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1. 发明公开

EP2582653A1 PROCESSES FOR PRODUCING HEXAMETHYLENEDIAMINE (HMD), ADIPONITRILE (ADN), ADIPAMIDE (ADM) AND DERIVATIVES THEREOF 审中-公开
标题翻译：用于生产己二胺（HMD），己二腈（ADN），二酰己二胺（ADM）及其衍生物
公开(公告)号：EP2582653A1
公开(公告)日：2013-04-24
申请号：EP11726031.5
申请日：2011-06-10
申请人： Bioamber, S.A.S.
发明人： FRUCHEY, Olan, S. , MANZER, Leo, E. , DUNUWILA, Dilum , KEEN, Brian, T. , ALBIN, Brooke, A. , CLINTON, Nye, A. , DOMBEK, Bernard, D.
IPC分类号： C07C51/02 , C07C51/41 , C07C51/46 , C07C55/14 , C07C209/46 , C07C209/48 , C07C209/50 , C07C231/02 , C07C253/20 , C07C253/22 , C07C253/30 , C08G69/26
CPC分类号： C07C253/22 , C07C51/02 , C07C51/412 , C07C51/46 , C07C209/46 , C07C209/48 , C07C209/50 , C07C231/02 , C07C253/20 , C07C253/30 , C08G69/26 , C08G69/28 , C07C55/14 , C07C211/12 , C07C233/05 , C07C255/04 , C07C255/24
摘要： Processes for producing nitrogen containing compounds include producing hexamethylenediamine (HMD), adiponitrile (ADN), adipamide (ADM) and derivatives thereof from adipic acid (AA) obtained from fermentation broths containing diammonium adipate (DAA) or monoammonium adipate (MAA).

2. 发明公开

EP2571840A1 PROCESSES FOR PRODUCING DIAMINOBUTANE (DAB), SUCCINIC DINITRILE (SDN) AND SUCCINAMIDE (DAM) 审中-公开
标题翻译：生产二氨基丁烷（DAB），琥珀酸二丁酯（SDN）和琥珀酰胺（DAM）
公开(公告)号：EP2571840A1
公开(公告)日：2013-03-27
申请号：EP11722257.0
申请日：2011-05-18
申请人： BioAmber S.A.S.
发明人： FRUCHEY, Olan, S. , MANZER, Leo, E. , DUNUWILA, Dilum , KEEN, Brian, T. , ALBIN, Brooke, A. , CLINTON, Nye, A. , DOMBEK, Bernard, D.
IPC分类号： C07C51/41 , C07C55/10 , C07C209/46 , C07C209/48 , C07C231/02 , C07C253/20 , C07C253/22 , C07C253/30 , C08G69/26 , C07C51/02 , C07C51/44
CPC分类号： C07C209/46 , C07C51/445 , C07C209/48 , C07C231/02 , C07C253/20 , C07C253/22 , C07C253/30 , C08G69/26 , C07C55/10 , C07C211/09 , C07C233/05 , C07C255/04 , C07C255/24
摘要： Processes that make nitrogen-containing compounds include converting succinic acid (SA) or monoammonium succinate (MAS) derived from a diammonium succinate (DAS)- or MAS-containing fermentation broth to produce such compounds including diaminobutane (DAB), succinic dinitrile (SDN), succinic amino nitrile (SAN), succinamide (DAM), and related polymers.
摘要翻译：制备含氮化合物的方法包括转化琥珀酸（SA）或琥珀酸二铵（DAS） - 或含MAS的发酵液得到的琥珀酸单铵（MAS），以生成包括二氨基丁烷（DAB），琥珀酸二腈（SDN），琥珀酸腈（SAN），琥珀酰胺（DAM）和相关聚合物。

3. 发明授权

EP1713763B1 VERFAHREN ZUR HERSTELLUNG VON NITRILEN UND ISONITRILEN DURCH DEHYDRATISIERUNGSREAKTIONEN MIT PROPANPHOSPHONSAEUREANHYDRIDEN 有权转让
标题翻译：用于生产和腈异腈涉及脱水与PROPANPHOSPHONSAEUREANHYDRIDEN
公开(公告)号：EP1713763B1
公开(公告)日：2011-05-18
申请号：EP05700951.6
申请日：2005-01-15
申请人： Archimica GmbH
发明人： MEUDT, Andreas , SCHERER, Stefan , NERDINGER, Sven
IPC分类号： C07C253/20 , C07C253/22 , C07C291/10 , C07C255/50
CPC分类号： C07C253/20 , C07C253/22 , C07C291/10 , C07C255/50
摘要： The invention concerns a method for producing: a) nitriles of formula (II) and; b) isonitriles of formula (III) by reacting: a) carboxylic acid amides (RCO-NH2), ammonium salts of carboxylic acids (RCOO-NH4+) or carboxylic acids in the presence of ammonia or ammonium salts (RCOOH +NH3, RCOOH + NH4+) or; b) formamides (H-CO-NHR) or mixtures of amines with formic acid, with cyclic phosphonic acid anhydrides while eliminating water at a temperature ranging from -30 to +120 °C, in which R represents an arbitrarily substituted linear or branched C1-C8 alkyl radical, a C3-C10 cycloalkyl radical, alkenyl radical, alkynyl radical or an aryl radical or heteroaryl radical. As a cyclic phosphonic acid anhydride, a 2,4,6,-substituted 1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide of formula (I) is used, in which: x = 3, 4 or 5; R', independent of one another, represents open-chain or branched, saturated or unsaturated, straight-chain C1 to C16 alkyl radicals or cyclic C3 to C16 alkyl radicals or aryl or heteroaryl.

4. 发明公开

EP1517884A1 A PROCESS FOR THE PREPARATION OF 3-CYANO-1-NAPHTHOIC ACID AND SOME ANALOGUES THEREOF 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG VON 3-CYANO-1-NAPHTOESÄUREUND EINIGEN ANALOGA DAVON
公开(公告)号：EP1517884A1
公开(公告)日：2005-03-30
申请号：EP03733769.8
申请日：2003-06-18
申请人： AstraZeneca AB
发明人： Ashworth, Ian,Syngenta Ltd , Bowden, Martin,Syngenta Ltd , Dembofsky, Bruce , LEVIN, Daniel
IPC分类号： C07C253/00 , C07C255/57 , C07C255/52 , C07C233/67 , C07C233/65 , C07D309/38
CPC分类号： C07D311/00 , C07C233/65 , C07C253/00 , C07C253/20 , C07C253/30 , C07C255/52 , C07C259/10 , C07C2602/10 , C07C255/57
摘要： The present invention is related to a process for the preparation of 3-cyano-1-naphthoic acid and some analogues thereof of formula (1), the intermediate 1-halo-3-cyano naphthalene and some analogues thereof used in this process and a process for the preparation of said intermediate.
摘要翻译：本发明涉及制备式（1）的3-氰基-1-萘甲酸及其一些类似物的方法，该方法中使用的中间体1-卤代-3-氰基萘及其一些类似物，和所述中间体的制备方法。

5. 发明授权

EP1298122B1 Process for the production of fluorinated nitriles from corresponding amides 失效
标题翻译：一种用于从相应的酰胺的制备氟化腈的过程
公开(公告)号：EP1298122B1
公开(公告)日：2004-06-30
申请号：EP02026445.3
申请日：1996-02-26
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Hung, Ming-Hong , Subramanyam , Vinayakam
IPC分类号： C07C231/02 , C07C233/09 , C07C235/06 , C07C253/20 , C07C255/07
CPC分类号： C07C235/06 , C07C231/02 , C07C253/20 , C07C255/13

6. 发明公开

EP0895986A3 A process for producing a nitrile 审中-公开
标题翻译：一种生产腈的方法
公开(公告)号：EP0895986A3
公开(公告)日：2001-08-29
申请号：EP98306299.3
申请日：1998-08-06
申请人： TORAY INDUSTRIES, INC.
发明人： Matsuoka, Shotaro , Sematsu, Masaaki , Ishikawa, Mamoru
IPC分类号： C07C253/20 , C07C255/50
CPC分类号： C07C253/20 , C07C255/50
摘要： In a process for producing a nitrile (II) :R - CN (where R is optionally substituted alkyl, alkenyl, alkynyl, aryl or aralkyl) by dehydration of an amide (I):R - CONH 2 (where R is as defined above), the dehydration reaction is carried out in the presence of a carboxylic acid (III) :R - COOH (where R is as defined above).
摘要翻译：一种生产腈（II）的方法：R t - CN通过酰胺（I）的脱水（其中R是任选取代的烷基，烯基，炔基，芳基或芳烷基），R - CONH 2（其中R定义同上）脱水反应在羧酸（III）：R-COOH（其中R如上所定义）存在下进行。

7. 发明公开

EP0872476A3 Verfahren zur Herstellung von 2,6-Dichlor-3-fluor-benzonitril und neue Zwischen-produkte 失效
标题翻译：一种用于2,6-二氯-3-氟 - 苄腈的制备和新的中间产物的方法
公开(公告)号：EP0872476A3
公开(公告)日：1999-07-07
申请号：EP98102479.7
申请日：1995-11-09
申请人： BAYER AG
发明人： Lantzsch, Reinhard, Dr. , Bussmann, Werner, Dr. , Käsbauer, Josef, Dr.
IPC分类号： C07C255/50
CPC分类号： C07C255/50 , A01N37/34 , C07C17/12 , C07C17/14 , C07C25/13 , C07C45/43 , C07C47/55 , C07C63/04 , C07C63/70 , C07C233/65 , C07C251/44 , C07C251/48 , C07C253/00 , C07C253/20
摘要： Die Erfindung betrifft ein Verfahren zur Herstellung von 2,6-Dichlor-3-fluor-benzonitril sowie neue Zwischenprodukte.

8. 发明公开

EP0895986A2 A process for producing a nitrile 审中-公开
标题翻译：一种生产腈的方法
公开(公告)号：EP0895986A2
公开(公告)日：1999-02-10
申请号：EP98306299.3
申请日：1998-08-06
申请人： TORAY INDUSTRIES, INC.
发明人： Matsuoka, Shotaro , Sematsu, Masaaki , Ishikawa, Mamoru
IPC分类号： C07C253/20 , C07C255/50
CPC分类号： C07C253/20 , C07C255/50
摘要： In a process for producing a nitrile (II) :

R - CN (II)

(where R is optionally substituted alkyl, alkenyl, alkynyl, aryl or aralkyl) by dehydration of an amide (I):

R - CONH 2 (I)

(where R is as defined above), the dehydration reaction is carried out in the presence of a carboxylic acid (III) :

R - COOH (III)

(where R is as defined above).
摘要翻译：在通过酰胺（I）脱水制备腈（II）：R-CN（II）（其中R为任选取代的烷基，链烯基，炔基，芳基或芳烷基）的方法中： R如上所定义），脱水反应在羧酸（III）：R-COOH（III）（其中R如上所定义）存在下进行。

9. 发明公开

EP0357244A3 Method for converting nitriles to amides and amides to nitriles 失效
标题翻译：将硝酸盐转化为氨基酸和氨基酸的方法
公开(公告)号：EP0357244A3
公开(公告)日：1991-12-04
申请号：EP89307928.5
申请日：1989-08-03
申请人： THE STANDARD OIL COMPANY
发明人： Boyer, Robert D., Jnr , Denman, Sandra L. , Cesa, Mark C. , Pagnotta, Marco
IPC分类号： C07C233/02 , C07C233/09 , C07C233/65 , C07C235/06 , C07C255/02 , C07C255/06 , C07C255/50 , C07D307/68 , C01C3/02 , C07C231/06 , C07C253/20
CPC分类号： C01C3/0204 , C07C231/06 , C07C253/20 , C07D307/68 , C07C233/65 , C07C255/03 , C07C233/04 , C07C255/04
摘要： A process which comprises contacting and catalytically reacting under essentially anhydrous conditions in the liquid phase an amide with a nitrile according to the equation:
RCONH₂ + R¹CN → RCN + R¹CONH₂
where R and R₁ are not the same and are each selected from
(1) H, hydrocarbyl, a hydrocarbyl group substituted with: one or more of F, Cl, Br, I, amido, cyano, formyl, hydrocarbylcarbonyl, hydrocarbyloxy, hydrocarbyloxycarbonyl, hydrocarbylcarbonyloxy and dihydrocarbylamino, and (2) any of group (1) where one or more H atoms are substituted by a deuterium atom.

10. 发明公开

EP0365842A3 Process for converting scrap to PET 4-aminomethyl benzoic acid 失效
标题翻译：将PET刮刀转换为DIAMINE MONOMERS的工艺
公开(公告)号：EP0365842A3
公开(公告)日：1991-09-11
申请号：EP89117668.7
申请日：1989-09-25
申请人： GENERAL ELECTRIC COMPANY
发明人： Blackmon, Kenneth Paul , Fox, Daniel Wayne , Shafer, Sheldon Jay
IPC分类号： C07C209/44 , C07C231/02 , C07C253/20
CPC分类号： C07C209/48 , C07C227/04 , C07C231/02 , C07C253/20 , C07C253/30 , C07C2601/14 , C07C29/00 , C07C31/202 , C07C233/65 , C07C255/51 , C07C255/60 , C07C255/57 , C07C229/34 , C07C211/27 , C07C211/25
摘要： Scrap poly(ethyleneterephthalate) is converted to useful amine and diamine monomers such as para-xylylenediamine, 1,4-bis(aminomethyl)cyclohexane and 4-aminomethyl benzoic acid for the production of various polyamides. The conversion of poly(ethyleneterephthalate) to diamine monomers is achieved by a three step process involving (a) ammonolysis of the poly(ethyleneterephthalate) to produce terephthalamide and ethylene glycol; (b) pyrolytic dehydration of the terephthalamide to produce terephthalonitrile; and (c) hydrogenation of the terephthalonitrile to produce the para-xylylene diamine and/or 1,4-bis(aminomethyl)cyclohexane. The conversion of poly(ethyleneterephthalate) to 4-aminomethyl benzoic acid involves the steps of (a) ammonolysis of the poly(ethyleneterephthalate) to produce terephthalamide; (b) partial pyrolytic dehydration of said terephthalamide to produce 4-cyanobenzoic acid; and (c) hydrogenation of said 4-cyanobenzoic acid to produce 4-aminomethylbenzoic acid. The process of the present invention permits the conversion of low value PET scrap such as beverage bottles, fibers and film to relatively high value and relatively pure diamine monomers and ethylene glycol.
摘要翻译：将聚（对苯二甲酸乙二醇酯）废料转化为有用的胺和二胺单体如对苯二甲胺，1,4-双（氨基甲基）环己烷和4-氨基甲基苯甲酸，用于生产各种聚酰胺。聚（对苯二甲酸乙二醇酯）向二胺单体的转化通过三步法实现，其包括（a）聚对苯二甲酸乙二醇酯的氨解产生对苯二甲酰胺和乙二醇; （b）对苯二甲酰胺的热解脱水产生对苯二腈; 和（c）对苯二腈的氢化以产生对二甲苯二胺和/或1,4-双（氨基甲基）环己烷。聚（对苯二甲酸乙二醇酯）向4-氨基甲基苯甲酸的转化涉及以下步骤：（a）聚对苯二甲酸乙二醇酯的氨解产生对苯二酰胺; （b）部分热解脱水所述对苯二酰胺以产生4-氰基苯甲酸; 和（c）氢化所述4-氰基苯甲酸以产生4-氨基甲基苯甲酸。本发明的方法允许将低价值PET废料如饮料瓶，纤维和膜转化成相对高的值和相对纯的二胺单体和乙二醇。

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