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1. 发明公开

EP0439041A1 Direct positive photographic material 失效
标题翻译： Photographisches Direktpositivmaterial。
公开(公告)号：EP0439041A1
公开(公告)日：1991-07-31
申请号：EP91100369.7
申请日：1991-01-14
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Inoue, Noriyuki
IPC分类号： G03C1/485
CPC分类号： G03C1/48538 , G03C2001/0845 , G03C2001/093 , G03C2001/094 , G03C2200/59
摘要： Disclosed is a direct positive photographic material comprising a support having thereon at least one photographic emulsion layer containing previously non-fogged internal latent image-type silver halide grains, wherein the photographic emulsion layer contains at least one compound of formulae (I), (II) and (III) preferably along with at least one compound of formulae (IV), (V) and (VI), and that the internal latent image-type silver halide grains are silver bromide, silver chloride, silver iodobromide, silver chlorobromide or silver chloroiodobromide grains and contain at least one metal of manganese, copper, zinc, cadmium, rhenium, lead, bismuth, indium, thallium, zirconium, lanthanum, chromium, mercury and metals of Group VIII of the Periodic Table.

(I) M₂SO₃

(II) MHSO₃

(III) M₂S₂O₅

wherein M represents a hydrogen atom or a cation.

(IV) R-SO₂S-M¹

(V) R-SO₂S-R¹

(VI) R-SO₂S-L m -S·O₂S-R²

wherein R, R¹ and R² which may be the same or different, each represents an aliphatic, aromatic or heterocyclic group, M¹ represents a cation, L represents a divalent linking group, and m is 0 or 1. The material provides a hard direct positive image having a lowered minimum image density without lowering the maximum image density and it has a high time-dependent storage stability.
摘要翻译：公开了一种直接正型照相材料，其包括其上具有至少一个包含预先未雾化的内部潜像型卤化银颗粒的照相乳剂层的支持体，其中照相乳剂层含有至少一种式（I），（II ）和（III）优选与至少一种式（IV），（V）和（VI）的化合物一起，并且内部潜像型卤化银颗粒是溴化银，氯化银，碘溴化银，氯溴化银或氯碘溴化银颗粒，并含有元素周期表第八族中的锰，铜，锌，镉，铼，铅，铋，铟，铊，锆，镧，铬，汞和金属中的至少一种金属。（I）M2SO3（II）MHSO3（Ⅲ）M2S2O5，其中M表示氢原子或阳离子。（IV）R-SO 2 S-M 1（V）R-SO 2 S-R 1（Ⅵ）R-SO 2 S-Lm-S 2 S-R 2其中R，R 1和R 2 其可以相同或不同，各自表示脂族，芳族或杂环基团，M 1表示阳离子，L表示二价连接基团，m表示0或1.该材料提供硬直接正像，其具有降低的最小图像密度而不降低最大图像浓度，并且其具有高的时间依赖性存储稳定性。

2. 发明公开

EP0267482A3 Direct positive color photosensitive material 失效
标题翻译：直接的积极色彩感光材料
公开(公告)号：EP0267482A3
公开(公告)日：1990-11-22
申请号：EP87115689.9
申请日：1987-10-26
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Heki, Tatsuo , Sakai, Nobuo , Inoue, Noriyuki
IPC分类号： G03C1/485 , G03C7/34
CPC分类号： G03C7/346 , G03C1/48538
摘要： A direct positive color photosensitive material comprised of a support having thereon at least one photographic emulsion layer containing nonprefogged internal latent image silver halide grains and at least one nondiffusible cyan coupler represented by formula (C-I):
in which R 1 represents an aliphatic group, an aromatic group, a heterocyclic group, an aromatic amino group or a heterocyclic amino group; R 2 represents an aliphatic group containing 2 to 20 carbon atoms; R 3 represents a hydrogen atom, a halogen atom, an aliphatic group, an aliphatic oxy group or an acylamino group; and Y 1 represents a hydrogen atom or a coupling-off group. The material provides images having high maximum cyan image density and low minimum cyan density, despite fluctuations in processing conditions.

3. 发明公开

EP0343604A3 Method of forming color images 失效
标题翻译：形成彩色图像的方法
公开(公告)号：EP0343604A3
公开(公告)日：1990-10-10
申请号：EP89109285.0
申请日：1989-05-23
申请人： Fuji Photo Film Co., Ltd.
发明人： Nakajo, Kiyoshi , Ueda, Shinji , Abe, Akira , Inoue, Noriyuki
IPC分类号： G03C7/30 , G03C1/485
CPC分类号： G03C7/3022 , G03C1/48546 , G03C7/407
摘要： A method for producing color images comprising developing a negative silver halide color photographic materials and an internal latent-image type direct positive silver halide color photographic material, with the same developer having a pH of 9.0 to 11.5, said direct positive photographic material containing at least one compound represented by formula (N-I) as nucleating agent and at least one compound represented by (I) or (II) as magenta coupler, thereby ensuring high color reproducibility to both photographic materials:
wherein
Z 11 represents nonmetallic atomic group necessary to complete a 5- or 6-membered heterocyclic ring, which may be substituted R 11 represents a unsubstituted or substituted aliphatic hydrocarbon residue; R 12 represents a hydrogen atom, an unsubstituted or substituted aliphatic or aromatic hydrocarbon residue, or a residue forming a ring by binding to the heterocyclic ring completed by Z 11 ; provided at least one of the groups R 11 , R 12 and Z" contains an alkynyl group, an aliphatic or aromatic acyl group, a hydrazino group or a hydrazono group, or R 11 and R 12 combine with each other to complete a 6- membered ring as a dihydropyridinium skeleton, and at least one of the groups R 11 , R 12 and Z 11 may contain a group capable of accelerating adsorption onto silver halide grains; Y 1 represents a counter ion for maintaining charge balance; and n represents 0 or 1;
wherein R 1 and R 3 each represent a substituted or unsubstituted phenyl group; R 2 represents a hydrogen atom, an aliphatic or aromatic acyl group, or an aliphatic or aromatic sulfonyl group, said aliphatic moiety including straight chain, branched chain and cyclic alkyl, alkenyl and alkynyl moieties; R 4 represents a hydrogen atom or a substituent; Za and Zb each represents an unsubstituted or substituted methine group, or = N-; Y 1 represents a hydrogen atom, or a eliminatable group capable of eliminating upon coupling with an oxidation product of a developing agent Y 2 represents a halogen atom, or a splitting-cff group; (I) may form a polymer, including a dimer, via Ri, R 2 , R 3 or Yi, and (II) may form a polymer, including a dimer via R 4 , Za, Zb or Y 4 .

4. 发明公开

EP0311110A3 Direct positive color photographic materials 失效
标题翻译：直接的彩色摄影材料
公开(公告)号：EP0311110A3
公开(公告)日：1990-05-09
申请号：EP88116672.2
申请日：1988-10-07
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Inoue, Noriyuki
IPC分类号： G03C7/26 , G03C1/485
CPC分类号： G03C7/3003 , G03C1/48538 , G03C7/38
摘要： A direct positive color photosensitive material comprising at least one internal latent image silver halide emulsion layer which has not been prefogged on a support and at least one color image-forming magenta coupler represented by general formula (I) and at least one nucleation accelerator represented by general formulae (II) and/or (III):
wherein Za and Zb represent a =C- or
group, R¹ and R² represent a hydrogen atom or a substituent group, and X represents a hydrogen atom or a group which can be eliminated by a coupling reaction with the oxidized form of a primary aromatic amine developing agent, where if Za and Zb form a carbon-carbon double bond, said double bond may be a part of an aromatic ring, R¹, R² or X may form dimers or larger polymers; wherein Q represents a group of atoms required to form a 5- or 6-membered heterocyclic ring, which may be condensed with a carbon aromatic ring or a heterocyclic aromatic ring, Y represents a divalent linking group consisting of one or more atoms selected from a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom, and R represents an organic group which contains at least one thioether group, amino group, ammonium group, ether group or heterocyclic group, n represents 0 or 1 and m represents 0, 1 or 2, and M represents a hydrogen atom, an alkali metal atom, an ammonium group or a group which is cleaved under alkaline conditions;
wherein Q′ represents a group of atoms required to form a 5- or 6-membered heterocyclic ring which can form imino silver, Y, R, n and M are the same as for general formula (I) and m′ represents 1 or 2.

5. 发明公开

EP0276842A3 Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：EP0276842A3
公开(公告)日：1989-05-10
申请号：EP88101198.5
申请日：1988-01-27
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Hirano, Shigeo , Kojima, Tetsuro , Yamamoto, Kitsuru , Inoue, Noriyuki , Heki, Tatsuo
IPC分类号： G03C1/485 , G03C1/10
CPC分类号： C07D401/04 , C07D219/02 , C07D219/04 , C07D219/06 , C07D219/08 , C07D221/12 , C07D221/16 , C07D221/18 , C07D401/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D491/04 , C07D495/04 , C07D513/04 , G03C1/067 , G03C1/48546 , Y10S430/141
摘要： A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide photographic emulsion layer, wherein at least one layer selected from the emulsion layer and other hydrophilic colloid layers contains at least one alkynyl substituted heterocyclic quaternary ammonium salt represented by the following general formula (I):
wherein Z represents a non-metallic atomic group necessary to form a substituted or unsubstituted 5- membered or 6-membered heterocyclic ring to which a aromatic ring or a heterocyclic ring may further be condensed; R I represents a substituted or unsubstituted aliphatic group; X represents = C -or - N -; Q represents a non-metallic atomic group necessary to form a substituted or unsubstituted 4-membered to 12- membered non-aromatic hydrocarbon ring or substituted or unsubstituted non-aromatic heterocyclic ring; at least one of R 1 , a substituent for Z and a substituent for Q includes an alkynyl group; Y represents a counter ion necessary for charge balance; and n represents a number necessary to balance the charge.
摘要翻译： 1，一种卤化银照相材料，其特征在于它包括一个在其上具有至少一层光敏卤化银照相乳剂层的载体，其中至少一层选自乳剂层和其它亲水胶体层的层含有至少一种由（I）表示：其中Z表示形成可以进一步稠合芳族环或杂环的取代或未取代的5元或6元杂环所必需的非金属原子团; RI表示取代或未取代的脂族基团; X代表= C-或 - N-; Q表示形成取代或未取代的4元至12元非芳族烃环或取代或未取代的非芳族杂环所必需的非金属原子团; R1，Z的取代基和Q的取代基中的至少一个包括炔基; Y表示电荷平衡所需的抗衡离子; 而n代表平衡收费所需的数字。

6. 发明公开

EP0311110A2 Direct positive color photographic materials 失效
标题翻译： Direkt-positive farbphotographische Materialien。
公开(公告)号：EP0311110A2
公开(公告)日：1989-04-12
申请号：EP88116672.2
申请日：1988-10-07
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Inoue, Noriyuki
IPC分类号： G03C7/26 , G03C1/485
CPC分类号： G03C7/3003 , G03C1/48538 , G03C7/38
摘要： A direct positive color photosensitive material comprising at least one internal latent image silver halide emulsion layer which has not been prefogged on a support and at least one color image-forming magenta coupler represented by general formula (I) and at least one nucleation accelerator represented by general formulae (II) and/or (III):
wherein Za and Zb represent a =C- or
group, R¹ and R² represent a hydrogen atom or a substituent group, and X represents a hydrogen atom or a group which can be eliminated by a coupling reaction with the oxidized form of a primary aromatic amine developing agent, where if Za and Zb form a carbon-carbon double bond, said double bond may be a part of an aromatic ring, R¹, R² or X may form dimers or larger polymers;
wherein Q represents a group of atoms required to form a 5- or 6-membered heterocyclic ring, which may be condensed with a carbon aromatic ring or a heterocyclic aromatic ring, Y represents a divalent linking group consisting of one or more atoms selected from a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom, and R represents an organic group which contains at least one thioether group, amino group, ammonium group, ether group or heterocyclic group, n represents 0 or 1 and m represents 0, 1 or 2, and M represents a hydrogen atom, an alkali metal atom, an ammonium group or a group which is cleaved under alkaline conditions;
wherein Q′ represents a group of atoms required to form a 5- or 6-membered heterocyclic ring which can form imino silver, Y, R, n and M are the same as for general formula (I) and m′ represents 1 or 2.
摘要翻译：一种直接正色感光材料，其包含至少一个尚未预先加载在载体上的内部潜像卤化银乳剂层和由通式（I）表示的至少一种彩色图像形成品红成色剂和至少一种由通式（II）和/或（III）：其中Za和Zb表示a = C-或基，R 1和R 2表示氢原子或取代基，X 表示氢原子或可以通过与氧化形式的伯芳族胺显影剂的偶联反应而被除去的基团，其中如果Za和Zb形成碳 - 碳双键，则所述双键可以是芳族的一部分 R 1，R 2或X可以形成二聚体或更大的聚合物; 其中Q表示形成可与碳芳环或杂环芳环稠合的5-或6-元杂环所需的一组原子，Y表示由一个或多个原子组成的二价连接基团选自氢原子，碳原子，氮原子，氧原子和硫原子，R表示含有至少一个硫醚基，氨基，铵基，醚基或杂环基的有机基团，n 表示0或1，m表示0,1或2，M表示氢原子，碱金属原子，铵基或在碱性条件下被切割的基团; 其中Q min表示形成可形成亚氨基银的5或6元杂环所需的一组原子，Y，R，n和M与通式（I）相同，m min表示 1或2。

7. 发明公开

EP1020881A2 Photo-electrochemical cell 审中-公开
标题翻译：光电化学电池
公开(公告)号：EP1020881A2
公开(公告)日：2000-07-19
申请号：EP00100734.3
申请日：2000-01-14
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Kubota, Tadahiko , Watanabe, Tetsuya , Tsukahara, Jiro , Kawai, Kiyoshi , Inoue, Noriyuki , Okazaki, Masaki
IPC分类号： H01G9/20
CPC分类号： H01G9/2063 , H01G9/2031 , H01L51/0064 , H01L51/0073 , H01L51/0077 , H01L51/0086 , Y02E10/542
摘要： A photoelectric conversion device comprising an electrically conductive substrate having thereon a particulate semiconductor particles-containing layer having adsorbed a dye, a charge transporting layer, and a counter electrode, wherein the particulate semiconductor particles-containing layer has adsorbed two or more dyes. Preferably, at least one of the dyes has a maximum incident photon to current conversion efficiency at a wavelength of 300 nm or longer and shorter than 600 nm, and at least another dye has a maximum incident photon to current conversion efficiency at a wavelength of 600 to 850 nm, each when adsorbed alone in the particulate semiconductor particles-containing layer.
摘要翻译：一种光电转换元件，其特征在于，具有导电性基体，在该导电性基体上具有吸附了染料的粒子状的半导体粒子含有层，电荷输送层和对电极，所述粒状半导体粒子含有层吸附有2种以上的染料。优选地，至少一种染料在300nm或更长且小于600nm的波长处具有最大入射光子到电流转换效率，并且至少另一种染料在波长600下具有最大入射光子到电流转换效率各自在单独吸附在含有颗粒半导体颗粒的层中时为850nm。

8. 发明授权

EP0439041B1 Direct positive photographic material 失效
标题翻译：照相直接的正面材料
公开(公告)号：EP0439041B1
公开(公告)日：1998-09-02
申请号：EP91100369.7
申请日：1991-01-14
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Inoue, Noriyuki
IPC分类号： G03C1/485
CPC分类号： G03C1/48538 , G03C2001/0845 , G03C2001/093 , G03C2001/094 , G03C2200/59

9. 发明授权

EP0276842B1 Silver halide photographic material 失效
标题翻译：银色摄影材料
公开(公告)号：EP0276842B1
公开(公告)日：1992-07-29
申请号：EP88101198.5
申请日：1988-01-27
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Hirano, Shigeo , Kojima, Tetsuro , Yamamoto, Kitsuru , Inoue, Noriyuki , Heki, Tatsuo
IPC分类号： G03C1/485 , G03C1/10
CPC分类号： C07D401/04 , C07D219/02 , C07D219/04 , C07D219/06 , C07D219/08 , C07D221/12 , C07D221/16 , C07D221/18 , C07D401/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D491/04 , C07D495/04 , C07D513/04 , G03C1/067 , G03C1/48546 , Y10S430/141

10. 发明公开

EP1020881A3 Photo-electrochemical cell 审中-公开
公开(公告)号：EP1020881A3
公开(公告)日：2004-10-20
申请号：EP00100734.3
申请日：2000-01-14
申请人： Fuji Photo Film Co., Ltd.
发明人： Kubota, Tadahiko , Watanabe, Tetsuya , Tsukahara, Jiro , Kawai, Kiyoshi , Inoue, Noriyuki , Okazaki, Masaki
IPC分类号： H01G9/20
CPC分类号： H01G9/2063 , H01G9/2031 , H01L51/0064 , H01L51/0073 , H01L51/0077 , H01L51/0086 , Y02E10/542
摘要： A photoelectric conversion device comprising an electrically conductive substrate having thereon a particulate semiconductor particles-containing layer having adsorbed a dye, a charge transporting layer, and a counter electrode, wherein the particulate semiconductor particles-containing layer has adsorbed two or more dyes. Preferably, at least one of the dyes has a maximum incident photon to current conversion efficiency at a wavelength of 300 nm or longer and shorter than 600 nm, and at least another dye has a maximum incident photon to current conversion efficiency at a wavelength of 600 to 850 nm, each when adsorbed alone in the particulate semiconductor particles-containing layer.

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