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    • 2. 发明授权
    • Thermoplastic elastomers
    • 热塑性弹性体
    • US4600749A
    • 1986-07-15
    • US348335
    • 1982-02-12
    • Saburo MinekawaKoretaka YamaguchiKazuo ToyomotoEinosuke FujimotoNorikatu NakayamaShikazo Senoh
    • Saburo MinekawaKoretaka YamaguchiKazuo ToyomotoEinosuke FujimotoNorikatu NakayamaShikazo Senoh
    • C08F2/00C08F297/04C08L53/02
    • C08L53/02C08F297/044
    • Thermoplastic elastomers of conjugated diolefins having 4 to 6 carbon atoms and monovinyl aromatic hydrocarbons are prepared by polymerizing 8 to 65 parts by weight of a monomer mixture A.sub.1 comprising a conjugated diolefin having 4 to 6 carbon atoms and a monovinyl aromatic hydrocarbon in a weight ratio of 85-10:15-90 in a hydrocarbon solvent and an inert atmosphere in the presence of 0.2 to 20 mmol., per 100 g. of the total amount of the mixture A.sub.1 and the mixture A.sub.2 described below, of a monolithium hydrocarbon calculated as active lithium to form an active copolymer, and after substantial completion of the polymerization, copolymerizing said active copolymer with 92 to 35 parts by weight of a monomer mixture A.sub.2 comprising the same conjugated diolefin having 4 to 6 carbon atoms and monovinyl aromatic hydrocarbon as said mixture A.sub.1 in a weight ratio of 95-20:5-80, such that the total amount of said mixtures A.sub.1 and A.sub.2 is 100 parts by weight, to thereby obtain a final copolymer having a monovinyl aromatic content of 10 to 70% by weight based on the total amount of said mixtures A.sub.1 and A.sub.2. The thus obtained thermoplastic elastomers have at least four polymeric blocks, and are comparable in elastic property to conventional thermoplastic elastomers and excellent in thermal resistance, resistance to oils and processability. Further, said thermoplastic elastomer does not require vulcanization or chemical cross-linking, and can be molded into an article having an excellent shape maintenance property.
    • 通过将8至65重量份的包含具有4-6个碳原子的共轭二烯烃和单乙烯基芳族烃的单体混合物A1与重量比为1的聚合,制备具有4至6个碳原子的共轭二烯烃和单乙烯基芳族烃的热塑性弹性体 85-10:15-90在烃溶剂和惰性气氛中,每100克存在0.2-20mmol。 的混合物A1和下述混合物A2的总量的单轴烃作为活性锂计算以形成活性共聚物,并且在基本上完成聚合之后,将所述活性共聚物与92〜35重量份的 单体混合物A2,其包含具有4至6个碳原子的相同的共轭二烯烃和作为所述混合物A1的单乙烯基芳烃,重量比为95-20:5-80,使得所述混合物A1和A2的总量为100份 重量,从而获得基于所述混合物A1和A2的总量,单乙烯基芳族化合物含量为10至70重量%的最终共聚物。 由此获得的热塑性弹性体具有至少四个聚合物嵌段,并且在弹性方面与常规热塑性弹性体相当,并且耐热性,耐油性和加工性优异。 此外,所述热塑性弹性体不需要硫化或化学交联,并且可以模塑成具有优异形状维持性的制品。
    • 8. 发明授权
    • Method for removing heavy metal ions from contaminated water and a
porous membrane usable therefor
    • 从污染水中除去重金属离子的方法及其可用的多孔膜
    • US5087372A
    • 1992-02-11
    • US493751
    • 1990-03-15
    • Kazuo ToyomotoTakehiko Otoyo
    • Kazuo ToyomotoTakehiko Otoyo
    • B01D61/00B01D67/00B01J20/28B01J45/00C02F1/44G21F9/12
    • B01D67/0093B01D61/00B01J45/00C02F1/444G21F9/12B01D2323/38Y10S210/912
    • A method for simultaneously removing a plurality of different heavy metal ions from contaminated water is disclosed. A plurality of different heavy metal ions can be simultaneously, efficiently removed by filtering contaminated water through a porous membrane comprising a membranous, porous resin matrix and a plurality of side chains chemically bound to both surfaces and pore wall surfaces of the matrix, which side chains each have a chelate group, preferably an iminodiacetic acid group, and terminating the filtration when the concentration of a determinant heavy metal ion in the filtrate reaches a predetermined level. By the method of the present invention, a plurality of different heavy metal ions, such as a cobalt ion and a nickel ion, can be simultaneously, efficiently removed from contaminated water, such as water to be used for and waste water from a nuclear power generator, on a commercial scale.
    • 公开了同时从污染水中除去多种不同重金属离子的方法。 多个不同的重金属离子可以同时有效地通过过滤污染的水通过多孔膜而被有效地除去,所述多孔膜包括膜多孔树脂基质和化学结合到基质的两个表面和孔壁表面的多个侧链,该侧链 各自具有螯合基团,优选亚氨基二乙酸基团,并且当滤液中的决定性重金属离子的浓度达到预定水平时终止过滤。 通过本发明的方法,多种不同的重金属离子如钴离子和镍离子可以同时被有效地从污染的水中除去,例如用于来自核电的废水和污水 发电机,商业规模。