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1. 发明专利

JP2006240294A Coated member 有权
标题翻译：涂层会员
公开(公告)号：JP2006240294A
公开(公告)日：2006-09-14
申请号：JP2006024978
申请日：2006-02-01
申请人： Shin Etsu Chem Co Ltd , Toyota Industries Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 信越化学工業株式会社 , 株式会社豊田自動織機
发明人： KOMORI TAKASHI , MURAMATSU HISASHI , HIDAKA OSAMU , YASUNAGA KENICHI , NAGAI TAKAYUKI , YAMATANI MASAAKI , HIGUCHI KOICHI
IPC分类号： B32B7/02
摘要： PROBLEM TO BE SOLVED: To provide a coated member having a coating film with excellent adhesion and crack resistance.
SOLUTION: The coated member comprises a resinous substrate 1, a primer layer 2 comprising a resin primer formed on a surface of the resinous substrate 1, and a hard coat layer 3 containing a flexibility-imparting agent 31 formed on the primer layer 2. The primer layer 2 and/or the hard coat layer 3 are characterized by containing an ultraviolet ray-absorbing agent 20 or 30. Also, the resinous substrate 1 is preferably a sunroof substrate.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有优异的粘附性和抗裂性的涂膜的涂布部件。解决方案：涂覆部件包括树脂基材1，底漆层2，其包含在树脂基材1的表面上形成的树脂底漆，以及硬涂层3，其含有形成在底漆层上的柔性赋予剂31 底漆层2和/或硬涂层3的特征在于含有紫外线吸收剂20或30.此外，树脂基材1优选为天窗基材。版权所有（C）2006，JPO＆NCIPI

2. 发明专利

JP2005179547A Resin composition for manufacturing automotive exterior part 审中-公开
标题翻译：用于制造汽车外部部件的树脂组合物
公开(公告)号：JP2005179547A
公开(公告)日：2005-07-07
申请号：JP2003424076
申请日：2003-12-22
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , IWAKI MITSUJI , NAKAMURA MITSURU , SUZUKI MASAMI , MURAMATSU SHIGERU , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： B62D25/16 , C08K3/04 , C08K3/34 , C08K5/524 , C08K5/5393 , C08L77/00
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for manufacturing automotive exterior parts excellent in the balance among fluidity, heat resistance, impact resistance, rigidity and a linear expansion coefficient and also excellent in electroconductivity, good coating adhesion and stagnation thermal stability (thermal stability when retained in a molten state for long hours).
SOLUTION: The resin composition for manufacturing automotive exterior parts comprises a modified product {a component (A)} obtained by reacting, in a molten state, (A1) a polyphenylene ether, (A2) a hydrogenated product of a block copolymer comprising a vinyl aromatic compound polymer block A and a conjugated diene compound polymer block B, (A3) an unsaturated acid anhydride and/or an unsaturated acid and (A4) a radical initiator, and, incorporated therewith, a polyamide {a component (B)}, a pentaerythritol phosphite compound {a component (C)}, a phosphonite compound {a component (D)}, magnesium silicate (talc) {a component (E)}, electroconductive carbon black {a component (F)} and an ethylene-vinyl alcohol copolymer {a component (G)}, each in a specific ratio.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决问题的方案：提供流动性，耐热性，耐冲击性，刚性和线性膨胀系数之间的平衡优异的汽车外用部件的树脂组合物，并且还具有优异的导电性，良好的涂层附着力和停滞热稳定性（长时间保持在熔融状态时的热稳定性）。解决方案：用于制造汽车外部部件的树脂组合物包括通过使熔融状态下的（A1）聚苯醚（A2）与嵌段共聚物的氢化产物（A2）反应获得的改性产物äa组分（A）乙烯基芳族化合物聚合物嵌段A和共轭二烯化合物聚合物嵌段B，（A3）不饱和酸酐和/或不饱和酸和（A4）自由基引发剂，并且与其结合，聚酰胺ä组分（B）} ，季戊四醇亚磷酸酯化合物ä组分（C）}，亚膦酸酯化合物组分（D）}，硅酸镁（滑石）组分（E）}，导电炭黑组分（F）}和乙烯 - 乙烯醇共聚物 äa组分（G）}，每个以具体的比例。版权所有（C）2005，JPO＆NCIPI

3. 发明专利

JP2006124647A Resin composition, resin molding and method for producing the same 有权
标题翻译：树脂组合物，树脂模塑及其制造方法
公开(公告)号：JP2006124647A
公开(公告)日：2006-05-18
申请号：JP2005224320
申请日：2005-08-02
申请人： Toyoda Gosei Co Ltd , Toyota Motor Corp , トヨタ自動車株式会社 , 豊田合成株式会社
发明人： TSUTSUMI DAISUKE , HAYASHI KOICHIRO , YASUNAGA KENICHI
IPC分类号： C08L101/00 , B60K15/03 , C08K7/06
CPC分类号： B29C65/02 , B29B9/14 , B29B15/122 , B29C45/0005 , B29C65/20 , B29C66/1312 , B29C66/543 , B29C66/71 , B29C66/7212 , B29C66/73921 , B29K2105/06 , B29L2031/7172 , B60K15/03177 , Y10T428/1352 , Y10T428/1372 , B29K2307/04 , B29K2077/00 , B29K2277/10 , B29K2067/006 , B29K2059/00 , B29K2081/04 , B29K2079/085 , B29K2077/10 , B29K2075/00 , B29K2071/00 , B29K2067/003 , B29K2067/00 , B29K2029/04 , B29K2027/18 , B29K2027/12 , B29K2027/08 , B29K2027/06 , B29K2023/086 , B29K2023/00 , B29K2001/00
摘要： PROBLEM TO BE SOLVED: To obtain a resin molding (especially fuel-based part) satisfying both specific properties (especially fuel barrier properties) and impact resistance. SOLUTION: The resin molding is obtained by dispersing fibers 2 that have a melting point higher than that of a thermoplastic resin or are infusible and have 4-20 mm length to the matrix of the thermoplastic resin 1. The resin molding is molded at a molding temperature higher than the melting point of the thermoplastic resin and lower than the melting point of the fiber. The resin molding is preferably applicable to a fuel-based part (fuel tank, etc.) to be exposed to a fuel and in the application, a thermoplastic resin having ≤1.0×10 -11 m 3 ×m/m 2 /sec/MPa fuel permeability coefficient to CE10 at 65°C is preferably used. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：获得满足特定性能（特别是燃料阻挡性）和耐冲击性的树脂模制品（特别是燃料基部件）。解决方案：通过将熔点高于热塑性树脂的纤维2或不熔融且具有4-20mm长度的纤维2分散到热塑性树脂1的基体上而获得树脂模制品。将树脂模塑成型在高于热塑性树脂的熔点的模塑温度下并低于纤维的熔点。树脂成形体优选适用于要暴露于燃料的燃料基部件（燃料箱等），在应用中，具有≤1.0×10 -11 m 3 ×m / m 2 /秒/ MPa。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2005187624A Propylene-based resin composition and its molding 有权
标题翻译：丙烯基树脂组合物及其成型
公开(公告)号：JP2005187624A
公开(公告)日：2005-07-14
申请号：JP2003430316
申请日：2003-12-25
申请人： Japan Polypropylene Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 日本ポリプロ株式会社
发明人： NAKAYAMA KOICHI , MASUDA KENJI , UBOSHI RYOJI , ZANKA YUKITO , NAGAI TAKAYUKI , YASUNAGA KENICHI , ISOBE YASUMITSU
IPC分类号： B05D1/04 , B05D7/24 , C08J7/04 , C08K3/04 , C08K3/34 , C08L53/00
摘要： PROBLEM TO BE SOLVED: To provide a propylene-based resin composition which has an excellent balance between mechanical properties and coatability, particularly electroconductivity enabling electrostatic primerless coating with a water-based coating and a molding using the composition.
SOLUTION: The propylene-based resin composition comprises 100 pts.wt. of (A) a propylene-based resin composition containing (a) a propylene-ethylene block copolymer, (b) an ethylenic elastomer, (c) talc and, as necessary, (d) a styrenic hydrogenated block polymer rubber. (B) 1-15 pts.wt. of a polyhydroxy polyolefin and (C) 1-10 pts.wt. of an electroconductive carbon. The volume specific resistance of the propylene-based resin composition is ≤10
8 Ωcm. The contact angle of a waterdrop to the surface of a molding molded from the propylene-based resin composition is 65-80°. The propylene-based resin composition is for use in electrostatic coating and has an excellent balance among electroconductivity, coatability and impact strength. The molding obtained from the composition is presented.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供在机械性能和可涂布性之间具有优异平衡的丙烯类树脂组合物，特别是使用水性涂料进行静电无底漆涂布的导电性和使用该组合物的模塑。解决方案：丙烯类树脂组合物包含100重量份（A）丙烯类树脂组合物，其含有（a）丙烯 - 乙烯嵌段共聚物，（b）乙烯类弹性体，（c）滑石，必要时，（d）苯乙烯氢化嵌段聚合物橡胶。（B）1-15重量的多羟基聚烯烃和（C）1-10重量份的导电碳。丙烯类树脂组合物的体积电阻率为≤10 8 Ωcm。水滴与由丙烯类树脂组合物成型的成型体的表面的接触角为65〜80度。丙烯类树脂组合物用于静电涂布，并且在导电性，涂布性和冲击强度之间具有优异的平衡。提出从组合物得到的模制品。版权所有（C）2005，JPO＆NCIPI

5. 发明专利

JP2004231685A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231685A
公开(公告)日：2004-08-19
申请号：JP2003018618
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , YASUNAGA KENICHI , SEKITO TAKESHI
IPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 100 pts. wt. of a resin composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer (F). The above resin composition is prepared by previously melt kneading and pelletizing 10-60 pts. wt. of a modified material (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a specific proportion in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black (C1) having specified physical properties with the polyamide 6 (B) in a specific proportion, 0.01-10 pts. wt. of a carboxylic acid having ≥2 carboxy groups or its derivative (D) and 8-20 pts. wt. of calcium metasilicate (E) having specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

6. 发明专利

JP2006022131A Resin component for producing automobile exterior part 审中-公开
标题翻译：用于生产汽车外部零件的树脂组件
公开(公告)号：JP2006022131A
公开(公告)日：2006-01-26
申请号：JP2004198879
申请日：2004-07-06
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： OYAMA HAJIME , TAKAGI KIYOJI , SUZUKI MASAMI , YASUNAGA KENICHI , NAGAI TAKAYUKI
IPC分类号： C08L77/00 , C08L23/08 , C08L23/26
摘要： PROBLEM TO BE SOLVED: To provide a resin composition, excellent in rigidity, surface impact resistance, flowing property, electroconductivity, appearance and coating property which are required as an automobile exterior part-producing material, and also having a small shrinkage of the resin even on being exposed to a high temperature in coating time.
SOLUTION: This composition is obtained by blending the following (A) to (E) components: (A) 36-68 pts. wt. polyamide 6 resin having ≤120 mL/g ISO viscosity number and ≥1.5 {the terminal carboxy group (unit: μeq/g)/the terminal amino group (unit: μeq/g)}, (B) 15-25 pts. wt. ethylene-butene-1 copolymer graft-modified with maleic anhydride, (C) 1-4 pts. wt. electroconductive carbon black, (D) 15-30 pts. wt. talc not being surface-treated with a silane-coupling agent, and (E) 1-5 pts. wt. ethylene vinyl alcohol resin.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供作为汽车外部零件生产材料所需的具有优异的刚性，耐表面冲击性，流动性，导电性，外观和涂布性的树脂组合物，并且还具有小的收缩率树脂即使在涂布时间内暴露于高温下也是如此。解决方案：通过将以下（A）至（E）组分混合得到该组合物：（A）36-68份。重量。 ≥120mL / g ISO粘度值和≥1.5％末端羧基（单位：μeq/ g）/末端氨基（单位：μeq/ g）}，（B）15-25 pts的聚酰胺6树脂。重量。用马来酸酐接枝改性的乙烯 - 丁烯-1共聚物，（C）1-4份。重量。导电炭黑，（D）15-30点。重量。滑石不用硅烷偶联剂进行表面处理，（E）1-5份。重量。乙烯乙烯醇树脂。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2004231686A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231686A
公开(公告)日：2004-08-19
申请号：JP2003018622
申请日：2003-01-28
申请人： Daihatsu Motor Co Ltd , Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , ダイハツ工業株式会社 , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , YASUNAGA KENICHI , SEKITO TAKESHI , FUTAI MASAHITO , YAMAGUCHI SUSUMU , KUSHIRO TAKAHIRO
IPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 95-100 pts. wt. of a composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer. The composition is prepared by previously melt kneading and pelletizing 10-60 pts. wt. of a modified resin (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black having specified physical properties with the polyamide 6 and 8-20 pts. wt. of calcium metasilicate (D) having the surface treated with an aminosilane coupling agent and specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

8. 发明专利

JP2003277602A Resin composition for exterior of automobile 有权
标题翻译：汽车外部树脂组合物
公开(公告)号：JP2003277602A
公开(公告)日：2003-10-02
申请号：JP2002080442
申请日：2002-03-22
申请人： Asahi Kasei Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 旭化成株式会社
发明人： NIINO MASAHIKO , YASUNAGA KENICHI , SEKITO TAKESHI
IPC分类号： C08L77/00 , C08K3/16 , C08K3/24
摘要： PROBLEM TO BE SOLVED: To obtain a polyamide-polyphenylene ether-based resin composition for an exterior of an automobile, satisfying a close adhesion to a coating material for the exterior of the automobile and the prevention of reduction of an Izod impact strength after its formation and retention.
SOLUTION: The polyamide-polyphenylene ether-based resin composition for the exterior of the automobile is characterized by containing (A) 50-95 pts.wt. of a polyamide 6,6 having ≤37 relative viscosity in formic acid, (B) 5-50 pts.wt. of a polyphenylene ether, (C) 1-30 pts.wt. of a block copolymer of an ABAB type hydrogenated aromatic vinyl-a conjugated diene compound [based on 100 pts.wt. (A)+(B)] and (D) a halogen salt having ≤100 μm mean particle diameter and a transition metal salt, and having 3,700-20,000 ppm halogen concentration in the composition and 0.001-0.08 concentration ratio of the transition metal to the halogen (the transition metal concentration/the halogen concentration).
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：为了获得汽车外部的聚酰胺 - 聚苯醚类树脂组合物，满足与汽车外部用涂料的紧密粘合性，防止艾佐德冲击强度降低其形成和保留后。解决方案：用于汽车外部的聚酰胺 - 聚苯醚类树脂组合物的特征在于含有（A）50-95重量份的在甲酸中具有≤37相对粘度的聚酰胺6,6（5-50重量份）的聚苯醚，（C）1-30重量份的ABAB型氢化芳族乙烯基 - 共轭二烯化合物的嵌段共聚物[基于100重量份（A）+（B）]和（D）平均粒径≤100μm的卤素盐和过渡金属盐，组合物中的卤素浓度为3,700-20,000ppm，过渡金属浓度为0.001-0.08 卤素（过渡金属浓度/卤素浓度）。版权所有（C）2004，JPO

9. 发明专利

JP2004230927A Resin composition for manufacture of automobile exterior parts 审中-公开
公开(公告)号：JP2004230927A
公开(公告)日：2004-08-19
申请号：JP2003018627
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： B62D29/04 , C08K3/04 , C08K7/02 , C08K9/04 , C08L53/02 , C08L71/12 , C08L77/02
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for manufacture of automobile exterior parts having excellent impact resistance, fluidity, dimension stability, conductivity, appearance and coating adhesiveness.
SOLUTION: This resin composition for manufacture of automobile exterior parts is obtained by previously melting and kneading the modified resin (A), which is obtained by reacting PPE (A1), hydrogen additive of SEBS (A2), conductive carbon black having a small specific surface area (A3) and unsaturated acid anhydride and/or unsaturated acid (A4) in the melting condition, of 10-60 parts weight, polyamide 6 (B) having a specified physical property of 10-60 parts weight, pellets (C) obtained by melting and kneading conductive carbon black (C1) having a large specific surface area and the polyamide 6 (C2) of 10-40 parts weight, and metasilicic calucium (D) having a specified physical property of 8-20 parts weight to form the pellet-type composition, and dry-blending ethylene-vinylalcohol copolymer (E) of 0.2-5 parts weight in relation to the pellet-type composition of 95-100 parts weight. This resin composition has a specified micro structure. The described characteristics are thereby obtained.
COPYRIGHT: (C)2004,JPO&NCIPI

10. 发明专利

JP2004231684A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231684A
公开(公告)日：2004-08-19
申请号：JP2003018613
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： C08L77/02 , C08K3/04 , C08K3/16 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 100 pts. wt. of a resin composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer (F). The above resin composition is prepared by previously melt kneading and palletizing 10-60 pts. wt. of a modified resin (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a specific proportion in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black (C1) having specified physical properties with the polyamide 6 (B) in a specific proportion, 10-40 pts. wt. of pellets (D) obtained by melt kneading a uniform mixture (D1) of potassium iodide with cuprous iodide with the polyamide 6 (B) in a specific proportion and 8-20 pts. wt. of calcium metasilicate (E) having specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

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