，低Dmin和高对比度的直接正像。

6. 发明公开

EP0220042A3 Azo compound 失效
标题翻译： AZO化合物
公开(公告)号：EP0220042A3
公开(公告)日：1990-01-17
申请号：EP86307904.2
申请日：1986-10-13
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Allen, Simon , Gordon, Paul Francis , Hann, Richard Anthony
IPC分类号： C09B29/06 , G02F1/00
CPC分类号： G02F1/3612 , C09B29/0007 , G02F1/3611 , G02F1/3614 , G02F1/377 , Y10S430/141 , Y10S430/146 , Y10S534/02
摘要： (i) A compound of the formula:
wherein R is H, a metal or a group containing a tetravalent N atom;
R' is N0 2 . CN or COOY; Y is H C 1-4 -alkyl, a metal or a group containing a tetravalent N atom; R 2 & R 3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; R 4 & R 5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; and R 6 & R 7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms; or R 4 & R 6 together comprise ring fused to Ring A and R 5 & R 7 are as hereinbefore defined; or R5 & R 7 together comprise ring fused to Ring A and R 4 & R 6 are as hereinbefore defined; or R 2 & R 4 together with the N atom te which R 2 is attached form a ring fused to Ring A and R 3 & R 5 are as hereinbefore defined; or R 3 & R 5 together with the N atom to which R 3 is attached form a ring fused to Ring A and R 2 & R 4 are as hereinbefore defined; provided there are, in total, from 8 to 40 carbon atoms in one or two of the groups independently represented by R 2 . R 3 , R4 & R 5 ; (ii) an optical element comprising a compound of Formula I having non-linear optical (NLO) properties for use in the generation of NLO signals. (iii) a method of preparation of such an optical element comprising a plurality of monomolecular layers of the compound of Formula I on the surface of a transparent or reflecting substrate by a Langmuir-Blodgett technique: and (iv) an optical device incorporating such an optical element.

7. 发明公开

EP0249239A3 Process for the formation of direct positive images 失效
标题翻译：形成直接积极影像的过程
公开(公告)号：EP0249239A3
公开(公告)日：1989-06-07
申请号：EP87108489.3
申请日：1987-06-12
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Inoue, Noriyuki c/o Fuji Photo Film Co., Ltd. , Kojima, Tetsuro c/o Fuji Photo Film Co., Ltd. , Heki, Tatsuo c/o Fuji Photo Film Co., Ltd. , Hirano, Shigeo c/o Fuji Photo Film Co., Ltd.
IPC分类号： G03C1/485
CPC分类号： G03C1/48546 , G03C1/061 , G03C2001/108 , Y10S430/141
摘要： A process for the formation of direct positive images comprising (1) imagewise exposing to light, a light-sensitive material comprising a photographic emulsion layer containing unfogged internal latent image type silver halide-particles on at least one support, and (2) developing the light-sensitive material in the presence of a nucleating agent and at least one nucleation accelerator of general formula (I):
wherein A represents a group which is adsorbed by a silver halide; Y represents a divalent linkage group consisting of atoms or atomic groups selected from the group consisting of a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom; R represents an organic group containing at least one of a thioether group, an amino group, an ammonium group, an ether group, and a heterocyclic group; n represents an integer of 0 or 1; and m represents an integer of 1 or 2 to form direct position images.

8. 发明公开

EP0276842A3 Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：EP0276842A3
公开(公告)日：1989-05-10
申请号：EP88101198.5
申请日：1988-01-27
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Hirano, Shigeo , Kojima, Tetsuro , Yamamoto, Kitsuru , Inoue, Noriyuki , Heki, Tatsuo
IPC分类号： G03C1/485 , G03C1/10
CPC分类号： C07D401/04 , C07D219/02 , C07D219/04 , C07D219/06 , C07D219/08 , C07D221/12 , C07D221/16 , C07D221/18 , C07D401/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D491/04 , C07D495/04 , C07D513/04 , G03C1/067 , G03C1/48546 , Y10S430/141
摘要： A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide photographic emulsion layer, wherein at least one layer selected from the emulsion layer and other hydrophilic colloid layers contains at least one alkynyl substituted heterocyclic quaternary ammonium salt represented by the following general formula (I):
wherein Z represents a non-metallic atomic group necessary to form a substituted or unsubstituted 5- membered or 6-membered heterocyclic ring to which a aromatic ring or a heterocyclic ring may further be condensed; R I represents a substituted or unsubstituted aliphatic group; X represents = C -or - N -; Q represents a non-metallic atomic group necessary to form a substituted or unsubstituted 4-membered to 12- membered non-aromatic hydrocarbon ring or substituted or unsubstituted non-aromatic heterocyclic ring; at least one of R 1 , a substituent for Z and a substituent for Q includes an alkynyl group; Y represents a counter ion necessary for charge balance; and n represents a number necessary to balance the charge.
摘要翻译： 1，一种卤化银照相材料，其特征在于它包括一个在其上具有至少一层光敏卤化银照相乳剂层的载体，其中至少一层选自乳剂层和其它亲水胶体层的层含有至少一种由（I）表示：其中Z表示形成可以进一步稠合芳族环或杂环的取代或未取代的5元或6元杂环所必需的非金属原子团; RI表示取代或未取代的脂族基团; X代表= C-或 - N-; Q表示形成取代或未取代的4元至12元非芳族烃环或取代或未取代的非芳族杂环所必需的非金属原子团; R1，Z的取代基和Q的取代基中的至少一个包括炔基; Y表示电荷平衡所需的抗衡离子; 而n代表平衡收费所需的数字。

9. 发明公开

EP0176325A3 Light sensitive silver halide color photographic material 失效
标题翻译：感光银色彩色摄影材料
公开(公告)号：EP0176325A3
公开(公告)日：1986-06-18
申请号：EP85306689
申请日：1985-09-19
申请人： KONISHIROKU PHOTO INDUSTRY CO. LTD.
发明人： Michiue, Kenji , Yagi, Toshihiko , Yamazaki, Katsumasa , Goto, Sohei , Mochizuki, Yoshiharu
IPC分类号： G03C07/26
CPC分类号： G03C7/3022 , Y10S430/141
摘要： Diclosed is a light-sensitive silver halide color photographic material comprising a support and a plurality of silver halide emulsion layers on the support, the emulsion layers being substantially identical in color sensitivity but different in sensitivity and containing at least one of a dye image-forming coupler, characterized in that silver halide grains contained in at least one layer of the plurality of silver halide emulsion layers consist substantially of monodispersed silver halide grains, a color concentration of the emulsion layer comprising the monodispersed silver halide grains being within the range of 60 to 98% of the total color concentration of the plurality of silver halide emulsion layers. The employment of the monodispersed silver halide grains of this invention and the increase in a concentration of the grains in the emulsion layers permit the improvement of graininess, the enlargement of exposure range and the betterment of stability to processing and stability with time.

10. 发明公开

EP0107302A2 Silver halide emulsions and process for preparing the same 失效
标题翻译：卤化银乳剂和其制备过程。
公开(公告)号：EP0107302A2
公开(公告)日：1984-05-02
申请号：EP83305112.1
申请日：1983-09-02
申请人： KONICA CORPORATION
发明人： Matsuzaka, Shoji , Kajiwara, Makoto , Miyoshi, Masanobu , Yamashita, Kiyoshi
IPC分类号： G03C1/02
CPC分类号： G03C1/015 , G03C2001/03535 , G03C2001/0357 , Y10S430/141
摘要： Improved process for preparing silver chlorobromide or silver chloroiodobromide emulsion wherein first silver ion solution and second halide ion solution are mixed by double jet method and mole % of silver bromide, silver chloride and silver iodide are in specified range, characterized in that molar ratio of Br - :Cℓ - :I in second solution is within specified range and further step is included to produce silver halide with control of silver ion concentration by using third solution containing Br- and C ℓ- . Such emulsions have sufficiently narrow grain diameter distribution and silver halide composition distribution, with constant productivity.

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