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    • 1. 发明公开
    • Method of forming dye image having superior rapid processing performance
    • 形成具有超快速加工性能的染色体图像的方法
    • EP0255784A3
    • 1988-11-17
    • EP87306842
    • 1987-07-31
    • KONICA CORPORATION
    • Miyoshi, MasanobuKajiwara, MakotoOnodera, KaoruSakamoto, Eiichi
    • G03C07/26G03C01/30
    • G03C7/3924G03C1/305Y10S430/164
    • A method of forming a dye image comprising;
          a step of imagewise exposing a light-sensitive silver halide photographic material which comprises a
          support and, provided thereon, at le­ast one silver halide emulsion layer comprising silver halide grains containing 90 mole % or more of silver chloride, a dye-forming coupler and a compound of formula [S];
      wherein Q₁ is a group which, together with the carbon and nitrogen to which it is attached, completes a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring; and M is hydrogen, an alkali metal or ammonium;
      the silver halide emulsion layer having been hardened by a hardener of formula [HDA] or [HDB];
      wherein Rd₁ is chlorine, hydroxyl, alkyl, alkoxy, alkylthio, -OM₁ wherein M₁ is a monovalent metal, -NRʹRʺ wherein Rʹ and Rʺ are, independently hydrogen, alkyl or aryl, or -NHCOR‴ in which R‴ is hydrogen alkyl or aryl, and Rd₂ is, independently, as defined for Rd₁ with the exception of chlorine; Wherein Rd₃ and Rd₄ are, independently, chlorine, hydroxyl, alkyl, alkoxy or -OM₂ in which M₂ is a monovalent meta; Q₂ and Qʹ₂ are independently, -0-, -S- or -NH-; L in alkylene or arylene; and p and q are, independently, 0 or 1; and
          a step of processing the imagewise exposed photographic material with a color developing solution which comprises from 2 × 10⁻⁴ to 1 × 10⁻² mole/liter sulfite ions and is substantially free of bromide ions.
    • 2. 发明公开
    • Light-sensitive silver halide color photographic material
    • 感光银色彩色摄影材料
    • EP0214832A3
    • 1988-10-05
    • EP86306780
    • 1986-09-02
    • KONICA CORPORATION
    • Inoie, HiroshiIshikawa, MinoruShimazaki, HiroshiSuzuki, KatutoyoHamada, FumioYagi, Toshihiko
    • G03C07/32G03C07/26
    • G03C7/3003G03C7/3022G03C7/30594
    • There is disclosed a light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least one of the light-sensitive silver halide emulsion layer comprises monodispersed silver halide grains containing 8 to 30 mole % of silver halide in core or contains twinned crystal silver halide grains, at least two of the light-sensitive silver halide emulsion layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or developing inhibitor precursor through the reaction with the oxidized product of a developing agent, the developing inhibitor or developing inhibitor precursor released from the DIR compound being diffusive, wherein the following conditions A: DIR compounds are added and incorporated in the emulsion layers so that the developing inhibitor released from the DIR compound incorporated in one color-sensitive silver halide emulsion layer and the developing inhibitor released from the DIR compound incorporated in the other color-sensitive silver halide emulsion layer are reversed in developing inhibiting power when the DIR compounds to be incorporated in the respective light-sensitive silver halide emulsion layers are exchanged with each other, and also each DIR compound may have greater inhibiting power for the other light-sensitive silver halide emulsion layer rather than for the light-sensitive silver halide emulsion layer in which it is incorporated, is satisfied for the at least two light-sensitive silver halide emulsion layers different in color sensitivities.
    • 3. 发明公开
    • Silver halide color photographic materials
    • 卤化银彩色照相材料
    • EP0250723A3
    • 1988-09-28
    • EP87104526
    • 1987-03-26
    • FUJI PHOTO FILM CO., LTD.
    • Mihayashi, Keiji Fuji Photo Film Co., Ltd.Ohki, Nobutaka Fuji Photo Film Co., Ltd.
    • G03C07/26C07C103/78
    • G03C7/39216
    • A silver halide color photographic material having low color stain and colorfog, which contains at least one substantially colorless compound selected from the group consisting of compounds represented by formula (I)
      and alkaline unstable precursors thereof, bis, tris and tetrakis compounds derived from the compound, and polymers derived from the compound; wherein R 1 and R 2 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl, acylamino, alkoxy, aryloxy, alkylthio, arylthio, sulfonyl, carbamoyl, or sulfamoyl group; or R' and R 2 together form a carbocyclic ring; R 3 represents a hydrogen atom or an alkyl group; and R 4 , R 5 , R 6 , R 7 , and R 8 each represents a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, or a substituted or unsubstituted alkyl, acylamino, sulfonamido, alkoxy, aryloxy, alkylthio, arylthio, amino, acyl, acyloxy, carbamoyl, carbamoylamino, carbamoyloxy, sulfamoyl, sulfamoylamino, alkoxycarbonyl, aryloxycarbonyl, alkoxycarbonylamino, aryloxycarbonylamino, alkoxycarbonyloxy, aryloxycarbonyloxy, heterocyclic ring, alkoxysulfonyl or aryloxysulfonyl group; or two adjacent groups together form a carbocyclic ring or a heterocyclic ring; the sum of the carbon atom number of R 1 to R 8 is at least 8; and the compound of formula (1) is substantially insoluble in water and does not form a color image by coupling reaction with an oxidized product of a developing agent.
    • 一种具有低色斑和色雾的卤化银彩色照相材料,它含有至少一种选自式(Ⅰ)化合物和其碱性不稳定前体的基本上无色的化合物,由化合物衍生的二,三和四化合物 和由该化合物衍生的聚合物; 其中R1和R2各代表氢原子,卤素原子,取代或未取代的烷基,酰氨基,烷氧基,芳氧基,烷硫基,芳硫基,磺酰基,氨基甲酰基或氨磺酰基; 或者R'和R2一起形成碳环; R3代表氢原子或烷基; R 4,R 5,R 6,R 7和R 8各自代表氢原子,卤素原子,羟基,氰基,硝基或取代或未取代的烷基,酰氨基,亚磺酰氨基,烷氧基,芳氧基,烷硫基, 氨基甲酰基,氨基甲酰基氨基,氨基甲酰基氧基,氨磺酰基,氨磺酰基氨基,烷氧基羰基,芳氧基羰基,烷氧基羰基氨基,芳氧基羰基氨基,烷氧基羰氧基,芳氧基羰氧基,杂环,烷氧基磺酰基或芳氧基磺酰基; 或两个相邻的基团一起形成碳环或杂环; R1至R8的碳原子数之和至少为8; 并且式(1)化合物基本上不溶于水,并且不会通过与显影剂的氧化产物偶联反应而形成彩色图像。
    • 5. 发明公开
    • Color photographic light-sensitive material
    • 彩色照相感光材料
    • EP0127162A3
    • 1987-02-25
    • EP84106000
    • 1984-05-25
    • FUJI PHOTO FILM CO., LTD.
    • Sakai, NobuoOkazaki, MasakiInagaki, Yoshio
    • G03C07/26G03C07/38C07D251/54C07D231/48
    • C07D231/48C07D251/50C07D251/70G03C7/3012G03C7/38G03C7/3924
    • A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having at least one layer containing at least one 2-equivalent magenta coupler of the 5-pyrazolone type represented by the following general formula (I):
      wherein W represents a phenyl group substituted with at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z represents a group capable of being released upon coupling, and at least one compound represented by the following general formula (II):
      wherein R' and R Z , which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group, provided that both R' and R' do not represent hydrogen atoms atthe same time; Z' represents a methine group, a substituted methine group orthe group-N=; and Q represents an atomic group which contains a nitrogen atom, a sulfur atom or an oxygen atom and is necessary to form a 5-membered ora 6-membered heterocyclic ring together with the group-C=Z 1 -. The silver halide color photographic light-sensitive material can provide an excellent magenta color image without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.
    • 1,一种卤化银彩色摄影感光材料,它包括一个载有至少一层卤化银乳剂层的载体,该彩色摄影感光材料至少有一层含有至少一种5-吡唑啉酮型的2当量品红成色剂 (I)表示:其中W表示被至少一个选自卤素原子,烷基,烷氧基,烷氧基羰基和氰基的取代基取代的苯基; Y代表酰氨基或苯胺基; Z表示能够在偶联时释放的基团,以及至少一种由以下通式(II)表示的化合物:其中R'和RZ可以相同或不同,各自表示氢原子,烷基 或芳基,条件是R'和R'两者不同时代表氢原子; Z'表示次甲基,取代的次甲基或N = Q表示含有氮原子,硫原子或氧原子的原子团,并且与基团-C = Z1-一起形成5元或6元杂环所必需的基团。 卤化银彩色照相感光材料即使在彩色照相材料在运行条件下在处理液中处理时,也可以提供优异的品红色彩色图像而不会发生色斑。