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1. 发明公开

EP0234751A3 Non-linear optical device 失效
标题翻译：非线性光学器件
公开(公告)号：EP0234751A3
公开(公告)日：1988-06-15
申请号：EP87300731
申请日：1987-01-28
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Allen, Simon , Gordon, Paul Francis , Morley, John Oswald
IPC分类号： G02F01/35 , C07C149/42
CPC分类号： G02F1/3613 , G02F1/3611 , G02F1/3612
摘要： Optical elements comprising a non-centrosymmetric compound comprising an electron donor and an electron acceptor linked by a conjugated bridging group, in which the electron acceptor is a nitroso groups, in which element the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and some of the compounds.

2. 发明公开

EP0240106A2 Non-linear optical elements and compounds 失效
标题翻译： Nicht-lineare optische Elemente und Verbindungen。
公开(公告)号：EP0240106A2
公开(公告)日：1987-10-07
申请号：EP87300730.6
申请日：1987-01-28
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Allen, Simon , Gordon, Paul Francis , Morley, John Oswald
IPC分类号： G02F1/35 , C07D231/06 , G02B6/10 , C07D207/20 , C07D207/22
CPC分类号： G02F1/3612 , C09K19/54 , C09K19/586 , G02F1/065
摘要： Optical elements having non-linear optical properties comprising a compound of the formula:
wherein
D is an electron donor
A is an electron acceptor;
& W, X, Y & Z are each independently H or any group capable of attachment to the pyrazolyl ring; in which the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and compounds of formula I.
摘要翻译：具有非线性光学特性的光学元件包括下式化合物：其中D是电子给体A的电子受体; ＆amp; W，X，Y和Z各自独立地为H或能够连接到吡唑基环的任何基团; 其中化合物的分子对准，使得元件具有净非中心对称性，其制备方法，包含这些元素的光学器件和式I化合物。

3. 发明公开

EP0186404A3 Optical recording medium 失效
标题翻译：光学记录介质
公开(公告)号：EP0186404A3
公开(公告)日：1987-06-24
申请号：EP85309134
申请日：1985-12-16
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC , TDK CORPORATION
发明人： Duggan, Peter John , Gordon, Paul Francis , Abbott, Stephen John , Kuroiwa, Akihito , Aoi, Toshiki , Kamijo, Tezumbumi
IPC分类号： G11B07/24
CPC分类号： G11B7/248 , Y10S430/146 , Y10S430/165
摘要： @ A pit-forming optical recording medium comprises a substrate supporting a film of optically deformable recording material comprising an organic dye for absorbing optical signals of modulated electromagnetic radiation applied to the film and thereby causing corresponding deformations of the film when the signal intensities exceed predetermined threshold levels. The dye is a phthalocyanine compound or mixture of phtalocyanine compounds in which each of at least five of the peripheral carbon atoms in the 1, 4, 5, 8, 9, 12, 13 or 16 positions (the "3,6-positions") of the phthalocyanine nucleus, as shown in Formula 1, is linked by an atom from group VB or Group VIB of the Periodic Table to a carbon atom of an organic radical. In preferred compounds each of the eight, 3,6-positions is linked by an atom from Group VB or Group VIB, especially sulphur, selenium or nitrogen, to an organic radical.
摘要翻译：形成凹坑的光学记录介质包括支撑包含有机染料的光学可变形记录材料膜的基板，所述有机染料用于吸收施加到膜上的调制电磁辐射的光学信号，并由此在信号强度超过预定阈值时引起膜的相应变形水平。染料是酞菁化合物或酞菁化合物的混合物，其中1,4,5,8,9,12,13或16位中的至少五个外围碳原子中的每一个（“3,6-位” ）的酞菁核通过来自元素周期表的VB族或VIB族的原子与有机基团的碳原子连接，如式1所示。在优选的化合物中，8位，3,6-位各自通过来自VB族或VIB族的原子，尤其是硫，硒或氮与有机基团连接。

4. 发明公开

EP0244051A3 Non-linear optical elements and compounds therefor 失效
标题翻译：非线性光学元件及其化合物
公开(公告)号：EP0244051A3
公开(公告)日：1989-01-18
申请号：EP87300729.8
申请日：1987-01-28
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Allen, Simon , Gordon, Paul Francis , Morley, John Oswald
IPC分类号： G02F1/35 , C07C121/66 , G02B6/10 , G02B5/30 , C07C95/08 , C07C121/70 , C07C87/62 , C07C119/042 , C07C101/453 , C07C97/10 , C07C47/277
CPC分类号： C07D295/073 , B82Y20/00 , C09K19/52 , G02F1/3611 , G02F1/3618
摘要： Optical element comprising a non-centrosymmetric compound comprising an electron donor and an electron acceptor other than one which is or comprises the group -NO linked through a conjugated alka-(polyene)-ylene bridging group containing at least three pairs of conjugated single and double bonds in which the the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and some of the compounds.

5. 发明公开

EP0268354A3 Substituted pyrazoline 失效
标题翻译：取代的吡咯烷酮
公开(公告)号：EP0268354A3
公开(公告)日：1988-06-15
申请号：EP87307975
申请日：1987-09-09
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Gordon, Paul Francis , Bothwell, Brian David
IPC分类号： C07D231/06 , C09K19/34 , G02F01/35
CPC分类号： C07D231/06 , C09K19/3483 , G02F1/3612
摘要： A compound of the formula:
wherein
E is an ethenyl group of the formula:
in which
X is H when Y is NO₂;
Y is H when X is NO₂; or
X is CN when Y is CN
which has the capacity to form a crystal in which the molecules are aligned substantially in the same manner giving it non-linear optical properties. The cyrstalline product is thus adapted for use in devices exhibiting non-linear optical effects.

6. 发明公开

EP0268354A2 Substituted pyrazoline 失效
标题翻译：取代吡唑啉。
公开(公告)号：EP0268354A2
公开(公告)日：1988-05-25
申请号：EP87307975.0
申请日：1987-09-09
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Gordon, Paul Francis , Bothwell, Brian David
IPC分类号： C07D231/06 , C09K19/34 , G02F1/35
CPC分类号： C07D231/06 , C09K19/3483 , G02F1/3612
摘要： A compound of the formula:
wherein
E is an ethenyl group of the formula:
in which
X is H when Y is NO₂;
Y is H when X is NO₂; or
X is CN when Y is CN
which has the capacity to form a crystal in which the molecules are aligned substantially in the same manner giving it non-linear optical properties. The cyrstalline product is thus adapted for use in devices exhibiting non-linear optical effects.
摘要翻译：下式的化合物，其中E是下式的乙烯基：其中当Y是NO 2时X是H; 当X为NO2时，Y为H; 或者当Y为CN时，X为CN，其具有形成其中分子基本上以相同方式排列的晶体的能力，得到非线性光学性质。因此，cyrstalline产品适用于显示非线性光学效果的装置。

7. 发明公开

EP0135995A1 Metal dithiene derivatives and a process for preparing them 失效
标题翻译： Dithienderivate和它们的制备的方法含金属。
公开(公告)号：EP0135995A1
公开(公告)日：1985-04-03
申请号：EP84304777.0
申请日：1984-07-12
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Gordon, Paul Francis , Thompson, David John , McDonnel, Damian Gerard , Hughes, Anthony James
IPC分类号： C07C149/267 , C07C149/273 , C09K19/40
CPC分类号： C09K19/40 , C07C321/00 , C07C323/00
摘要： A metal dithiene of the formula:
wherein R 1 is C 3 to C 20 alkyl;

R 2 is selected from alkyl, alkylamino, dialkylamino, alkylthio and alkoxy in which each alkyl contains up to 20 carbon atoms;
R 3 is H, halogen or a group represented by R 2 ; and
M is a metal selected from Groups Ib, Ilb, Vllb, and Vlllb of the Periodic Table, and a composition of the metal dithiene in a liquid crystal medium. The composition is suitable for use in a light valve for a laser-addressed liquid crystal display.

8. 发明公开

EP0293093A2 Azo Compound 失效
标题翻译： Nichtlineares优化元素。
公开(公告)号：EP0293093A2
公开(公告)日：1988-11-30
申请号：EP88303953.9
申请日：1988-04-29
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC , CENTRE NATIONAL d'ETUDES DES TELECOMMUNICATIONS
发明人： Allen, Simon , Gordon, Paul Francis , Zyss, Joseph
IPC分类号： G02B1/00 , C09B29/085 , C09B29/36
CPC分类号： B82Y20/00 , C09B29/0003 , C09B29/0807 , C09B29/0816 , C09B29/36 , G02F1/3132 , G02F1/3618 , Y10S534/02
摘要： An optical element, such as a wave guide, having non-linear optical properties, suitable for use in optical devices in which it is desirable to alter the characteristics of the light, comprising a transparent or reflecting substrate having at least a partial superficial coating comprising alternating monolayers of a first non-linear optical (NLO) compound of the formula:
wherein
R is an non-hydrophilic aliphatic or cycloaliphatic group containing from 8 to 40 carbon atoms;
m is 1 or 2;
R¹ is NO₂, CN or COOR²;
R² is H or C₁₋₄-alkyl;
n is from 1 to 4
and R³ is H, a metal or a group containing a tetravalent N atom and a second NLO compound of the formula:
wherein T is H, a metal or a group containing a tetravalent N atom;
T¹ is NO₂, CN or COOY;
Y is selected from H, C₁₋₄-alkyl, a metal or a group containing a tetravalent N atom;
T² & T³ are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;
T⁴ & T⁵ are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;
and T⁶ & T⁷ are each independently H or a non-hydrophilic group containing up to 4 carbon atoms;
or T⁴ & T⁶ together comprise ring fused to Ring A and T⁵ & T⁷ are as hereinbefore defined;
or T⁵ & T⁷ together comprise ring fused to Ring A and T⁴ & T⁶ are as hereinbefore defined;
or T² & T⁴ together with the N atom to which T² is attached from a ring fused to Ring A and T³ & T⁵ are as hereinbefore defined;
or T³ & T⁵ together with the N atom to which T³ is attached from a ring fused to Ring A and T² & T⁴ are as hereinbefore defined;
provided there are, in total, from 8 to 40 atoms in one or two of the groups independently represented by T², T³, T⁴ & T⁵.
摘要翻译：具有非线性光学性质的光学元件，例如波导，适用于期望改变光的特性的光学装置，包括具有至少部分表面涂层的透明或反射基板，其包括交替单层下式的第一非线性光学（NLO）化合物：其中R是含有8至40个碳原子的非亲水脂族或脂环族基团; m为1或2; R 1是NO 2，CN或COOR 2; R 2是H或C 1-4 - 烷基; n为1至4，R 3为H，金属或含有四价N原子的基团和下式的第二NLO化合物：其中T为H，金属或含有四价N 原子; T 1是NO 2，CN或COOY; Y选自H，C 1-4 - 烷基，金属或含有四价N原子的基团; T 2和T 3各自独立地为H或含有至多30个碳原子的非亲水脂族或脂环族基团; T 4和T 5各自独立地为H或含有至多30个碳原子的非亲水性脂族或脂环族基团; 和T 6＆amp; T 7各自独立地为H或含有至多4个碳原子的非亲水基团; 或T 4和T 6一起包含与环A稠合的环，T 5和T 7如上文所定义; 或T 5和T 7一起包含与环A稠合的环，并且T 4和T 6如上文所定义; 或T 2和T 4连同与环A稠合的环和T 3和T 5连接的T 2连接的N原子如上文所定义; 或T 3和T 5连同与环A稠合的环与T 3连接的N原子，T 2和T 4如上文所定义; 条件是在T 2，T 3，T 4和T 5独立地表示的一个或两个基团中总共有8至40个原子。

9. 发明公开

EP0292139A1 Azo compound 失效
标题翻译： Azoverbindungen。
公开(公告)号：EP0292139A1
公开(公告)日：1988-11-23
申请号：EP88303956.2
申请日：1988-04-29
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Allen, Simon , Gordon, Paul Francis
IPC分类号： C07C245/08 , C07C255/50 , C07C255/49 , C09K19/24 , G02F1/13
CPC分类号： G02F1/3611 , C07C245/08 , C09B29/0003 , C09B29/0816 , C09K19/24 , C09K19/601
摘要： An azo compound of the formula:
wherein
R is an non-hydrophilic aliphatic or cycloaliphatic group containing from 8 to 40 carbon atoms;
m is 0 or 1;
R¹ is NO₂, CN or COOR²;
R² is H or C₁₋₄-alkyl;
n is from 1 to 4
and R³ is H, a metal or a group containing a tetravalent N atom.
The compoound has non-linear optical properties which make it suitable for use in an optical element such as a waveguide, for altering the characteristics of light passing through the element.
摘要翻译：下式的偶氮化合物：其中R是含有8至40个碳原子的非亲水脂族或脂环族基团; m为0或1; R 1是NO 2，CN或COOR 2; R 2是H或C 1-4 - 烷基; n为1〜4，R 3为H，金属或含有四价N原子的基团。该组合物具有非线性光学性质，其使其适用于诸如波导的光学元件，用于改变穿过元件的光的特性。

10. 发明公开

EP0234751A2 Non-linear optical device 失效
标题翻译：非线性光学器件。
公开(公告)号：EP0234751A2
公开(公告)日：1987-09-02
申请号：EP87300731.4
申请日：1987-01-28
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Allen, Simon , Gordon, Paul Francis , Morley, John Oswald
IPC分类号： G02F1/35 , C07C323/01 , C07C207/00
CPC分类号： G02F1/3613 , G02F1/3611 , G02F1/3612
摘要： Optical elements comprising a non-centrosymmetric compound comprising an electron donor and an electron acceptor linked by a conjugated bridging group, in which the electron acceptor is a nitroso groups, in which element the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and some of the compounds.

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