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    • 81. 发明公开
    • Method and apparatus for photodeposition of films on surfaces
    • Methode und Apparat zum photochemischen Auftragen von Filmen aufOberflächen。
    • EP0241190A2
    • 1987-10-14
    • EP87302703.1
    • 1987-03-30
    • MASSACHUSETTS INSTITUTE OF TECHNOLOGY
    • Ehrlich, Daniel J.Rothschild, Mordecai
    • C23C16/48C23C16/16H01F41/14H01F41/22
    • G03F1/72C23C16/047C23C16/483G03F7/2043H01F41/20H01F41/22H01F41/34
    • The invention relates to visible-laser deposition reactions of metal containing oxyhalide and carbonyl vapors, such as, chromyl chloride vapor, CrO 2 Cl 2 , or cobalt carbonyl, Co 2 (CO) 8 , for direct writing of metal containing opaque patterns on various substrates (S i , S i O 2 , GaAs and glass). Deposition at low laser power is by photolyses of adsorbed reactant molecules. Higher powers initiate deposition photochemically and continue it with a combined photolytic/ pyrolytic reaction, simultaneously inducing a solid-phase conversion of the deposited film. Mixed Cr 2 O 3 /CrO 2 or cobalt thin films of 1-nanometerto several-micrometer thickness, as well as 1-millimeter-long single crystals of Cr 2 0 3 or cobalt, can be grown with this process, the former at rates up to 3 µm/s. Thin chromium oxide films produced in this manner are strongly ferromagnetic.
    • 本发明涉及含有卤氧化物和羰基蒸气的染料的可见激光沉积反应,例如氯化铬蒸气,CrO 2 Cl 2或羰基钴Co 2(CO)8,用于将各种不透明图案的金属直接写入各种衬底(Si, SiO2,GaAs和玻璃)。 在低激光功率下沉积是通过吸附的反应物分子的光解。 更高的功率开始光化学沉积,并通过组合的光解/热解反应继续进行,同时诱导沉积膜的固相转化。 可以用该方法生长1纳米至几微米厚的混合Cr2O3 / CrO2或钴薄膜,以及1毫米长的Cr2O3或钴单晶,前者的速率高达3微米/ 秒。 以这种方式生产的薄铬氧化物膜是强铁磁性的。