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    • 6. 发明公开
    • Silver halide photographic material
    • 卤化银照相材料
    • EP0303301A3
    • 1989-05-17
    • EP88113272.4
    • 1988-08-16
    • FUJI PHOTO FILM CO., LTD.
    • Hirano, Shigeo Fuji Photo Film Co., Ltd.Kobayashi, Hidetoshi Fuji Photo Film Co., Ltd.Deguchi, Naoyasu Fuji Photo Film Co., Ltd.Inoue, Noriyuki Fuji Photo Film Co., Ltd.
    • G03C7/32
    • G03C7/305G03C1/48538
    • A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer thereof containing at least one compound capable of releasing a foggant represented by formula (M-1) or (M-2) by a coupling reaction or a redox reaction with the oxidation product of a developing agent under alkaline conditions during development:
      (M-1) A - (L)ℓ - Q'
      in which A represents a group to accelerate adsorbing to silver halide; L represents a divalent linking group; ℓ is 0 or 1; and Q' represents a group derived from a quaternary salt nucleating agent represented by formula Q, by removing any hydrogen redical therefrom:
      where Z represents a substituted or unsubstituted non-metallic atomic group necessary for forming a 5- or 6-membered hetero-ring; R' represents a substituted or unsubstituted aliphatic group; R 2 represents hydrogen, a substituted or unsubstituted aliphatic group or substituted or unsubstituted and aromatic group, R 2 may be linked to Z to form a ring; provided that at least one of R', R 2 and Z contains an alkyl group, an acyl group, a hydrazine group or a hydrazone group, or R' and R 2 are linked to form a 6-membered dihydropyridinium ring; Y represents a counter ion necessary for charge balance; and n is 0 or 1; and

      in which R m1 represents a divalent atomic group; R m2 represents hydrogen, an alkyl group, an aralkyl group, an aryl group, an alkoxy group, an aryloxy group or an amino group; G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group or an iminomethylene group; one of R m3 and R m4 is hydrogen, and the other hydrogen, an alkylsulfonyl group, an arylsulfonyl group or an acyl group; A represents a group accelerate the adsorbing to a silver halide; L represents a divalent linking group; and t is 0 or 1. The material forms a direct positive image with a high maximum image density and a high resolving power. The material has a high storage stability even under high temperature and high humidity.
    • 一种卤化银照相材料,由其上至少有一层感光卤化银乳剂层的载体组成,其至少一层含有至少一种能释放由式(M-1)或(M-2)表示的雾化剂的化合物 ):在显影过程中在碱性条件下通过与显影剂的氧化产物进行偶联反应或氧化还原反应:(M-1)A-(L)l-Q'其中A表示加速吸附至卤化银的基团; L代表二价连接基团; ℓ是0或1; 并且Q'表示由式Q表示的季盐成核剂衍生的基团,通过除去任何来自其的氢:其中Z表示形成5或6元杂环所需的取代或未取代的非金属原子团 ; R'表示取代或未取代的脂族基团; R2代表氢,取代或未取代的脂族基团或者取代或未取代的芳族基团,R2可以与Z连接形成环; 条件是R 1,R 2和Z中的至少一个含有烷基,酰基,肼基或腙基,或者R'和R 2连接形成6元二氢吡啶鎓环; Y表示电荷平衡所需的抗衡离子; 并且n是0或1; 并且其中Rm1表示二价原子团; Rm2表示氢,烷基,芳烷基,芳基,烷氧基,芳氧基或氨基; G表示羰基,磺酰基,亚磺酰基,磷酰基或亚氨基亚甲基; Rm3和Rm4中的一个是氢,另一个是氢,烷基磺酰基,芳基磺酰基或酰基; A代表一个基团加速了对卤化银的吸附; L代表二价连接基团; 并且t是0或1.该材料形成具有高的最大图像密度和高分辨率的直接正像。 该材料即使在高温和高湿度下也具有高储存稳定性。
    • 7. 发明公开
    • Method for common development processing of two kinds of light-sensitive silver halide photographic material
    • 一种用于两种光敏感的卤化银照相材料的共同发展处理方法。
    • EP0269227A2
    • 1988-06-01
    • EP87308820.7
    • 1987-10-06
    • KONICA CORPORATION
    • Ishikawa, MasaoKoboshi, ShigeharuKuse, SatoruKobayashi, Kazuhiro
    • G03C7/30G03C7/26G03C1/485
    • G03C1/48538G03C7/39292G03C7/413
    • There is disclosed a method for common development processing of two kinds of light-sensitive silver halide photographic material which comprises the step of development processing an internal latent type direct positive light-sensitive silver halide photographic material and a negative-type light-sensitive silver halide photographic material in the same development processing bath, and the step of applying whole surface exposure on the internal latent type direct positive light-sensitive silver halide photogrpahic material during development processing of the internal latent type direct positive light-sensitive silver halide photographic material, characterized in that the developing processing solution contains a compound represented by the formula (A) shown below:
      wherein R 1 and R 2 each represent hydrogen atom or an alkyl group having 1 to 5 carbon atoms which may have a substituent or may be combined with each other to form a heteroxyclic ring.
    • 有圆盘游离缺失对于两种光敏感的卤化银照相材料的共同显影处理方法,其包括显影处理银中的内部潜型直接正性光敏卤化银照相材料的步骤和负型光敏卤化 照相材料在相同的显影处理浴中,使内部潜型直接正性光敏卤化银照相材料的显影处理过程中在内部潜型直接正性光敏卤化银photogrpahic材料涂覆整个表面曝光的步骤,其特征在于 DASS DER显影处理溶液含有如下所示的式(A)表示的化合物:worin R1和R2各自代表氢原子或烷基,其可以具有取代基或可结合基具有1至5个碳原子 海誓山盟形成环heteroxyclic。