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    • 2. 发明申请
    • Fluorine-containing unsaturated compound and method for its production
    • 含氟不饱和化合物及其制备方法
    • US20050113609A1
    • 2005-05-26
    • US11026012
    • 2005-01-03
    • Yutaka Furukawa
    • Yutaka Furukawa
    • C07C43/17C07C41/00
    • C07C43/17
    • A novel fluorine-containing unsaturated compound and a method for its production. A fluorine-containing unsaturated compound represented by R1CY1HCY2Y3OQ1CH═CH2 or CH2═CHQ2OCZ1Z2CZ3HR2CZ4HCZ5Z6OQ2CH═CH2 (wherein R1 is a monovalent fluorine containing organic group, etc., R2 is a bivalent fluorine containing organic group, etc., Y1 to Y3 and Z1 to Z6 are fluorine atoms, and Q1 and Q2 are alkylene groups, etc.). A method for producing a fluorine-containing unsaturated compound having a group represented by —CX1HCX2X3OQCH═CH2 (wherein X1 to X3 are fluorine atoms, and Q is an alkylene group, etc.), which comprises reacting a compound having —CX1═CX2X3 with HOQCH═CH2 in the presence of an alkali metal compound.
    • 一种新型含氟不饱和化合物及其制备方法。 由R 1表示的含氟不饱和化合物1 CH 2 CH 2或CH 2 -CHQ 2 O 2 ZZZ 2 O 2 / SUP> CZ 3 2 > 2 CH-CH 2(其中R 1是一价含氟有机基团等,R 2是 二价含氟有机基团等,Y 1至Y 3和Z 1至Z 6均为氟 原子,Q 1和Q 2是亚烷基等)。 一种具有由-CX 1 -OXCH 2 O 3 OQCH-CH 2表示的基团的含氟不饱和化合物的制备方法 (其中X 1至X 3是氟原子,Q是亚烷基等),其包括使具有-CX 3 3。
    • 6. 发明授权
    • Polyether modified fluoroalkylsiloxanes
    • 聚醚改性氟烷基硅氧烷
    • US5908950A
    • 1999-06-01
    • US862939
    • 1997-05-29
    • Jeffrey A. CookeGerald J. MurphyYutaka FurukawaSeisaku Kumai
    • Jeffrey A. CookeGerald J. MurphyYutaka FurukawaSeisaku Kumai
    • C08L83/05C08G77/385C08G77/46C08G81/00C07F7/08
    • C08G77/385C08G77/46
    • Polyether modified fluoroalkylsiloxanes having the general structure of Formula (I), Formula (II) or Formula (III): ##STR1## wherein x is about 0 to 500, y is about 1 to 50, z is about 1 to 50, R=C.sub.p H.sub.2p --(OC.sub.2 H.sub.4).sub.n --(OC.sub.3 H.sub.6).sub.n).sub.m --OR' in which p is about 2 to 5, n is about 0 to 50, N is about 0 to 50, and one of n or m must be >0, and R'=H, an alkyl group with 1-4 carbons, or an acetyl group and R.sub.f =C.sub.a H.sub.2a --O.sub.b --C.sub.c H.sub.2c --C.sub.d F.sub.2d+1 in which a is 3 or 4, b is 0 or 1, c is 0 or 2-4 and d is 4-12 with the provisos that if b=0, then c=0, and that if b=1, then c=2-4; z.sub.1 is about 0 to 50 and y.sub.1 is about 0 to 50, are useful to reduce the coefficient of friction and to increase mar resistance of coatings, to increase spreadability and wettability of coating formulations, and as foam control agents.
    • 具有式(I),式(II)或式(III)的通式结构的聚醚改性氟代烷基硅氧烷:其中x为约0至500,y为约1至50,z为约1至50,R = CpH 2 p-( OC2H4)n - (OC3H6)n)m-OR',其中p为约2至5,n为约0至50,N为约0至50,n或m中的一个必须> 0,R' = H,具有1-4个碳原子的烷基或乙酰基,R f = CaH 2 a -Ob-CcH2c-CdF2d + 1,其中a为3或4,b为0或1,c为0或2-4, d为4-12,条件是如果b = 0,则c = 0,如果b = 1,则c = 2-4; z1为约0〜50,y1约为0〜50,可用于降低摩擦系数,提高涂层的耐磨性,增加涂料配方的铺展性和润湿性,以及泡沫控制剂。
    • 8. 发明授权
    • Automatic tension maintaining transmission belt
    • 自动张力保持传动皮带
    • US4522614A
    • 1985-06-11
    • US621439
    • 1984-08-23
    • Hiroshi MatsuokaYutaka Furukawa
    • Hiroshi MatsuokaYutaka Furukawa
    • F16G5/06F16G1/00B29D3/00F16G5/00F16G9/00
    • F16G5/06
    • An automatic tension maintaining power transmission belt, a method of making the same and a method for maintaining tension in a rubber belt transmission. The belt is made by embedding polyester fiber cord employing a polyester of high relative viscosity and after being subjected to a hot stretching process as a tensile member in rubber forming the belt. The thermal contraction force of the polyester cord is to be substantially maintained by avoiding shrinkage of the belt during vulcanization.The belt of the present invention is characterized by exhibiting shrinkage of said polyester fiber cords through thermal contractive forces caused by frictional heat generated by slippage of the belt upon lowering of belt tension during belt running. The minimum tension necessary for transmission of power is recovered, the slippage is eliminated for a while and proper tension is maintained. Such automatic action repeats when it becomes needed again.
    • 一种自动张力保持动力传递带,其制造方法以及用于保持橡胶带传动装置中的张力的方法。 带通过使用具有高相对粘度的聚酯的聚酯纤维帘线嵌入,并且在经受热拉伸过程之后作为形成带的橡胶中的拉伸构件而制成。 通过避免硫化期间带的收缩,聚酯帘线的热收缩力基本上得到保持。 本发明的带的特征在于,通过在带运行期间降低带张力时由带滑动引起的摩擦热引起的热收缩力表现出所述聚酯纤维帘线的收缩。 恢复功率传递所需的最小张力,一段时间消除滑动并保持适当的张力。 这种自动动作在再次需要时重复。
    • 9. 发明授权
    • Polymerizable fluorine-containing compound and treated substrate having a hydrophilic region and a water repellent region
    • 可聚合的含氟化合物和具有亲水区域和拒水区域的处理过的基材
    • US08338502B2
    • 2012-12-25
    • US12365970
    • 2009-02-05
    • Taiki HoshinoYutaka Furukawa
    • Taiki HoshinoYutaka Furukawa
    • C08G18/67C08G61/00C08F2/46B05D3/02B41M5/00C07C55/36
    • C07C69/708Y10T428/24802Y10T428/265Y10T442/2189
    • To provide a polymerizable fluorine-containing compound useful for producing a treated substrate having a hydrophilic region and a water repellent region, of which the contrast is high on its surface, without requiring a special apparatus, high energy light, or irradiation with light for a long time.A polymerizable fluorine-containing compound, which is a derivative of a polyhydric alcohol and comprises at least one following structure (A) and at least one following structure (B) in its molecule: structure (A): a structure wherein a compound having a fluoroalkyl group and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage, structure (B): a structure wherein a compound having an ethylenic double bond and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage or a structure wherein a compound having an ethylenic double bond and an isocyanate group is bonded to one hydroxyl group of a polyhydric alcohol by a urethane bond.
    • 为了提供可用于制备具有亲水区域和防水区域的处理基材的可聚合含氟化合物,其表面上的对比度高,而不需要特殊装置,高能量光或用于光的照射 长时间。 一种可聚合的含氟化合物,其是多元醇的衍生物,其分子中包含至少一种以下结构(A)和至少一种以下结构(B):结构(A):其中具有 氟烷基和羧基通过酯键与多元醇的一个羟基键合,结构(B):其中具有烯键式双键和羧基的化合物与多元醇的一个羟基键合的结构 通过酯键或其中具有烯属双键和异氰酸酯基的化合物通过氨基甲酸酯键与多元醇的一个羟基键合的结构。