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    • 1. 发明专利
    • Curable composition and coated article
    • 可固化组合物和涂层物品
    • JP2007231059A
    • 2007-09-13
    • JP2006051756
    • 2006-02-28
    • Shin Etsu Chem Co LtdToyota Industries CorpToyota Motor Corpトヨタ自動車株式会社信越化学工業株式会社株式会社豊田自動織機
    • HIGUCHI KOICHIYAMATANI MASAAKIMURAMATSU HISASHISENBOKU KOICHIWATANABE TOSHIONAGAI TAKAYUKIKONDO TOSHIRO
    • C08L83/10C08K5/3477
    • C08J7/047C08J2369/00C08J2483/00C08L83/06C08L101/00C09D143/04C09D183/10Y10T428/31663C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) an organic-inorganic composite where a polysiloxane with hydrolyzable silyl groups and/or SiOH groups and a vinyl polymer are bound to each other via Si-C bond and (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state. This curable composition, because the ultraviolet light absorber is prevented from being washed away owing to siloxane crosslinking and the organic-inorganic composite rich in weatherability is used as a binder, gives ultraviolet-absorbing coating film of high water resistance and solvent resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成保护涂膜的可固化组合物,其不含长期使用下的开裂,脱粘和变黄以及耐候性优良的缺点,并提供使用该组合物的涂布制品。 解决方案:可固化组合物包含(A)其中具有可水解甲硅烷基和/或SiOH基的聚硅氧烷和乙烯基聚合物通过Si-C键彼此结合的有机 - 无机复合物,(B)有机紫外线 光吸收剂在150℃下保持24小时,分子量为500以上,质量残留率为95%以上。 该可固化组合物由于防止紫外光吸收剂被硅氧烷交联而被洗涤,并且将具有耐候性的有机 - 无机复合材料用作粘合剂,得到具有高耐水性和耐溶剂性的紫外线吸收涂膜。 当用这种可固化组合物涂覆/固化耐候性差的制品时,防止了制品的变色和/或变质,并且可赋予制品良好的耐候性。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Curable composition and coated article
    • 可固化组合物和涂层物品
    • JP2007231060A
    • 2007-09-13
    • JP2006051759
    • 2006-02-28
    • Shin Etsu Chem Co LtdToyota Industries CorpToyota Motor Corpトヨタ自動車株式会社信越化学工業株式会社株式会社豊田自動織機
    • HIGUCHI KOICHIYAMATANI MASAAKIMURAMATSU HISASHISENBOKU KOICHIWATANABE TOSHIONAGAI TAKAYUKIKONDO TOSHIRO
    • C08L101/10C08K5/3477C08K5/5415
    • C09D183/06C08L83/06C09D143/04C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) a vinyl polymer where hydrolyzable silyl groups and/or SiOH groups and organic ultraviolet-absorbing groups are bound to the side chains, (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state, and (C) an organosilicon compound having in the molecule a nitrogen atom and an alkoxysilyl group. This curable composition, because being markedly improved in light resistance, prevented from the ultraviolet light absorber's being washed away and used as a weatherability-rich binder, gives ultraviolet-absorbing coating film of high water resistance, high solvent resistance and high light resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成保护涂膜的可固化组合物,其不含长期使用下的开裂,脱粘和变黄以及耐候性优良的缺点,并提供使用该组合物的涂布制品。 解决方案:可固化组合物包含(A)其中水解性甲硅烷基和/或SiOH基团和有机紫外线吸收基团与侧链结合的乙烯基聚合物,(B)分子中的有机紫外线吸收剂500以上 重量和95%以上的质量残留百分比,在150℃下保持打开状态24小时,(C)分子内具有氮原子和烷氧基甲硅烷基的有机硅化合物。 该可固化组合物由于耐光性显着提高,防止紫外线吸收剂被洗去并用作耐候脆性粘合剂,得到耐水性高,耐溶剂性高,耐光性高的紫外线吸收性涂膜。 当用这种可固化组合物涂覆/固化耐候性差的制品时,防止了制品的变色和/或变质,并且可赋予制品良好的耐候性。 版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • Coating agent composition, method for producing the same and article coated or surface-treated with the composition
    • 涂料代理组合物,其制备方法和用组合物涂覆或表面处理的物品
    • JP2008174604A
    • 2008-07-31
    • JP2007007675
    • 2007-01-17
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • TSUCHIDA KAZUHIROYAMATANI MASAAKI
    • C09D139/02C09C1/00C09C3/10C09C3/12C09D4/00C09K3/18
    • C08F8/42C03C25/40C09D139/02C09D143/04C08F26/02
    • PROBLEM TO BE SOLVED: To obtain a coating agent composition that has a water solubility and adhesion and serves as a primer or modifier for improving many properties including mechanical strength, water and boiling water resistance and weatherability, to provide a method for producing the same and to obtain an article coated or surface-treated with the composition.
      SOLUTION: The coating agent composition comprises a silicon-containing water-soluble polymer compound having a repeating unit represented by the formula (1) (10≤m≤260; 1≤n≤100; R
      1 is a hydrogen atom, an alkyl group or an acetyl group; a and b are each 1-3; X is an alkylene chain which may contain a substituent group; the substituent group is an alkyl group; Y is a direct bond, an oxygen atom or a CHR
      5 group; R
      2 -R
      5 are each a hydrogen atom or an alkyl group and R
      3 or R
      4 and R
      5 may be bonded to form a saturated carbon ring) and a plurality of primary amino groups, hydrolyzable silyl groups and/or silanol groups and an organic solvent and/or water.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了获得具有水溶性和粘合性并用作底漆或改性剂的涂料组合物,用于改善许多性能,包括机械强度,耐水和耐沸水性和耐候性,提供一种生产方法 并且获得用该组合物涂覆或表面处理的制品。 解决方案:涂料组合物包含具有由式(1)表示的重复单元的含硅水溶性高分子化合物(10≤m≤260;1≤n≤100; R 1 < SP>是氢原子,烷基或乙酰基; a和b各自为1-3; X为可以含有取代基的亚烷基链;取代基为烷基,Y为直接键, 氧原子或CHR 5 基团; R SP2各自为氢原子或烷基,R 3为 或者可以将R 4 和R 5 键合以形成饱和碳环)和多个伯氨基,可水解甲硅烷基和/或硅烷醇基 和有机溶剂和/或水。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Photoreactive group-containing siloxane compound, process for producing the same, and photocurable resin composition and article having cured film thereof
    • 含有光固化性基团的硅氧烷化合物,其制造方法和可光固化的树脂组合物及其固化膜的制品
    • JP2007308674A
    • 2007-11-29
    • JP2006192436
    • 2006-07-13
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • YOSHIKAWA YUJIYAMATANI MASAAKI
    • C08L83/07C08L83/06C08L83/08C09D4/02C09D7/12C09D155/00C09D183/04C09D183/10
    • C08G77/14C08G77/045C08G77/16C08G77/18C08G77/20C08G77/50C08L83/04C08L83/14Y10T428/31663
    • PROBLEM TO BE SOLVED: To provide a photoreactive group-containing siloxane compound imparting scratch resistance, crack resistance, a stainproofing effect of preventing staining by staining materials and wiping properties for a permanent marker to a substrate, provide a process for producing the photoreactive group-containing siloxane compound, and provide a photocurable resin composition and an article having a cured film of the photocurable resin composition. SOLUTION: The photoreactive group-containing siloxane compound is produced by subjecting a system comprising (a) a photoreactive group-containing alkoxy silane being either one kind or two or more kinds selected from the group consisting of photoreactive group-containing alkoxy silanes of formulae (1)-(5) wherein in the case of one kind of photoreactive group-containing alkoxy silane, it is a trialkoxysilane and in the case of two or more kinds thereof, it is constituted of 70 mol% or more trialkoxysilane and (b) a dimethyl siloxane containing hydrolyzable groups at both ends represented by formula (6) to hydrolytic condensation with an excess of water over that required to complete the hydrolytic condensation of all the alkoxy groups in the presence of a basic catalyst. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供赋予耐刮擦性,抗裂性,防止染色的污渍的防污效果和对基材的永久性标记的擦拭性能的含光反应性基团的硅氧烷化合物,提供一种制备 提供光固化性树脂组合物和具有光固化性树脂组合物的固化膜的制品。 解决方案:含有光反应性基团的硅氧烷化合物是通过使(A)含有光反应性基团的烷氧基硅烷为选自由含有光反应性基团的烷氧基硅烷中的一种或两种以上的一种或两种以上的系统 式(1) - (5)其中,在一种含光反应性基团的烷氧基硅烷的情况下,它是三烷氧基硅烷,在两种或更多种的情况下,由70摩尔%以上的三烷氧基硅烷和 (b)在碱性催化剂存在下,由式(6)表示的两端含有可水解基团的二甲基硅氧烷与过量的水进行水解缩合,以完成所有烷氧基的水解缩合。 版权所有(C)2008,JPO&INPIT
    • 8. 发明专利
    • Flame-retardant resin composition and its molding
    • 阻燃树脂组合物及其成型
    • JP2006152246A
    • 2006-06-15
    • JP2005239301
    • 2005-08-22
    • Mitsubishi Gas Chem Co IncShin Etsu Chem Co Ltd三菱瓦斯化学株式会社信越化学工業株式会社
    • ITAGAKI AKINARITANAKA MASAKIYAMATANI MASAAKIADACHI TAKAHIRONORISUE YASUMASAKANAYAMA SATOSHI
    • C08L69/00C08G65/326C08L51/04C08L71/12C08L83/04
    • PROBLEM TO BE SOLVED: To obtain a flame-retardant resin composition that does not use a halogen-based or phosphorus-based flame retardant causing environmental pollution and performance degradation, satisfies a severe flame-retardant level equal to that obtained by using the halogen-based or phosphorus-based flame retardant and yet has excellent impact strength, weld strength, mold deposit resistance and appearance and its molding.
      SOLUTION: The flame-retardant resin composition is obtained by mixing (A) 100 parts by mass of a polycarbonate resin with (B) 5-40 parts by mass of a rubber-modified styrene/(meth)acrylonitrile-based graft copolymer obtained by polymerizing at least a styrene-based monomer with (meth)acrylonitrile in the presence of rubber and (C) 0.01-3.0 parts by mass of an alkali metal or an alkaline earth metal salt of sulfonic acid of a PPE (polyphenylene ether) oligomer. The molding is obtained by molding the composition.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题为了获得不使用引起环境污染和性能降解的卤素系或磷系阻燃剂的阻燃性树脂组合物,满足与通过使用 卤素或磷系阻燃剂,但具有优异的冲击强度,焊接强度,抗霉蚀性和外观及其成型性。 解决方案:阻燃树脂组合物通过将(A)100质量份聚碳酸酯树脂与(B)5-40质量份橡胶改性苯乙烯/(甲基)丙烯腈系接枝 通过在橡胶存在下使至少一种苯乙烯类单体与(甲基)丙烯腈聚合而获得的共聚物和(C)0.01-3.0质量份的PPE的磺酸的碱金属或碱土金属盐(聚苯醚 )低聚物。 通过模塑该组合物获得模制品。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • Antireflection film, coating agent composition for forming the antireflection film, and article provided with the antireflection film
    • 抗反射膜,形成抗反射膜的涂料组合物,以及提供抗反射膜的文章
    • JP2006139259A
    • 2006-06-01
    • JP2005269697
    • 2005-09-16
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • YAMATANI MASAAKISATO KAZUHARU
    • G02B1/11B32B27/00C08G77/50G02B1/10
    • PROBLEM TO BE SOLVED: To provide an antireflection film containing an F atom and a Si atom superior in alkaline durability, the anti-scratching properties, and the anti-stain properties and having a three-dimensional crosslinking structure, a coating agent composition for forming the antireflection film, an optical article on which the antireflection film is formed and a multilayer laminate of the optical article. SOLUTION: The antireflection film having superior alkaline durability is the three-dimensionally crosslinked antireflection film, having a F atom and a Si atom provided to the outermost layer of a synthetic resin transparent substrate, (I) the crosslinking structure is constituted of a Si-O-Si bond and a Si-C 2 H 4 -(CF 2 ) n -C 2 H 4 -Si bond (n is 4 or 6), (II) the ratio of F atom to Si atom is F/Si=8.0-10.0 (mol ratio), and (III) 90-100 mol% of perfluoroalkyl group, represented by -C 2 H 4 -(CF 2 ) a F (a is 4, 6, 8, 10, or 12), is contained in the total monovalent organic substituent bonded to Si. The antireflection film and the article on whose surface the same is formed are superior in alkaline durability, anti-scratching properties and the anti-stain properties. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供含有碱性耐久性优异的F原子和Si原子的防反射膜,抗划伤性,抗污染性和具有三维交联结构的涂布剂 用于形成防反射膜的组合物,其上形成有防反射膜的光学制品和光学制品的多层层压体。 解决方案:具有优异的碱性耐久性的抗反射膜是三维交联的抗反射膜,其具有设置在合成树脂透明基板的最外层的F原子和Si原子,(I)交联结构由 Si-O-Si键和Si-C 2 - (CF 2 (II)F原子与Si原子的比例为F / Si = 8.0-10.0(摩尔) 比例),和(III)由-C SB 2 - (CF 2 SB 2)表示的全氟烷基的90-100摩尔% 在与Si结合的总的一价有机取代基中包含SB> a F(a为4,6,8,10或12)。 防反射膜及其表面相同的制品具有优异的碱性耐久性,抗刮伤性和抗污染性。 版权所有(C)2006,JPO&NCIPI