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    • 1. 发明申请
    • NEGATIVE PHOTOSENSITIVE COMPOSITION, PARTITION WALLS FOR OPTICAL DEVICE USING IT AND OPTICAL DEVICE HAVING THE PARTITION WALLS
    • 负离子光敏组合物,使用其和具有分隔壁的光学装置的光学装置的分界面
    • US20110117333A1
    • 2011-05-19
    • US13012939
    • 2011-01-25
    • Yutaka FURUKAWA
    • Yutaka FURUKAWA
    • G03F7/004G03F7/20B32B3/10
    • G03F7/0757G02B5/201G02B5/223G02F1/133516G02F1/13439G03F7/0007G03F7/0046H01L27/3246H01L27/3283H01L51/0005Y10T428/24802
    • To provide a negative photosensitive composition applicable to preparation of partition walls which can maintain excellent ink repellency even after ink affinity-imparting treatment, and partition walls for an optical device using such a composition.A negative photosensitive composition comprising the following ink repellent (A) in an amount of from 0.01 to 10 mass % to the total amount, a photosensitive resin (B) having an acidic group and an ethylenic double bond in one molecule, and a photopolymerization initiator (C), and partition walls for an optical device using such a composition: Ink repellent (A): a hydrolyzed condensate of at least three hydrolyzable silane compounds, the three hydrolyzable silane compounds respectively selected from a trifunctional hydrolyzable silane compound having a C3-10 perfluoroalkyl group which may contain an etheric oxygen atom, a bi- to tetrafunctional hydrolyzable silane compound, and a bi- or trifunctional hydrolyzable silane compound having a (meth)acryloyl group, which has a fluorine atom content of from 10 to 55 mass %.
    • 为了提供适用于制备分隔壁的负型感光性组合物,即使在赋予油墨亲和力的处理之后也能够保持优异的拒墨性,以及使用这种组合物的光学装置的分隔壁。 包含相对于总量为0.01〜10质量%的以下拒墨剂(A)的负型感光性组合物,1分子中具有酸性基团和烯属双键的感光性树脂(B)和光聚合引发剂 (C)和使用这种组合物的光学装置的分隔壁:防墨水(A):至少三种可水解硅烷化合物的水解缩合物,分别选自三官能可水解硅烷化合物的三种可水解硅烷化合物,其具有C3- 10个可以含有醚性氧原子的全氟烷基,双官能的水解性硅烷化合物和具有10〜55质量%的氟原子含量的具有(甲基)丙烯酰基的双官能或三官能的水解性硅烷化合物, 。
    • 2. 发明申请
    • TREATED SUBSTRATE HAVING HYDROPHILIC REGION AND WATER REPELLENT REGION, AND PROCESS FOR PRODUCING IT
    • 具有水文地区和水域的处理基底及其生产工艺
    • US20100196702A9
    • 2010-08-05
    • US12204847
    • 2008-09-05
    • Yutaka FURUKAWA
    • Yutaka FURUKAWA
    • B32B33/00B32B27/00C08F2/48B05D5/00
    • H01L21/02118G03F7/027G03F7/0755G03F7/0757H01L21/312Y10T428/265Y10T428/3154Y10T428/31663Y10T428/31667
    • To provide a treated substrate having a hydrophilic region and a water repellent region, of which contrast is high on its surface. Further, to provide a process for producing a treated substrate, wherein a specific equipment, light having a high energy or light irradiation for a long time is not required, and the treated substrate can be produced with a low amount of light for a short time.A treated substrate having a hydrophilic region and a water repellent region on a surface of a substrate, characterized in that the water repellent region is made of a water repellent film formed by curing the composition (A) comprising a photopolymerization initiator and a compound (a) having at least one (meth)acryloyl group, and a water repellent moiety and having a film thickness of from 0.1 to 100 nm. A process for producing a treated substrate, characterized by using a hydrophilic substrate or carrying out a hydrophilic treatment on a surface of a substrate to make the surface hydrophilic, then forming a film containing the composition (A) on the surface, then forming a water repellent film having a film thickness of from 0.1 to 100 nm by irradiating light on a part of the film surface to cure the composition (A) and then removing an uncured composition (A) present on the surface of the substrate in order to expose the hydrophilic surface.
    • 提供具有亲水区域和防水区域的处理过的基材,其表面上的对比度高。 此外,为了提供一种处理基板的制造方法,其中特定的设备,不需要长时间的高能量或光照射的光,并且可以在短时间内以少量的光生产处理过的基板 。 一种在基材表面上具有亲水区域和防水区域的处理过的基材,其特征在于,所述防水区域由通过固化包含光聚合引发剂和化合物(a)的组合物(A)而形成的防水膜制成, )具有至少一个(甲基)丙烯酰基和斥水性部分,并且膜厚度为0.1-100nm。 一种处理基材的制造方法,其特征在于,在基材表面使用亲水性基材或进行亲水处理,使表面亲水,然后在表面上形成含有组合物(A)的膜,然后形成水 通过在膜表面的一部分上照射光来固化组合物(A),然后除去存在于基材表面上的未固化组合物(A),以使曝光的膜的厚度为0.1至100nm的防水膜 亲水表面。
    • 3. 发明申请
    • TREATED SUBSTRATE HAVING HYDROPHILIC REGION AND WATER REPELLENT REGION, AND PROCESS FOR PRODUCING IT
    • 具有水文地区和水域的处理基底及其生产工艺
    • US20090011227A1
    • 2009-01-08
    • US12204847
    • 2008-09-05
    • Yutaka FURUKAWA
    • Yutaka FURUKAWA
    • B32B33/00B32B27/00C08F2/48B05D5/00
    • H01L21/02118G03F7/027G03F7/0755G03F7/0757H01L21/312Y10T428/265Y10T428/3154Y10T428/31663Y10T428/31667
    • To provide a treated substrate having a hydrophilic region and a water repellent region, of which contrast is high on its surface. Further, to provide a process for producing a treated substrate, wherein a specific equipment, light having a high energy or light irradiation for a long time is not required, and the treated substrate can be produced with a low amount of light for a short time.A treated substrate having a hydrophilic region and a water repellent region on a surface of a substrate, characterized in that the water repellent region is made of a water repellent film formed by curing the composition (A) comprising a photopolymerization initiator and a compound (a) having at least one (meth)acryloyl group, and a water repellent moiety and having a film thickness of from 0.1 to 100 nm. A process for producing a treated substrate, characterized by using a hydrophilic substrate or carrying out a hydrophilic treatment on a surface of a substrate to make the surface hydrophilic, then forming a film containing the composition (A) on the surface, then forming a water repellent film having a film thickness of from 0.1 to 100 nm by irradiating light on a part of the film surface to cure the composition (A) and then removing an uncured composition (A) present on the surface of the substrate in order to expose the hydrophilic surface.
    • 提供具有亲水区域和防水区域的处理过的基材,其表面上的对比度高。 此外,为了提供一种处理基板的制造方法,其中特定的设备,不需要长时间的高能量或光照射的光,并且可以在短时间内以少量的光生产处理过的基板 。 一种在基材表面上具有亲水区域和防水区域的处理过的基材,其特征在于,所述防水区域由通过固化包含光聚合引发剂和化合物(a)的组合物(A)而形成的防水膜制成, )具有至少一个(甲基)丙烯酰基和斥水性部分,并且膜厚度为0.1-100nm。 一种处理基材的制造方法,其特征在于,在基材表面使用亲水性基材或进行亲水处理,使表面亲水,然后在表面上形成含有组合物(A)的膜,然后形成水 通过在膜表面的一部分上照射光来固化组合物(A),然后除去存在于基材表面上的未固化组合物(A),以使曝光的膜的厚度为0.1至100nm的防水膜 亲水表面。
    • 5. 发明申请
    • Fluorine-containing unsaturated compound and method for its production
    • 含氟不饱和化合物及其制备方法
    • US20050113609A1
    • 2005-05-26
    • US11026012
    • 2005-01-03
    • Yutaka Furukawa
    • Yutaka Furukawa
    • C07C43/17C07C41/00
    • C07C43/17
    • A novel fluorine-containing unsaturated compound and a method for its production. A fluorine-containing unsaturated compound represented by R1CY1HCY2Y3OQ1CH═CH2 or CH2═CHQ2OCZ1Z2CZ3HR2CZ4HCZ5Z6OQ2CH═CH2 (wherein R1 is a monovalent fluorine containing organic group, etc., R2 is a bivalent fluorine containing organic group, etc., Y1 to Y3 and Z1 to Z6 are fluorine atoms, and Q1 and Q2 are alkylene groups, etc.). A method for producing a fluorine-containing unsaturated compound having a group represented by —CX1HCX2X3OQCH═CH2 (wherein X1 to X3 are fluorine atoms, and Q is an alkylene group, etc.), which comprises reacting a compound having —CX1═CX2X3 with HOQCH═CH2 in the presence of an alkali metal compound.
    • 一种新型含氟不饱和化合物及其制备方法。 由R 1表示的含氟不饱和化合物1 CH 2 CH 2或CH 2 -CHQ 2 O 2 ZZZ 2 O 2 / SUP> CZ 3 2 > 2 CH-CH 2(其中R 1是一价含氟有机基团等,R 2是 二价含氟有机基团等,Y 1至Y 3和Z 1至Z 6均为氟 原子,Q 1和Q 2是亚烷基等)。 一种具有由-CX 1 -OXCH 2 O 3 OQCH-CH 2表示的基团的含氟不饱和化合物的制备方法 (其中X 1至X 3是氟原子,Q是亚烷基等),其包括使具有-CX 3 3。
    • 8. 发明授权
    • Polymerizable fluorine-containing compound and treated substrate having a hydrophilic region and a water repellent region
    • 可聚合的含氟化合物和具有亲水区域和拒水区域的处理过的基材
    • US08338502B2
    • 2012-12-25
    • US12365970
    • 2009-02-05
    • Taiki HoshinoYutaka Furukawa
    • Taiki HoshinoYutaka Furukawa
    • C08G18/67C08G61/00C08F2/46B05D3/02B41M5/00C07C55/36
    • C07C69/708Y10T428/24802Y10T428/265Y10T442/2189
    • To provide a polymerizable fluorine-containing compound useful for producing a treated substrate having a hydrophilic region and a water repellent region, of which the contrast is high on its surface, without requiring a special apparatus, high energy light, or irradiation with light for a long time.A polymerizable fluorine-containing compound, which is a derivative of a polyhydric alcohol and comprises at least one following structure (A) and at least one following structure (B) in its molecule: structure (A): a structure wherein a compound having a fluoroalkyl group and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage, structure (B): a structure wherein a compound having an ethylenic double bond and a carboxyl group is bonded to one hydroxyl group of a polyhydric alcohol by an ester linkage or a structure wherein a compound having an ethylenic double bond and an isocyanate group is bonded to one hydroxyl group of a polyhydric alcohol by a urethane bond.
    • 为了提供可用于制备具有亲水区域和防水区域的处理基材的可聚合含氟化合物,其表面上的对比度高,而不需要特殊装置,高能量光或用于光的照射 长时间。 一种可聚合的含氟化合物,其是多元醇的衍生物,其分子中包含至少一种以下结构(A)和至少一种以下结构(B):结构(A):其中具有 氟烷基和羧基通过酯键与多元醇的一个羟基键合,结构(B):其中具有烯键式双键和羧基的化合物与多元醇的一个羟基键合的结构 通过酯键或其中具有烯属双键和异氰酸酯基的化合物通过氨基甲酸酯键与多元醇的一个羟基键合的结构。