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1. 发明授权

EP2752402B1 PRODUCTION METHOD FOR 2-ALKENYLAMINE COMPOUND 有权
公开(公告)号：EP2752402B1
公开(公告)日：2018-06-27
申请号：EP12827952.8
申请日：2012-08-29
申请人： Showa Denko K.K. , National University Corporation Nagoya University
发明人： ISHIBASHI, Yoshitaka , FUKUMOTO, Naoya , KITAMURA, Masato
IPC分类号： C07C209/14 , C07C209/22 , C07C211/21 , C07C211/25 , C07C211/27 , C07C211/48 , C07B61/00
CPC分类号： C07C209/60 , C07C209/14 , C07C209/22 , C07D295/03 , C07C211/21 , C07C211/25
摘要： Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenyleamine compound is produced by 2-alkenylating a primary or secondary amine compound, using a specified 2-alkenylating agent and in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.

2. 发明公开

EP0365842A2 Process for converting scrap to PET 4-aminomethyl benzoic acid 失效
标题翻译：维他命Zur Umwandlung von PET在Diamin-Monomere。
公开(公告)号：EP0365842A2
公开(公告)日：1990-05-02
申请号：EP89117668.7
申请日：1989-09-25
申请人： GENERAL ELECTRIC COMPANY
发明人： Blackmon, Kenneth Paul , Fox, Daniel Wayne , Shafer, Sheldon Jay
IPC分类号： C07C209/44 , C07C231/02 , C07C253/20
CPC分类号： C07C209/48 , C07C227/04 , C07C231/02 , C07C253/20 , C07C253/30 , C07C2601/14 , C07C29/00 , C07C31/202 , C07C233/65 , C07C255/51 , C07C255/60 , C07C255/57 , C07C229/34 , C07C211/27 , C07C211/25
摘要： Scrap poly(ethyleneterephthalate) is converted to useful amine and diamine monomers such as para-xylylenediamine, 1,4-bis(aminomethyl)cyclohexane and 4-aminomethyl benzoic acid for the production of various polyamides. The conversion of poly(ethyleneterephthalate) to diamine monomers is achieved by a three step process involving (a) ammonolysis of the poly(ethyleneterephthalate) to produce terephthalamide and ethylene glycol; (b) pyrolytic dehydration of the terephthalamide to produce terephthalonitrile; and (c) hydrogenation of the terephthalonitrile to produce the para-xylylene diamine and/or 1,4-bis(aminomethyl)cyclohexane. The conversion of poly(ethyleneterephthalate) to 4-aminomethyl benzoic acid involves the steps of (a) ammonolysis of the poly(ethyleneterephthalate) to produce terephthalamide; (b) partial pyrolytic dehydration of said terephthalamide to produce 4-cyanobenzoic acid; and (c) hydrogenation of said 4-cyanobenzoic acid to produce 4-aminomethylbenzoic acid. The process of the present invention permits the conversion of low value PET scrap such as beverage bottles, fibers and film to relatively high value and relatively pure diamine monomers and ethylene glycol.
摘要翻译：将聚（对苯二甲酸乙二醇酯）废料转化为有用的胺和二胺单体如对苯二甲胺，1,4-双（氨基甲基）环己烷和4-氨基甲基苯甲酸，用于生产各种聚酰胺。聚（对苯二甲酸乙二醇酯）向二胺单体的转化通过三步法实现，其包括（a）聚对苯二甲酸乙二醇酯的氨解产生对苯二甲酰胺和乙二醇; （b）对苯二甲酰胺的热解脱水产生对苯二腈; 和（c）对苯二腈的氢化以产生对二甲苯二胺和/或1,4-双（氨基甲基）环己烷。聚（对苯二甲酸乙二醇酯）向4-氨基甲基苯甲酸的转化涉及以下步骤：（a）聚对苯二甲酸乙二醇酯的氨解产生对苯二酰胺; （b）部分热解脱水所述对苯二酰胺以产生4-氰基苯甲酸; 和（c）氢化所述4-氰基苯甲酸以产生4-氨基甲基苯甲酸。本发明的方法允许将低价值PET废料如饮料瓶，纤维和膜转化成相对高的值和相对纯的二胺单体和乙二醇。

3. 发明公开

EP1442008A1 UNSATURATED 1-AMINO-ALKYLCYCLOHEXANE NMDA, 5HT3 AND NEURONAL NICOTINIC RECEPTOR ANTAGONISTS 审中-公开
标题翻译： UNGESÄTTIGTE1-AMINO-ALKYLCYCLOHEXAN NMDA，5HT3 UND NEURONALE NICOTIN REZEPTOR ANTAGONISTEN
公开(公告)号：EP1442008A1
公开(公告)日：2004-08-04
申请号：EP02772631.4
申请日：2002-11-07
申请人： Merz Pharma GmbH & Co. KGaA
发明人： PARSONS, Christopher, Graham, Raphael , HENRICH, Markus , DANSYZ, Wojciech , KALVINSH, Ivars , KAUSS, Valerjans , JIRGENSONS, Aigars , GOLD, Markus
IPC分类号： C07C211/40 , C07C211/35 , C07D211/06 , A61P25/28 , A61K31/13
CPC分类号： C07D295/033 , C07C211/25 , C07C211/40 , C07C2601/14 , C07C2601/16
摘要： Unsaturated 1-amino-alkylcyclohexane compounds which are systemically-active as NMDA, 5HT3 and nicotinic receptor antagonists, pharmaceutical compositions comprising the same, method of preparation thereof, and method of treating CNS disorders which involve disturbances of glutamatergic, serotoninergic, and nicotinic transmission, treating immunomodulatory disorders, and antimalaria, antitrypanosomal, anti-Borna virus, anti-HSV and anti-Hepatitis C virus activity.
摘要翻译：作为NMDA，5HT3和烟碱受体拮抗剂具有全身活性的不饱和1-氨基 - 烷基环己烷化合物，包含其的药物组合物，其制备方法和治疗涉及谷氨酸能，血清素能和烟碱传播障碍的CNS病症的方法治疗免疫调节性疾病，抗疟疾，抗睾丸激素，抗牛痘病毒，抗HSV和抗丙型肝炎病毒活性。

4. 发明公开

EP0900194A1 CYCLOPENTADIENE COMPOUND SUBSTITUTED WITH LINEAR GROUPS 失效
标题翻译：带线性基团取代的环戊二烯化合物
公开(公告)号：EP0900194A1
公开(公告)日：1999-03-10
申请号：EP97919752.0
申请日：1997-04-28
申请人： DSM N.V.
发明人： GRUTER, Gerardus, Johannes, Maria , VAN BEEK, Johannes, Antonius, Maria , GREEN, Richard , IJPEIJ, Edwin, Gerard
IPC分类号： B01J31 , C07C211 , C07F17 , C08F4 , C08F10
CPC分类号： B01J31/143 , B01J31/2295 , B01J2531/46 , C07C211/25 , C07F17/00 , C08F4/65912 , C08F4/6592 , C08F10/00
摘要： Polysubstituted cyclopentadiene compound, wherein at least one substituent is of the form -RDR'n, where R is a bonding group between the cyclopentadiene and the DR'n group, D is a hetero atom chosen from group (15 or 16) of the Periodic System of the Elements, R' is a substituent and n is the number of R' groups bonded to D, and in which at least one further substituent is a linear alkyl group comprising at least 2 carbon atoms. Metal complexes in which at least one of these cyclopentadiene compounds is present as a ligand are useful as catalysts for the polymerisation of alpha-olefins.

5. 发明授权

EP0365842B1 Process for converting scrap to PET 4-aminomethyl benzoic acid 失效
标题翻译： Verfahren zur Umwandlung von PET在4-氨基甲基苯并苯甲醚中。
公开(公告)号：EP0365842B1
公开(公告)日：1995-02-01
申请号：EP89117668.7
申请日：1989-09-25
申请人： GENERAL ELECTRIC COMPANY
发明人： Blackmon, Kenneth Paul , Fox, Daniel Wayne , Shafer, Sheldon Jay
IPC分类号： C07C209/44 , C07C231/02 , C07C253/20
CPC分类号： C07C209/48 , C07C227/04 , C07C231/02 , C07C253/20 , C07C253/30 , C07C2601/14 , C07C29/00 , C07C31/202 , C07C233/65 , C07C255/51 , C07C255/60 , C07C255/57 , C07C229/34 , C07C211/27 , C07C211/25
摘要： Scrap poly(ethyleneterephthalate) is converted to useful amine and diamine monomers such as para-xylylenediamine, 1,4-bis(aminomethyl)cyclohexane and 4-aminomethyl benzoic acid for the production of various polyamides. The conversion of poly(ethyleneterephthalate) to diamine monomers is achieved by a three step process involving (a) ammonolysis of the poly(ethyleneterephthalate) to produce terephthalamide and ethylene glycol; (b) pyrolytic dehydration of the terephthalamide to produce terephthalonitrile; and (c) hydrogenation of the terephthalonitrile to produce the para-xylylene diamine and/or 1,4-bis(aminomethyl)cyclohexane. The conversion of poly(ethyleneterephthalate) to 4-aminomethyl benzoic acid involves the steps of (a) ammonolysis of the poly(ethyleneterephthalate) to produce terephthalamide; (b) partial pyrolytic dehydration of said terephthalamide to produce 4-cyanobenzoic acid; and (c) hydrogenation of said 4-cyanobenzoic acid to produce 4-aminomethylbenzoic acid. The process of the present invention permits the conversion of low value PET scrap such as beverage bottles, fibers and film to relatively high value and relatively pure diamine monomers and ethylene glycol.
摘要翻译：将聚（对苯二甲酸乙二醇酯）废料转化为有用的胺和二胺单体如对苯二甲胺，1,4-双（氨基甲基）环己烷和4-氨基甲基苯甲酸，用于生产各种聚酰胺。聚（对苯二甲酸乙二醇酯）向二胺单体的转化通过三步法实现，其包括（a）聚对苯二甲酸乙二醇酯的氨解产生对苯二甲酰胺和乙二醇; （b）对苯二甲酰胺的热解脱水产生对苯二腈; 和（c）对苯二腈的氢化以产生对二甲苯二胺和/或1,4-双（氨基甲基）环己烷。聚（对苯二甲酸乙二醇酯）向4-氨基甲基苯甲酸的转化涉及以下步骤：（a）聚对苯二甲酸乙二醇酯的氨解产生对苯二酰胺; （b）部分热解脱水所述对苯二酰胺以产生4-氰基苯甲酸; 和（c）氢化所述4-氰基苯甲酸以产生4-氨基甲基苯甲酸。本发明的方法允许将低价值PET废料如饮料瓶，纤维和膜转化成相对高的值和相对纯的二胺单体和乙二醇。

6. 发明公开

EP2752402A4 PRODUCTION METHOD FOR 2-ALKENYLAMINE COMPOUND 有权
标题翻译：处理对2 - 烯基CONNECTION
公开(公告)号：EP2752402A4
公开(公告)日：2015-05-06
申请号：EP12827952
申请日：2012-08-29
申请人： SHOWA DENKO KK , UNIV NAGOYA NAT UNIV CORP
发明人： ISHIBASHI YOSHITAKA , FUKUMOTO NAOYA , KITAMURA MASATO
IPC分类号： C07C209/14 , C07B61/00 , C07C209/22 , C07C211/21 , C07C211/25 , C07C211/27 , C07C211/48
CPC分类号： C07C209/60 , C07C209/14 , C07C209/22 , C07D295/03 , C07C211/21 , C07C211/25
摘要： Provided is a method for producing a 2-alkenylamine compound efficiently and at low cost, using a primary or secondary amine compound and a 2-alkenyl compound as the starting materials therefor. The 2-alkenyleamine compound is produced by 2-alkenylating a primary or secondary amine compound, using a specified 2-alkenylating agent and in the presence of a catalyst comprising a complexing agent and a transition metal precursor stabilized by a monovalent anionic five-membered conjugated diene.

7. 发明授权

EP2173691B1 METHODS OF INHIBITING ETHYLENE RESPONSES IN PLANTS USING CYCLOPROPENE AMINE COMPOUNDS 有权
标题翻译：方法INHIBITING乙烯反应在使用CYCLOPROPENAMINVERBINDUNGEN植物
公开(公告)号：EP2173691B1
公开(公告)日：2013-11-13
申请号：EP08768433.8
申请日：2008-06-13
申请人： North Carolina State University
发明人： SISLER, Edward, C.
IPC分类号： C07C13/04 , C07C211/17 , C07C211/45 , A01N27/00 , A01N3/02 , A01G7/06 , A01N33/04 , A23B7/14 , A23B7/144 , A23B7/153 , C07C211/25
CPC分类号： A01N33/04 , A23B7/144 , A23B7/154 , C07C211/25 , C07C211/45 , C07C211/48 , C07C2601/02

8. 发明公开

EP2651878A1 CYCLOHEXANE COMPOUNDS AND THEIR USE AS ANTIBIOTICS 审中-公开
标题翻译： CYCLOHEXANVERBINDUNGEN UND IHRE VERWENDUNG ALS ANTIBIOTIKA
公开(公告)号：EP2651878A1
公开(公告)日：2013-10-23
申请号：EP11793835.7
申请日：2011-12-13
申请人： Rheinische Friedrich-Wilhelms-Universität Bonn , Universität Konstanz
发明人： MAYER, Günter , LÜNSE, Christina, Elsbeth , WITTMANN, Valentin , SCHMIDT, Magnus, S.
IPC分类号： C07C213/02 , C07C215/44 , C07F9/144 , A61K31/66 , A61K31/133 , A61K31/435
CPC分类号： C07F9/44 , A61K31/13 , A61K31/66 , C07C211/25 , C07C215/42 , C07C215/44 , C07C233/23 , C07C2601/14 , C07F9/117 , C07F9/5304
摘要： The present invention relates to compounds according to general formula (I), pharmaceutical compositions comprising compounds according to general formula (I) and the use of the compounds for the treatment of a bacterial infection, particularly for use as an antibiotic.
摘要翻译：本发明涉及根据通式（I）的化合物，包含根据通式（I）的化合物的药物组合物以及该化合物用于治疗细菌感染，特别是用作抗生素的用途。

9. 发明公开

EP2489654A1 Cyclohexane compounds and their use as antibiotics 审中-公开
标题翻译： Cyclohexanverbindungen und ihre Verwendung als Antibiotika
公开(公告)号：EP2489654A1
公开(公告)日：2012-08-22
申请号：EP10194929.5
申请日：2010-12-14
申请人： Rheinische Friedrich-Wilhelms-Universität Bonn , Universität Konstanz
发明人： Mayer, Günter , Lünse, Christina, Elsbeth , Wittmann, Valentin , Schmidt, Magnus, S.
IPC分类号： C07C213/02 , C07C215/44 , C07F9/144 , A61K31/66 , A61K31/133 , A61K31/435
CPC分类号： C07F9/44 , A61K31/13 , A61K31/66 , C07C211/25 , C07C215/42 , C07C215/44 , C07C233/23 , C07C2601/14 , C07F9/117 , C07F9/5304
摘要： The present invention relates to compounds according to general formula (I), pharmaceutical compositions comprising compounds according to general formula (I) and the use of the compounds for the treatment of a bacterial infection, particularly for use as an antibiotic.
摘要翻译：本发明涉及根据通式（I）的化合物，包含根据通式（I）的化合物的药物组合物以及该化合物用于治疗细菌感染，特别是用作抗生素的用途。

10. 发明授权

EP1544192B1 Fluorierungsreagenzien enthaltend 1-Fluor-1-aminoolefine, deren Herstellung und Verwendung 有权
标题翻译：含有1-氟-1- aminoolefine氟化试剂，其制备和用途
公开(公告)号：EP1544192B1
公开(公告)日：2009-03-04
申请号：EP04028658.5
申请日：2004-12-03
申请人： Saltigo GmbH
发明人： Ebenbeck, Wolfgang, Dr. , Marhold, Albrecht, Dr.
IPC分类号： C07C211/25 , C07C17/16 , C07C22/08 , C07B39/00 , B01J31/02
CPC分类号： C07B39/00 , C07C17/16 , C07C209/74 , C07C211/25

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