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    • 9. 发明公开
    • Method of manufacturing a gas sensor
    • 法赫伦·赫斯特伦
    • EP0070551A1
    • 1983-01-26
    • EP82106505.9
    • 1982-07-19
    • Hitachi, Ltd.
    • Sunano, NaomasaAsahi, Naotatsu
    • G01N27/56G01N27/12
    • G01N27/4073
    • Herein disclosed is a gas sensor which is constructed of an electrically insulating base (1), electrodes (2) formed on said base, and a gas sensitive film (3) formed on the surface of said base (1) at a portion where it detects the gas to be sensed, e.g. an oxygen gas. The gas sensitive film (3) is a thermal-sprayed film made of an oxide having a perovskite structure. The thermal-sprayed film has its surface formed with fine cracks to have its effective surface area increased so that the response is accelerated. Moreover, the thermal spraying process is so effected during the formation of the oxide film (3) that impurities which might adversely affect the reliability may be avoided from being mixed. The gas sensor may have said gas sensitive film (3) coated with a ceramic material (4) so that its performance may be further improved while protecting the gas sensitive film. Furthermore, it is also effective to add another sensor which uses the same electrically insulating base (1).
    • 这里公开了一种气体传感器,其由电绝缘基座(1),形成在所述基座上的电极(2)和形成在所述基座(1)的表面上的气体敏感膜(3)构成, 检测要感测的气体,例如 氧气。 气体敏感膜(3)是由具有钙钛矿结构的氧化物制成的热喷涂膜。 热喷涂膜的表面形成有细小的裂缝,使其有效的表面积增加,从而加速反应。 此外,在形成氧化膜(3)期间热喷涂方法如此受到可能避免混合可能对可靠性造成不利影响的杂质。 气体传感器可以具有涂覆有陶瓷材料(4)的所述气体敏感膜(3),从而可以进一步改善其性能,同时保护气敏元件。 此外,添加使用相同的电绝缘基底(1)的另一个传感器也是有效的。
    • 10. 发明公开
    • High wear-resistant member, method of producing the same, and valve gear using the same for use in internal combustion engine
    • Hochverschleissbeständiges其制备和阀齿轮用于内燃发动机内使用组件,过程。
    • EP0266149A2
    • 1988-05-04
    • EP87309424.7
    • 1987-10-26
    • HITACHI, LTD.M. H. CENTER, LTD.
    • Doi, MasayukiAsahi, NaotatsuKojima, YoshitakaKanamaru, HisanobuAoyama, Susumu
    • C23C4/18C23C4/06C23C4/08C23C30/00
    • C23C4/06C23C4/18Y10T428/12576Y10T428/12806Y10T428/12979
    • A wear-resistant metal member comprises a surface that has a sprayed layer consisting essentially of, by weight, 2 to 10% C, 18 to 60% Cr, 0.3 to 20% V, 25% or less Mo, 25% or less W, 10% or less Nb, 10% or less Ti, 10% or less Zr, 10% or less Hf and the balance being Fe in a proportion of 20% or greater. The sprayed layer has a martensite-phase matrix containing carbide particles, nitride particles or carbonitride particles. In addition, the member of the present invention is produced by the steps of: plasma-spraying the above-described metal in a reduced pressure atmosphere; and quenching the thus-sprayed metal layer from a predetermined temperature to form a materisite phase in that layer. In addition, the sprayed metal layer may be subjected to carburizing, nitriding or carbonitrid­ing to form a carburized, nitrided or carbonitrided layer in the sprayed metal layer. The member of the present invention has a high wear resistance and is used as a sliding portion of a valve gear in an internal combustion engine.
    • 一种耐磨损性金属构件包括表面并具有喷涂层基本上由按重量计2%至10%C,18〜60%的Cr,0.3〜20%的V,25%以下的Mo,25%以下的W ,10%或更少的Nb,10%以下的Ti,10%以下的Zr,10%以下的Hf,余量为20%或更大的比例为Fe。 所述喷涂层具有马氏体相基质包含碳化物颗粒,氮化物颗粒或碳氮化颗粒。 另外,本发明的构件是通过以下步骤产生的:等离子喷涂上述金属在减压气氛; 并且从预定的温度淬火由​​此喷涂金属层,以形成相materisite DASS层。 另外,喷涂金属层可以进行渗碳,氮化或碳氮共渗,以在所述喷涂金属层的渗碳,渗氮或碳氮共渗层。 本发明的构件具有高的耐磨性和用作阀齿轮的滑动部中,以内燃机。