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    • 2. 发明专利
    • Curable composition and coated article
    • 可固化组合物和涂层物品
    • JP2007231060A
    • 2007-09-13
    • JP2006051759
    • 2006-02-28
    • Shin Etsu Chem Co LtdToyota Industries CorpToyota Motor Corpトヨタ自動車株式会社信越化学工業株式会社株式会社豊田自動織機
    • HIGUCHI KOICHIYAMATANI MASAAKIMURAMATSU HISASHISENBOKU KOICHIWATANABE TOSHIONAGAI TAKAYUKIKONDO TOSHIRO
    • C08L101/10C08K5/3477C08K5/5415
    • C09D183/06C08L83/06C09D143/04C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) a vinyl polymer where hydrolyzable silyl groups and/or SiOH groups and organic ultraviolet-absorbing groups are bound to the side chains, (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state, and (C) an organosilicon compound having in the molecule a nitrogen atom and an alkoxysilyl group. This curable composition, because being markedly improved in light resistance, prevented from the ultraviolet light absorber's being washed away and used as a weatherability-rich binder, gives ultraviolet-absorbing coating film of high water resistance, high solvent resistance and high light resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成保护涂膜的可固化组合物,其不含长期使用下的开裂,脱粘和变黄以及耐候性优良的缺点,并提供使用该组合物的涂布制品。 解决方案:可固化组合物包含(A)其中水解性甲硅烷基和/或SiOH基团和有机紫外线吸收基团与侧链结合的乙烯基聚合物,(B)分子中的有机紫外线吸收剂500以上 重量和95%以上的质量残留百分比,在150℃下保持打开状态24小时,(C)分子内具有氮原子和烷氧基甲硅烷基的有机硅化合物。 该可固化组合物由于耐光性显着提高,防止紫外线吸收剂被洗去并用作耐候脆性粘合剂,得到耐水性高,耐溶剂性高,耐光性高的紫外线吸收性涂膜。 当用这种可固化组合物涂覆/固化耐候性差的制品时,防止了制品的变色和/或变质,并且可赋予制品良好的耐候性。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Curable composition and coated article
    • 可固化组合物和涂层物品
    • JP2007231059A
    • 2007-09-13
    • JP2006051756
    • 2006-02-28
    • Shin Etsu Chem Co LtdToyota Industries CorpToyota Motor Corpトヨタ自動車株式会社信越化学工業株式会社株式会社豊田自動織機
    • HIGUCHI KOICHIYAMATANI MASAAKIMURAMATSU HISASHISENBOKU KOICHIWATANABE TOSHIONAGAI TAKAYUKIKONDO TOSHIRO
    • C08L83/10C08K5/3477
    • C08J7/047C08J2369/00C08J2483/00C08L83/06C08L101/00C09D143/04C09D183/10Y10T428/31663C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) an organic-inorganic composite where a polysiloxane with hydrolyzable silyl groups and/or SiOH groups and a vinyl polymer are bound to each other via Si-C bond and (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state. This curable composition, because the ultraviolet light absorber is prevented from being washed away owing to siloxane crosslinking and the organic-inorganic composite rich in weatherability is used as a binder, gives ultraviolet-absorbing coating film of high water resistance and solvent resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成保护涂膜的可固化组合物,其不含长期使用下的开裂,脱粘和变黄以及耐候性优良的缺点,并提供使用该组合物的涂布制品。 解决方案:可固化组合物包含(A)其中具有可水解甲硅烷基和/或SiOH基的聚硅氧烷和乙烯基聚合物通过Si-C键彼此结合的有机 - 无机复合物,(B)有机紫外线 光吸收剂在150℃下保持24小时,分子量为500以上,质量残留率为95%以上。 该可固化组合物由于防止紫外光吸收剂被硅氧烷交联而被洗涤,并且将具有耐候性的有机 - 无机复合材料用作粘合剂,得到具有高耐水性和耐溶剂性的紫外线吸收涂膜。 当用这种可固化组合物涂覆/固化耐候性差的制品时,防止了制品的变色和/或变质,并且可赋予制品良好的耐候性。 版权所有(C)2007,JPO&INPIT
    • 7. 发明专利
    • Propylenic resin composition, and injection molding thereof
    • 丙烯树脂组合物及其注塑成型
    • JP2012229303A
    • 2012-11-22
    • JP2011097110
    • 2011-04-25
    • Sumitomo Chemical Co Ltd住友化学株式会社Toyota Motor Corpトヨタ自動車株式会社
    • KANZAKI SUSUMUTAKAHASHI AKIHIRONAGAI TAKAYUKIWATANABE TOSHIO
    • C08L23/10B29C45/00C08K3/34C08L23/08C08L53/00
    • PROBLEM TO BE SOLVED: To provide a propylenic resin composition from which a molding can be produced which has excellent molding processability and molding appearance, and rigidity, has a small linear expansion coefficient to influence the dimensional stability, particularly a low anisotropy of the linear expansion coefficient.SOLUTION: The propylenic resin composition contains 35 to 54 wt.% of a propylenic polymer (component A) having a melt flow rate of ≥60 g/10-min, 15 to 25 wt.% of an ethylene-α-olefin copolymer (component B) being a random copolymer of ethylene and a 4-10C α-olefin and having a melt flow rate of 1.5 g to 3.5 g/10-min, and 33 to 40 wt.% of a talc (component C) having an average particle diameter of ≤5 μm (here, the total amount of the (component A), the (component B) and the (component C) is taken to be 100 wt.%).
    • 要解决的问题:为了提供具有优异的成型加工性和成型外观以及刚性的可以制造成型品的丙烯树脂组合物,具有小的线性膨胀系数以影响尺寸稳定性,特别是低的各向异性 线膨胀系数。 解决方案:丙烯类树脂组合物含有35〜54重量%的熔体流动速率≥60g/ 10分钟的丙烯类聚合物(A成分),乙烯-α-烯烃的15〜25重量% 烯烃共聚物(组分B)是乙烯和4-10Cα-烯烃的无规共聚物,熔体流动速率为1.5g至3.5g / 10min,和33至40wt。%的滑石(组分C )(这里,(成分A),(成分B)和(成分C)的合计量为100重量%)。 版权所有(C)2013,JPO&INPIT
    • 8. 发明专利
    • Method for producing modified polyolefin
    • 生产改性聚烯烃的方法
    • JP2007063196A
    • 2007-03-15
    • JP2005252306
    • 2005-08-31
    • Sanyo Chem Ind LtdToyota Motor Corpトヨタ自動車株式会社三洋化成工業株式会社
    • INOUE HIROFUMINAGAI TAKAYUKIONISHI KEISUKE
    • C07C259/06C07C231/14C08K5/053C08L23/26C08L101/00
    • PROBLEM TO BE SOLVED: To provide a method for producing a modified polyolefin constituting a coatability modifier for improving coatability (adhesion of coated film, etc.) of a resin without reducing the mechanical properties of a resin by the addition of a small amount because the coatability modifier having a coatability-improving effects of the resin without reducing the resin properties of the resin by the addition of the small amount is not known, although a method for kneading a large amount of a modified polyolefin having a polar functional group grafted on the polyolefin with a polypropylene for improving the coatability (adhesion of the coated film, etc.) of the polypropylene has been known; and to provide a thermoplastic resin composition containing the coatability improver in the thermoplastic resin. SOLUTION: The method for producing the modified polyolefin comprises reacting (a) a 6-30C olefin polymer with (b) a hydroxy group-containing unsaturated monomer in the presence or absence of (c) a radical initiator. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种构成可涂布性改性剂的改性聚烯烃的制造方法,其通过添加小型树脂而不降低树脂的机械性能来改善树脂的涂布性(涂膜的粘附性) 因为通过加入少量树脂而不降低树脂的树脂性能而具有树脂的涂布性改进效果的可涂布性改性剂是未知的,尽管将大量具有极性官能团的改性聚烯烃 已知用聚丙烯接枝聚丙烯以提高聚丙烯的涂布性(涂膜的粘合性等); 并提供在热塑性树脂中含有可涂层性改进剂的热塑性树脂组合物。 解决方案:制备改性聚烯烃的方法包括在(c)自由基引发剂存在或不存在的情况下使(a)6-30C烯烃聚合物与(b)含羟基的不饱和单体反应。 版权所有(C)2007,JPO&INPIT
    • 9. 发明专利
    • Laminate and its molded product
    • 层压板及其模制产品
    • JP2006007538A
    • 2006-01-12
    • JP2004186781
    • 2004-06-24
    • Toyota Motor Corpトヨタ自動車株式会社
    • NAGAI TAKAYUKI
    • B32B27/32
    • PROBLEM TO BE SOLVED: To provide a laminate excellent in strength, having good appearance quality and excellent coating properties, reduced in wall thickness, light in weight and having excellent strength, and to provide its molded product.
      SOLUTION: The laminate is constituted by bonding an upper layer, which comprises a polypropylene resin molded body composed of a crystalline ethylene-propylene block copolymer, a thermoplastic elastomer and talc, and a lower layer comprising a thermoplastic resin molded body containing reinforcing fibers. Its molded product is also disclosed.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供强度优异,外观品质好,涂布性能优异,壁厚减轻,重量轻,强度优异的层叠体,提供其成型品。 解决方案:层压体通过粘合上层,其包含由结晶乙烯 - 丙烯嵌段共聚物组成的聚丙烯树脂成型体,热塑性弹性体和滑石,以及包含含有增强材料的热塑性树脂成型体的下层 纤维。 还公开了其成型产品。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Dispersant or coating properties improver
    • 分散或涂层性能改善
    • JP2005307201A
    • 2005-11-04
    • JP2005089183
    • 2005-03-25
    • Sanyo Chem Ind LtdToyota Motor Corpトヨタ自動車株式会社三洋化成工業株式会社
    • NAKAYAMA HIROMITSUKATSUKAWA MAKOTOINOUE HIROFUMINAGAI TAKAYUKIONISHI KEISUKE
    • C08L23/00C08F8/46
    • PROBLEM TO BE SOLVED: To provide a dispersant or a coating properties improver which has a clay dispersing effect into and a coating properties improving effect of a resin without a deterioration of physical properties by adding a small amount of the dispersant or the improver thereto that has not been known so far, and up to now, a maleic acid modified polypropylene oligomer has been used as a dispersant of the clay into a resin, and a hydoxyl group modified polypropylene having a hydroxyl group has been known as a resin modifier which improves the coating properties to a resin. SOLUTION: The dispersant (I) or the coating properties improver (II) comprises a modified polyolefin (A) having a hydrophobic group comprising a polyolefin (a) having a number-average molecular weight of 1,500-100,000 and a hydrophilic group having at least one of an onium base (b), and per one of the (b), the number-average molecular weight being 750-50,000. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种分散剂或涂料性能改进剂,其具有粘土分散效果和涂料性能改善效果,而不会通过加入少量分散剂或改进剂而使物理性能下降 迄今为止尚未公知,迄今为止已将马来酸改性聚丙烯低聚物用作粘土的分散剂为树脂,并且已知具有羟基的羟基改性聚丙烯作为树脂改性剂 这提高了树脂的涂层性能。 解决方案:分散剂(I)或涂料性能改进剂(II)包含具有疏水基团的改性聚烯烃(A),其包含数均分子量为1,500-100,000的聚烯烃(a)和亲水基团 具有鎓基(b)和(b)中的每一种中的至少一种,数均分子量为750-50,000。 版权所有(C)2006,JPO&NCIPI