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1. 发明申请

WO2006045765A1 REVERSE FLOW REACTOR WITH INTEGRATED SEPARATION AND PROCESS FOR THE EMPLOYING THIS REACTOR 审中-公开
标题翻译：具有集成分离的反向流动反应器和使用该反应器的方法
公开(公告)号：WO2006045765A1
公开(公告)日：2006-05-04
申请号：PCT/EP2005/055483
申请日：2005-10-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BOS, Alouisius, Nicolaas, Renee , KABRA, Girish, Rajkumar , LANGE, Jean-Paul
发明人： BOS, Alouisius, Nicolaas, Renee , KABRA, Girish, Rajkumar , LANGE, Jean-Paul
IPC分类号： B01J8/04
CPC分类号： B01D51/10 , B01D53/02 , B01D2253/10 , B01D2253/202 , B01D2257/204 , B01D2257/30 , B01D2257/80 , B01J8/0446 , B01J2208/00106 , B01J2208/00699 , B01J2208/00707 , B01J2208/025
摘要： The present invention pertains to a reverse-flow reactor comprising at least one catalyst bed which is preceded and followed by at least one bed containing selectively adsorbing material, and its application for in a process for the removal of contaminants from a process stream.
摘要翻译：本发明涉及一种反流反应器，其包含至少一个催化剂床，其前面和后面是至少一个含有选择性吸附材料的床，以及其在从工艺流中除去污染物的方法中的应用。

2. 发明申请

WO2011141546A2 PROCESS FOR LIQUEFYING A CELLULOSIC MATERIAL 审中-公开
标题翻译：用于液化材料的方法
公开(公告)号：WO2011141546A2
公开(公告)日：2011-11-17
申请号：PCT/EP2011/057695
申请日：2011-05-12
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VON HEBEL, Klaas Lambertus , LANGE, Jean-Paul
发明人： VON HEBEL, Klaas Lambertus , LANGE, Jean-Paul
IPC分类号： C08H8/00 , C10G1/06
CPC分类号： C10G1/002 , C08H8/00 , C10G1/065 , C10G3/50 , C10G2300/1014 , C10G2300/208 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/04 , C10L2200/0469 , C10L2290/544 , Y02E50/13 , Y02P30/20
摘要： A process for liquefying a cellulosic material to produce a liquefied product, which process comprises contacting the cellulosic material simultaneously with - an acid catalyst; - a solvent mixture containing water and a co-solvent, which co-solvent comprises one or more polar solvents and which co-solvent is present in an amount of more than or equal to 10% by weight and less than or equal to 95% by weight, based on the total weight of water and co-solvent; - a hydrogenation catalyst; and - a source of hydrogen. Products obtained from the above process and use of such products to prepare biofuels.
摘要翻译：一种用于液化纤维素材料以产生液化产品的方法，该方法包括将纤维素材料与酸催化剂同时接触; - 含有水和共溶剂的溶剂混合物，所述共溶剂包含一种或多种极性溶剂，并且所述助溶剂的存在量为大于或等于10重量％且小于或等于95重量％，基于水和共溶剂的总重量; - 氢化催化剂; 和 - 氢源。从上述方法获得的产品和使用这些产品制备生物燃料。

3. 发明申请

WO2009077606A2 GASOLINE COMPOSITION AND PROCESS FOR THE PREPARATION OF ALKYLFURFURYL ETHER 审中-公开
标题翻译：汽油组合物和制备烷基糠醇醚的方法
公开(公告)号：WO2009077606A2
公开(公告)日：2009-06-25
申请号：PCT/EP2008/067937
申请日：2008-12-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HAAN, Rene Johan , LANGE, Jean-Paul
发明人： HAAN, Rene Johan , LANGE, Jean-Paul
IPC分类号： C10L1/02 , C10L1/18 , C07D307/42
CPC分类号： C10L1/023 , C10L1/14 , C10L1/1824 , C10L1/1855 , C10L1/19 , C10L10/10
摘要： The invention provides a gasoline composition comprising in the range of from 0.1 to 30 wt% alkylfurfuryl ether with an alkyl group having 1 to 4 carbon atoms. The invention further provides a process for the preparation of a gasoline composition comprising blending the alkylfurfuryl ether in a gasoline base fuel, and a process for the preparation of an alkylfurfuryl ether wherein an alkyl alcohol having in the range of 1 to 4 carbon atoms is reacted with furfuryl alcohol by contacting a liquid phase comprising the alkyl alcohol and furfuryl alcohol with an acidic zeolite catalyst at a temperature in the range of from 50 to 200 °C.
摘要翻译：本发明提供了一种汽油组合物，其包含0.1-30重量％的具有1-4个碳原子的烷基的烷基糠基醚。本发明进一步提供了一种制备汽油组合物的方法，该方法包括将烷基糠基醚在汽油基础燃料中混合，以及制备烷基糠基醚的方法，其中使具有1至4个碳原子的烷基醇反应与糠醇接触，其中包含烷基醇和糠醇的液相与酸性沸石催化剂在50-200℃的温度下接触。

4. 发明申请

WO2003042141A1 METHOD FOR THE CATALYTIC CONVERSION OF ALKYLENE CARBONATE WITH A MG, AL MIXED (HYDR) OXIDE CATALYST 审中-公开
标题翻译：甲基丙烯酸乙酯与氢氧化铝催化剂的催化转化方法
公开(公告)号：WO2003042141A1
公开(公告)日：2003-05-22
申请号：PCT/EP2002/012640
申请日：2002-11-12
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE JONGE, Johannes, Petrus , LANGE, Jean-Paul , PELLO, Dennis, Humphrey, Louis
发明人： DE JONGE, Johannes, Petrus , LANGE, Jean-Paul , PELLO, Dennis, Humphrey, Louis
IPC分类号： C07C29/09
CPC分类号： C07C29/095 , B01J21/10 , B01J37/03 , C07C68/065 , Y02P20/52 , C07C69/96 , C07C31/202 , C07C31/205
摘要： Method for catalytic conversion of alkylene carbonate, wherein alkylene carbonate is contacted with C 1 -C 5 aliphatic alcohol and/or water in the presence of Mg, A1 mixed (hydr) oxide catalyst having a Mg: A1 molar ratio in the range of from 4 to 20.
摘要翻译：碳酸亚烷基酯的催化转化方法，其中碳酸亚烷基酯在Mg，Al混合（氢氧化物）氧化物催化剂存在下与C1-C5脂族醇和/或水接触，Mg：A1摩尔比在4〜 20。

5. 发明申请

WO2011015385A1 PROCESS FOR PREPARING AN ESTER 审中-公开
标题翻译：制备ESTER的方法
公开(公告)号：WO2011015385A1
公开(公告)日：2011-02-10
申请号：PCT/EP2010/055862
申请日：2010-04-29
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HAAN, Rene, Johan , LANGE, Jean-Paul
发明人： HAAN, Rene, Johan , LANGE, Jean-Paul
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , C07C67/00 , C07C69/24
摘要： A process for preparing an ester of formula (I): R 3 CH 2 - (CR 1 R 2 ) n -CH 2 -O-CO-(CR 1 R 2 ) n -CH 2 R 3 (I) wherein n is 1-3 and R 1 and R 2 are each, independently, a hydrogen atom or a carbon-linked organic group and R 3 is a carbon-linked organic group, by hydrogenation of a reactant selected from: (a) a lactone of formula (II) wherein n is 1-3 and R 1 and R 2 are each, independently, a hydrogen atom or a carbon-linked organic group and R 3 is a carbon-linked organic group; (b) an ester of a carboxylic acid of formula (III) R 4 -O-CO- (CR 1 R 2 ) n -CO-R 3 (III) wherein n is 1-3 and R 1 and R 2 are each, independently, a hydrogen atom or a carbon-linked organic group and R 3 and R 4 are a carbon-linked organic group; and c) a carboxylic acid of formula (IV) H-O-CO- (CR 1 R 2 ) n -CO-R 3 (IV) wherein n is 1-3 and R 1 and R 2 are each, independently, a hydrogen atom or a carbon-linked organic group and R 3 is a carbon-linked organic group; which process involves contacting the reactant with a heterogeneous catalyst comprising a hydrogenating metal in the presence of hydrogen, wherein the catalyst is a zeolite-free heterogeneous catalyst comprising a hydrogenating metal supported on a metal oxide or a mixed oxide.
摘要翻译：制备式（I）的酯的方法：R 3 -CH 2 - （CR 1 R 2）n -CH 2 -O-CO-（CR 1 R 2）n -CH 2 R 3（I）其中n为1-3，并且R 1和R 2各自独立地为氢原子或碳连接的有机基团，并且R 3是碳连接的有机基团，通过氢化选自以下的反应物：（a）式（II）的内酯，其中n为1-3且R 1和R 2各自为氢，独立地是氢原子或碳连接的有机基团，并且R 3是碳连接的有机基团; （b）式（III）的羧酸R 4 -O-CO-（CR 1 R 2）n -CO-R 3（III）的酯，其中n为1-3，并且R 1和R 2各自独立地为氢原子或碳键的有机基团，R 3和R 4为碳键的有机基团; 和c）式（Ⅳ）HO-CO-（CR1R2）n-CO-R3（Ⅳ）的羧酸，其中n为1-3，R 1和R 2各自独立地为氢原子或碳键连接的有机基团和R 3是碳键的有机基团; 该方法包括在氢气存在下使反应物与包含氢化金属的多相催化剂接触，其中所述催化剂是不含沸石的多相催化剂，其包含负载在金属氧化物上的氢化金属或混合氧化物。

6. 发明申请

WO2010136436A1 GASOLINE COMPOSITIONS 审中-公开
标题翻译：汽油组合物
公开(公告)号：WO2010136436A1
公开(公告)日：2010-12-02
申请号：PCT/EP2010/057132
申请日：2010-05-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , FELIX-MOORE, Allison , LANGE, Jean-Paul , SMITH, Johanne
发明人： FELIX-MOORE, Allison , LANGE, Jean-Paul , SMITH, Johanne
IPC分类号： C10L1/02 , C10L1/18 , C10L10/08 , C10L10/10
CPC分类号： C10L10/08 , C10L1/023 , C10L1/19 , C10L10/10
摘要： An unleaded gasoline composition comprising: (i) a gasoline base fuel; and (ii) component A, wherein component A is an alkyl alkenoate compound, or a mixture of alkyl alkenoate compounds, selected from compounds of formula I: wherein R 1 is a linear alkenyl group containing 3 to 5 carbon atoms, optionally substituted by a methyl group, and R 2 is a linear or branched alkyl group containing 1 to 6 carbon atoms. The gasoline composition of the present invention exhibits good lubricity.
摘要翻译：一种无铅汽油组合物，包括：（i）汽油基燃料; 或（ii）成分A，其中组分A为烷基烯酸酯化合物，或选自式I化合物的烷基烯酸酯化合物的混合物：其中R 1为含有3至5个碳原子的直链烯基，任选被甲基并且R 2是含有1至6个碳原子的直链或支链烷基。本发明的汽油组合物表现出良好的润滑性。

7. 发明申请

WO2011015643A1 PROCESS FOR HYDROGENATION 审中-公开
标题翻译：加氢方法
公开(公告)号：WO2011015643A1
公开(公告)日：2011-02-10
申请号：PCT/EP2010/061458
申请日：2010-08-06
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HAAN, Rene, Johan , LANGE, Jean-Paul
发明人： HAAN, Rene, Johan , LANGE, Jean-Paul
IPC分类号： C07C51/377 , C07C53/126
CPC分类号： C07C51/377 , C07C53/126
摘要： A process for the hydrogenation of a reactant selected from: (a) a 5- or 6-membered lactone that is substituted at the ring-closing carbon atom and has a proton at a carbon atom adjacent to the ring-closing carbon atom; (b) an ester of a carboxylic acid having a gamma- carbonyl group and a proton at a carbon atom adjacent to the carbon atom of the carbonyl group; and (c) a carboxylic acid having a gamma-carbonyl group and a proton at a carbon atom adjacent to the carbon atom of the carbonyl group, which process involves contacting the reactant with a catalyst in the presence of hydrogen, at a temperature from 100 to 3500C and a pressure from 1 to 150 bar (absolute), provided the pressure is low enough to avoid condensation of the heaviest feed component at the temperature chosen, and wherein the catalyst is a weakly acidic heterogeneous catalyst comprising a hydrogenating metal.
摘要翻译：一种选自以下的反应物的氢化方法：（a）在闭环碳原子上被取代并在与闭环碳原子相邻的碳原子处具有质子的5-或6-元内酯; （b）在与羰基的碳原子相邻的碳原子处具有γ-羰基和质子的羧酸的酯; 和（c）在与羰基碳原子相邻的碳原子处具有γ-羰基和质子的羧酸，该方法包括在氢气存在下使反应物与催化剂接触，温度为100℃ 只要压力足够低以避免在所选择的温度下最重的进料组分的冷凝，并且其中催化剂是包含氢化金属的弱酸性非均相催化剂。

8. 发明申请

WO2009007391A1 PROCESS FOR CONVERTING LEVULINIC ACID INTO PENTANOIC ACID 审中-公开
标题翻译：将维生素酸转化成苦味酸的方法
公开(公告)号：WO2009007391A1
公开(公告)日：2009-01-15
申请号：PCT/EP2008/058901
申请日：2008-07-09
申请人： Shell Internationale Research Maatschappij B.V. , LANGE, Jean-Paul
发明人： LANGE, Jean-Paul
IPC分类号： C07C51/377 , C07C53/126
CPC分类号： C07C51/377 , C07C53/126
摘要： A process for converting levulinic acid into pentanoic acid, comprising the following steps: (a) supplying hydrogen and a feedstock comprising levulinic acid to a first catalytic zone comprising a strongly acidic catalyst and a hydrogenation metal; (b) converting, in the first catalytic zone, the levulinic acid at a temperature in the range of from 100 to 250 °C into gamma valerolactone to obtain a first effluent comprising gamma valerolactone; (c) supplying at least part of the first effluent to a second catalytic zone comprising a strongly acidic catalyst and a hydrogenation metal; and (d) converting, in the second catalytic zone, gamma valerolactone into pentanoic acid at a temperature in the range of from 200 to 350 °C to obtain a second effluent comprising pentanoic acid, wherein the conversion temperature in the first catalytic zone is lower than the conversion temperature in the second catalytic zone, and wherein the acidic catalyst and the hydrogenation metal in the first catalytic zone has the same composition as the acidic catalyst and the hydrogenation metal in the second catalytic zone.
摘要翻译：一种将乙酰丙酸转化为戊酸的方法，包括以下步骤：（a）向包含强酸性催化剂和氢化金属的第一催化区供应氢和包含乙酰丙酸的原料; （b）在第一催化区中将乙酰丙酸在100-250℃的温度范围内转化成γ-戊内酯，得到含有γ-戊内酯的第一流出液; （c）将至少部分第一流出物供应到包含强酸性催化剂和氢化金属的第二催化区; 和（d）在第二催化区域中将γ-戊内酯在200-350℃的温度范围内转化成戊酸，得到包含戊酸的第二流出物，其中第一催化区域的转化温度较低其中第一催化区中的酸性催化剂和氢化金属与第二催化区中的酸性催化剂和氢化金属具有相同的组成。

9. 发明申请

WO2007023173A1 A PROCESS FOR THE CONVERSION OF FURFURYL ALCOHOL INTO LEVULINIC ACID OR ALKYL LEVULINATE 审中-公开
标题翻译：一种将富含酒精转化成橄榄酸或亚油酸酯的方法
公开(公告)号：WO2007023173A1
公开(公告)日：2007-03-01
申请号：PCT/EP2006/065613
申请日：2006-08-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DE GRAAF, Wouter David , LANGE, Jean-Paul
发明人： VAN DE GRAAF, Wouter David , LANGE, Jean-Paul
IPC分类号： C07C51/00 , C07C59/185
CPC分类号： C07C51/00 , C07C67/00 , C07C59/185 , C07C69/716
摘要： A process for the conversion of furfuryl alcohol into levulinic acid or alkyl levulinate comprising contacting furfuryl alcohol and water or an alkyl alcohol with a porous heterogeneous catalyst comprising strong acid ion exchange resin, wherein the catalyst has pores with an average pore diameter in the range of from 1 to 1000 nm.
摘要翻译：将糠醇转化为乙酰丙酸或乙酰丙酸烷基酯的方法，其包括使糠醇与水或烷基醇与包含强酸离子交换树脂的多孔非均相催化剂接触，其中所述催化剂具有平均孔径在从1至1000nm。

10. 发明申请

WO2005051939A1 PROCESS FOR THE PREPARATION OF PROPYLENE CARBONATE 审中-公开
标题翻译：制备丙烯碳酸酯的方法
公开(公告)号：WO2005051939A1
公开(公告)日：2005-06-09
申请号：PCT/EP2004/053085
申请日：2004-11-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BECKERS, Johannes, Gerhardus, Joseph , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus, Martinus, Maria , LANGE, Jean-Paul
发明人： BECKERS, Johannes, Gerhardus, Joseph , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus, Martinus, Maria , LANGE, Jean-Paul
IPC分类号： C07D317/36
CPC分类号： C07C29/12 , C07C68/065 , C07D317/36 , C07C69/96 , C07C31/205
摘要： A process comprising contacting a propylene oxide feed with carbon dioxide in the presence of a suitable catalyst to obtain a reaction mixture comprising propylene carbonate in which process the propylene oxide feed comprises at least 50 ppmw of acids and/or carbonyls.
摘要翻译：一种方法包括在合适的催化剂存在下使环氧丙烷进料与二氧化碳接触以获得包含碳酸丙烯酯的反应混合物，其中环氧丙烷进料包含至少50ppmw的酸和/或羰基。

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