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    • 4. 发明授权
    • Vacuum/gas phase reactor for dehydroxylation and alkylation of porous silica
    • 真空/气相反应器用于多羟基硅烷的脱羟基和烷基化
    • US06548113B1
    • 2003-04-15
    • US09711666
    • 2000-11-09
    • Jerome BirnbaumGary MaupinGlen DunhamGlen FryxellSuresh Baskaran
    • Jerome BirnbaumGary MaupinGlen DunhamGlen FryxellSuresh Baskaran
    • C23C1644
    • C01B37/02H01L21/31695Y10T428/249969Y10T428/249972
    • Vacuum/gas phase reactor embodiments used in gas phase dehydroxylation and alkylation reactions are described in which the substrate could be subjected to high vacuum, heated to target temperature, and treated with silane as quickly and efficiently as possible. To better facilitate the silylation and to increase the efficiency of the process, the reactor is designed to contain quasi-catalytic surfaces which can act both as an “activator” to put species in a higher energy state or a highly activated state, and as a “scrubber” to eliminate possible poisons or reactive by-products generated in the silylation reactions. One described embodiment is a hot filament reactor having hot, preferably metallic, solid surfaces within the reactor's chamber in which wafers having mesoporous silicate films are treated. Another is an IR reactor having upper and lower quartz windows sealing the upper and lower periphery of an aluminum annulus to form a heated chamber. Finally, a flange reactor is described that includes a flange base and lid forming a tiny chamber therein for a wafer, the reactor being heated by conduction from a hot sand bath. The dehydroxylation and alkylation treatment of mesoporous silica films produces treated films exhibiting low dielectric constant and high elastic modulus.
    • 描述了用于气相脱羟基和烷基化反应的真空/气相反应器实施例,其中基底可经受高真空,加热至目标温度,并尽可能快速且有效地用硅烷处理。 为了更好地促进甲硅烷基化和提高该方法的效率,反应器被设计成包含准催化剂表面,它们既可以作为“活化剂”来将物质置于更高能量状态或高活化状态,也可以作为 “洗涤器”来消除在甲硅烷化反应中产生的可能的毒物或反应性副产物。 一个描述的实施方案是在反应器室内具有热的,优选金属的固体表面的热丝反应器,其中处理具有介孔硅酸盐膜的晶片。 另一种是IR反应器,其具有密封铝环空的上下周边的上,下石英窗,以形成加热室。 最后,描述了一种法兰反应器,其包括法兰基座和盖子,用于在晶片上形成微小的室,该反应器由热砂浴传导加热。 介孔二氧化硅膜的脱羟基化和烷基化处理产生显示低介电常数和高弹性模量的处理膜。
    • 6. 发明授权
    • Chemical vapor deposition of near net shape monolithic ceramic parts
    • 化学气相沉积近净形单块陶瓷零件
    • US06231923B1
    • 2001-05-15
    • US09375734
    • 1999-08-17
    • Alexander TeverovskyJames C. MacDonaldLee Erich Burns
    • Alexander TeverovskyJames C. MacDonaldLee Erich Burns
    • C23C1644
    • C23C16/4588C23C16/01C23C16/458
    • A method and apparatus for producing a coating or a near net shaped monolithic ceramic part by chemical vapor deposition, where the resultant coatings or parts consume less deposit material and require less machining. Mandrel substrates are closely designed for producing a specific, near net shaped final part, including negative relief features. Several of the mandrel substrates are mounted through centers in a spaced relationship on one or more rotable shafts as tooling for a chemical vapor deposition furnace. The tooling is installed in a chemical vapor deposition furnace so that the shafts are oriented perpendicular and the substrate planar surfaces are parallel to the flow pattern of reactant gases through the furnace. The shafts are rotated during the deposition process so that the mandrel substrates each receive a uniformly distributed ceramic deposit in the near net shape of the final part.
    • 一种用于通过化学气相沉积制造涂层或近网状整体陶瓷部件的方法和装置,其中所得的涂层或部件消耗较少的沉积材料并且需要较少的加工。 心轴衬底被紧密地设计用于生产特定的近净形的最终部件,包括负的浮雕特征。 几个心轴基板通过中心以一个或多个可旋转的轴间隔开地安装,作为用于化学气相沉积炉的工具。 工具安装在化学气相沉积炉中,使得轴垂直取向,并且基板平面与通过炉的反应气体的流动图形平行。 轴在沉积过程中旋转,使得心轴基板各自接收最终部件的近净形状的均匀分布的陶瓷沉积物。
    • 7. 发明授权
    • Method and apparatus for vapor generation and film deposition
    • 用于蒸气产生和膜沉积的方法和装置
    • US06805907B2
    • 2004-10-19
    • US10154588
    • 2002-05-24
    • James J. SunBenjamin Y. H. Liu
    • James J. SunBenjamin Y. H. Liu
    • C23C1644
    • C23C16/448
    • A vapor generator (19, 62) and connected chemical vapor deposition chamber (28) for providing a vapor for operations such as chemical vapor deposition has an atomizer (16, 16A, 38, 50) for forming an aerosol or droplet spray (36, 58, 74, 80) separate from a vaporization chamber (19, 62). The aerosol is passed into a heated vaporization chamber (19, 62) wherein the particles or droplets are flash vaporized and larger droplets are vaporized by direct contact with heated surfaces. The resulting gas/vapor stream is then used for chemical vapor deposition, in a separate chemical vapor deposition chamber (26). The vapor and gas stream is preferably passed through a restricted passageway (22, 44, 68) for mixing before being introduced into the chemical vapor deposition chamber (26).
    • 用于提供用于诸如化学气相沉积的操作的蒸汽的蒸汽发生器(19,62)和连接的化学气相沉积室(28)具有用于形成气溶胶或液滴喷雾的雾化器(16,16A,38,50) 58,74,80)与蒸发室(19,62)分离。 气溶胶通入加热的蒸发室(19,62),其中颗粒或液滴被闪蒸,并且通过与加热的表面直接接触而使较大的液滴蒸发。 然后在单独的化学气相沉积室(26)中将所得的气体/蒸气流用于化学气相沉积。 蒸汽和气体流优选通过限制通道(22,44,68),以在被引入化学气相沉积室(26)之前进行混合。