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1. 发明申请

WO2012047832A2 PROCESS FOR THE PRODUCTION OF ALCOHOLS FROM BIOMASS 审中-公开
标题翻译：由生物质生产醇的方法
公开(公告)号：WO2012047832A2
公开(公告)日：2012-04-12
申请号：PCT/US2011054686
申请日：2011-10-04
申请人： SHELL OIL CO , SHELL INT RESEARCH , CHHEDA JUBEN NEMCHAND , FALENDER ALLISON ELAINE , VAN DER HEIDE EVERT
发明人： CHHEDA JUBEN NEMCHAND , FALENDER ALLISON ELAINE , VAN DER HEIDE EVERT
IPC分类号： C12P7/02
CPC分类号： D21C3/02 , C12P7/10 , C12P2201/00 , D21C3/222 , D21C11/0007 , Y02E50/16 , Y02E50/17
摘要： Alcohols useful as fuel compositions are produced from biomass by: contacting the biomass with a cooking liquor containing (i) 1 to 20 wt %, based on the cooking liquor, of sodium hydroxide, (ii) optionally, 0 to 20 wt %, based on the cooking liquor, of sodium sulfide; (iii) optionally, 0 to 3%, based on the cooking liquor, of anthraquinone, sodium borate and/or polysulfides; and (iv) water, wherein such cooking liquor has an active alkali of between 5 to 25%, and a sodium carbonate concentration of less than 3.5 wt% based on cooking liquor, at a cooling liquor to biomass ratio within the range of 2 to 6, at a temperature within the range of 1000C to 2300C with a residence time within 0.25 h to 4h under conditions effective to provide a pulp stream containing pulp having a lignin content of 5% to 20% by weight, based on the pulp, and a chemical liquor stream containing sodium compounds; washing the pulp stream with a water stream producing washed pulp stream; hydrolyzing the washed pulp stream by treating the streams with an enzyme solution comprising cellulases and optionally xylanases at a pH within the range of 3 to 7 at a temperature within the range of 300C to 900C to produce a hydrolyzate containing from 4% to 30% by weight of fermentable sugar; fermenting the hydrolyzate in the presence of a microorganism at a temperature with the range of 250C to 550C at a pH within the range of 4 to 6 thereby producing an alcohol stream containing at least one alcohol having 2 to 18 carbon atoms.
摘要翻译：可用作燃料组合物的醇是通过以下步骤生产的：使生物质与蒸煮液接触，所述蒸煮液含有（i）基于蒸煮液1-20wt％的氢氧化钠，（ii）任选地0-20wt％蒸煮液中的硫化钠; （iii）任选地，基于蒸煮液0至3％的蒽醌，硼酸钠和/或多硫化物; 和（iv）水，其中所述蒸煮液具有基于蒸煮液的5至25％的活性碱和小于3.5wt％的碳酸钠浓度，冷却液与生物质的比例在2至 6，在100℃至2300℃范围内的温度下，停留时间在0.25h至4h内，在有效提供含木质素含量为纸浆重量的5％至20％的纸浆的纸浆料流的条件下，和含有钠化合物的化学液体流; 用产生洗过的纸浆流的水流洗涤纸浆流; 通过用包含纤维素酶和任选的木聚糖酶的酶溶液在3-7范围内的pH下，在30℃至90℃范围内的温度下处理所述经洗涤的纸浆流以生成含有4％至30％的水解产物可发酵糖的重量; 在微生物存在下，在250-550℃的温度范围内，在4-6范围内的pH下发酵水解产物，由此产生含有至少一种具有2-18个碳原子的醇的醇流。

2. 发明申请

WO2009141377A1 PROCESS FOR PREPARING AN 1,2-ALKYLENE CARBONATE 审中-公开
标题翻译：制备1,2-亚烷基碳酸酯的方法
公开(公告)号：WO2009141377A1
公开(公告)日：2009-11-26
申请号：PCT/EP2009/056134
申请日：2009-05-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , VROUWENVELDER, Cornelis Leonardus Maria
发明人： VAN DER HEIDE, Evert , VROUWENVELDER, Cornelis Leonardus Maria
IPC分类号： C07D317/36 , C07D317/38 , C07C29/12
CPC分类号： C07D317/36 , C07C29/12 , C07C68/065 , C07D317/38 , C07C31/202 , C07C69/96
摘要： The invention relates to a process for producing an 1,2-alkylene carbonate comprising (i) transporting liquid carbon dioxide to an 1,2-alkylene carbonate production plant; (ii) feeding the liquid carbon dioxide to an evaporation vessel; (iii) evaporating the liquid carbon dioxide such that a partial pressure of gaseous carbon dioxide of at least 5 x 10 5 N/m 2 is generated; (iv) feeding the gaseous carbon dioxide to a reactor; and (v) contacting the gaseous carbon dioxide with an 1,2- alkylene oxide and a carbonation catalyst to produce 1,2- alkylene carbonate.
摘要翻译：本发明涉及一种生产1,2-亚烷基碳酸酯的方法，其包括（i）将液体二氧化碳输送到1,2-亚烷基碳酸酯生产设备中; （ii）将液体二氧化碳供给到蒸发容器中; （iii）蒸发液态二氧化碳，使得产生至少5×10 5 N / m 2的气态二氧化碳分压; （iv）将气态二氧化碳送入反应器; 和（v）使气态二氧化碳与1,2-环氧烷和碳酸化催化剂接触以产生1,2-亚烷基碳酸酯。

3. 发明申请

WO2009141361A2 PROCESS FOR THE PRODUCTION OF ALKYLENE CARBONATE 审中-公开
标题翻译：生产亚烷基碳酸酯的方法
公开(公告)号：WO2009141361A2
公开(公告)日：2009-11-26
申请号：PCT/EP2009056098
申请日：2009-05-19
申请人： SHELL INT RESEARCH , ALLAIS CYRILLE PAUL , VAN DER HEIDE EVERT , VAN KESSEL GERARDUS MARTINUS M
发明人： ALLAIS CYRILLE PAUL , VAN DER HEIDE EVERT , VAN KESSEL GERARDUS MARTINUS MARIA
IPC分类号： C07D317/36 , C07D317/38
CPC分类号： C07D317/36 , C07D317/38
摘要： The invention relates to a process for the production of an alkylene carbonate by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium catalyst in which process (a) the alkylene oxide, carbon dioxide and phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and phosphonium catalyst is withdrawn; (b) alkylene carbonate and a stream containing phosphoniura catalyst are separated from the product stream; (c) the alkylene carbonate, separated in step (b), is recovered as product; and (d) the stream containing phosphoniura catalyst, separated in step (b), is recycled to the reaction zone, in which process a treatment of alkylene carbonate and/or catalyst with a sorption agent comprising carbon is carried out.
摘要翻译：本发明涉及在鏻催化剂存在下，通过烯化氧与二氧化碳的反应制备碳酸亚烷基酯的方法，其中方法（a）将烯化氧，二氧化碳和鏻催化剂连续引入取出含有碳酸亚烷基酯和鏻催化剂的产物流的反应区; （b）将碳酸亚烃酯和含有膦酰氧基催化剂的物流与产物流分离; （c）在步骤（b）中分离的碳酸亚烃酯作为产物回收; 和（d）在步骤（b）中分离的含有膦酰氧基催化剂的料流被循环到反应区，在该方法中，用含碳吸附剂处理碳酸亚烷基酯和/或催化剂。

4. 发明申请

WO2009135851A1 PROCESS FOR PREPARING ALKANEDIOL AND DIALKYL CARBONATE 审中-公开
标题翻译：制备阿尔卡尼和碳酸二乙酯的方法
公开(公告)号：WO2009135851A1
公开(公告)日：2009-11-12
申请号：PCT/EP2009/055434
申请日：2009-05-05
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , ALLAIS, Cyrille Paul , BOELENS, Minne , VAN DER HEIDE, Evert
发明人： ALLAIS, Cyrille Paul , BOELENS, Minne , VAN DER HEIDE, Evert
IPC分类号： C07C68/06 , C07C69/96 , C07C29/12 , C07C31/20 , C07C27/00
CPC分类号： C07C68/065 , C07C69/96
摘要： The invention relates to a process for the preparation of an alkanediol and a dialkyl carbonate comprising: (a) reacting an alkylene carbonate and an alkanol at a temperature of from 10 to 200 °C, at a pressure of from 5x10 4 to 5x10 6 N/m 2 and in the absence of a transesterification catalyst, to obtain a mixture comprising hydroxyalkyl alkyl carbonate, alkanol and alkylene carbonate; (b) contacting the mixture comprising hydroxyalkyl alkyl carbonate, alkanol and alkylene carbonate with a transesterification catalyst at a temperature of from 10 to 200 °C and at a pressure of from 5xl0 4 to 5xl0 6 N/m 2 , to obtain a mixture comprising the alkanediol and the dialkyl carbonate; and (c) recovering the alkanediol and the dialkyl carbonate from the mixture comprising the alkanediol and the dialkyl carbonate.
摘要翻译：本发明涉及一种制备链烷二醇和碳酸二烷基酯的方法，包括：（a）在10至200℃的温度下，在5×10 4至5×10 6 N / m 2的压力下使碳酸亚烷基酯和链烷醇反应并且在不存在酯交换催化剂的情况下，得到包含碳酸烷基酯，链烷醇和碳酸亚烷基酯的混合物; （b）使含碳酸烷基酯，链烷醇和碳酸亚烷基酯的混合物与酯交换催化剂在10〜200℃，压力为5×10 4〜5×10 6 N / m 2下接触，得到含有链烷二醇和碳酸二烷基酯; 和（c）从包含链烷二醇和碳酸二烷基酯的混合物中回收链烷二醇和碳酸二烷基酯。

5. 发明申请

WO2009080737A2 A PROCESS FOR CONVERTING LIGNOCELLULOSE INTO SUGARS 审中-公开
标题翻译：将木质纤维素转化为糖的方法
公开(公告)号：WO2009080737A2
公开(公告)日：2009-07-02
申请号：PCT/EP2008067983
申请日：2008-12-19
申请人： SHELL INT RESEARCH , VAN DER HEIDE EVERT , MACKAY MUNRO , ZHANG TING
发明人： VAN DER HEIDE EVERT , MACKAY MUNRO , ZHANG TING
IPC分类号： C12P7/10 , C12P19/02
CPC分类号： C12P7/10 , C12P19/02 , Y02E50/16
摘要： A process for converting lignocellulose into sugars comprising the following steps: (a) chemically pre-treating lignocellulose-comprising solid biomass by contacting the biomass with a cooking liquid comprising at least 40 vol% formic acid and at least 50 vol% organic acid, at a temperature in the range of from 90 to 180 °C, at a biomass to liquid ratio in the range of from 1:3 to 1:50 to obtain a pre-treated solid residue and spent cooking liquid; (b) separating the solid residue from the spent cooking liquid; (c) washing the solid residue with washing liquid comprising at least 40 vol% formic acid and at least 50 vol% organic acid to obtain washed solid residue and spent washing liquid; (d) separating the washed solid residue from the spent washing liquid; (e) supplying the spent washing liquid obtained in step (d) to step (a) to form part of the cooking liquid that is contacted with the biomass; (f) evaporating free organic acids from the washed solid residue to obtain evaporated washed solid residue; (g) subjecting the evaporated washed solid residue to enzymatic hydrolysis to obtain sugars.
摘要翻译：一种将木质纤维素转化成糖的方法，包括以下步骤：（a）通过使生物质与包含至少40体积％甲酸和至少50体积％有机酸的烹饪液接触，化学预处理含木质纤维素的固体生物质，温度范围为90-180℃，生物质液比为1:3-1:50，以获得预处理的固体残余物和用过的烹饪液; （b）将固体残余物与废弃的烹饪液体分离; （c）用包含至少40体积％甲酸和至少50体积％有机酸的洗涤液洗涤固体残余物以获得洗涤的固体残余物和废洗涤液; （d）将洗过的固体残余物与废弃洗涤液分离; （e）将步骤（d）中获得的用过的洗涤液供应至步骤（a）以形成与生物质接触的部分烹饪液体; （f）从洗过的固体残余物中蒸发游离的有机酸，以获得蒸发的洗涤的固体残余物; （g）将蒸发过的洗涤的固体残余物进行酶水解以获得糖。

6. 发明申请

WO2008090106A1 PROCESS FOR THE PREPARATION OF DIARYL CARBONATE 审中-公开
标题翻译：制备二氧化碳的方法
公开(公告)号：WO2008090106A1
公开(公告)日：2008-07-31
申请号：PCT/EP2008/050604
申请日：2008-01-21
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis , VROUWENVELDER, Cornelis Leonardo Maria
发明人： VAN DER HEIDE, Evert , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis , VROUWENVELDER, Cornelis Leonardo Maria
IPC分类号： C07C68/06 , C07C69/96
CPC分类号： C07C68/06 , Y02P20/127 , C07C69/96
摘要： The invention relates to a process for the preparation of a diaryl carbonate by transesterification of an aromatic alcohol with a dialkyl carbonate in the presence of a transesterification catalyst during a period of time [t a ], in which the aryl moiety is selected from unsubstituted phenyl and mono-, di- and trisubstituted phenyl groups, in which the alkyl moiety is selected from C 2 to C 4 linear and branched alkyl groups, in which the catalyst concentration is designated [c a ], expressed as gram catalyst per gram of aromatic alcohol and dialkyl carbonate, in which the period of time [t m ] and catalyst concentration [c m ] are determined to arrive at a pre-set approach to the equilibrium for the transesterification of the aromatic alcohol with dimethyl carbonate to methyl aryl carbonate and methanol, in which the product [c a ]*t a is at least 1.5* [c m ]*t m , under otherwise the same reaction conditions.
摘要翻译：本发明涉及一种通过在酯交换催化剂存在下在一段时间内酯交换芳族醇与碳酸二烷基酯来制备碳酸二芳基酯的方法，其中芳基部分选自未取代的苯基和单取代，二取代和三取代的苯基，其中烷基部分选自C 2〜C 4直链和支链烷基，其中催化剂浓度指定为[克/ a]，其表示为克催化剂/克芳族醇和碳酸二烷基酯，其中时间[t] 并确定催化剂浓度[℃]以得到芳族醇与碳酸二甲酯与碳酸甲基芳基酯和甲醇的酯交换的平衡的预设方法，其中产物[c 在其它方面相同的情况下，至少1.5 * [c m REA 条件条件。

7. 发明申请

WO2007096346A1 PROCESS FOR THE PREPARATION OF AN ALKANEDIOL AND A DIALKYL CARBONATE 审中-公开
标题翻译：制备阿尔卡尼醇和碳酸二乙酯的方法
公开(公告)号：WO2007096346A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051590
申请日：2007-02-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , NISBET, Timothy Michael
发明人： VAN DER HEIDE, Evert , NISBET, Timothy Michael
IPC分类号： C07C68/06 , C07C69/96
CPC分类号： C07C68/065 , Y02P20/127 , C07C69/96
摘要： A process for the preparation of an alkanediol and a dialkyl carbonate is provided, which process comprises: (a) contacting an alkylene carbonate with an alkanol feedstock under transesterification conditions in a reactive distillation column to obtain an upwardly moving stream comprising dialkyl carbonate and the alkanol and a downwardly moving stream comprising the alkanediol; (b) recovering the alkanediol at the bottom of the column; (c) withdrawing a dialkyl carbonate- and alkanol-containing product stream at the upper part of the column, which upper part is below the top of the column; and (d) removing lower-boiling compounds at the top of the column.
摘要翻译：提供了一种制备链烷二醇和碳酸二烷基酯的方法，该方法包括：（a）在反应性蒸馏塔中的酯交换条件下使碳酸亚烷基酯与链烷醇原料接触，以获得包含碳酸二烷基酯和链烷醇和包含所述链烷二醇的向下移动的流; （b）回收柱底部的链烷二醇; （c）在柱的上部排出碳酸二烷基酯和含链烷醇的产物流，该上部在塔的顶部下方; 和（d）除去塔顶部的低沸点化合物。

8. 发明申请

WO2007096341A1 PROCESS FOR THE PRODUCTION OF ALKYLENE CARBONATE AND USE OF ALKYLENE CARBONATE THUS PRODUCED IN THE MANUFACTURE OF AN ALKANE DIOL AND A DIALKYL CARBONATE 审中-公开
标题翻译：生产亚烷基二醇和碳酸二乙酯生产中生产的亚烷基碳酸酯的方法
公开(公告)号：WO2007096341A1
公开(公告)日：2007-08-30
申请号：PCT/EP2007/051583
申请日：2007-02-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus Martinus Maris , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
发明人： VAN DER HEIDE, Evert , VAN KESSEL, Gerardus Martinus Maris , NISBET, Timothy Michael , VAPORCIYAN, Garo Garbis
IPC分类号： C07D317/36 , C07C29/128 , C07C31/20
CPC分类号： C07C29/128 , C07D317/36 , Y02P20/584 , C07C31/202
摘要： An alkylene carbonate is produced by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium compound as catalyst in a process in which (a) the alkylene oxide, carbon dioxide and the phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and catalyst is withdrawn, (b) alkylene carbonate and a mixture of alkylene carbonate and phosphonium catalyst are separated from the product stream and, and (c) the alkylene carbonate, separated in step (b), is recovered as product, and (d) the mixture of alkylene carbonate and phosphonium catalyst is continuously recycled to the reaction zone. The alkylene carbonate thus produced is suitably reacted with an alkanol to produce an alkane diol and a dialkyl carbonate.
摘要翻译：在鏻化合物作为催化剂的存在下，通过烯化氧与二氧化碳的反应制备碳酸亚烃酯，其中（a）将环氧烷，二氧化碳和鏻催化剂从取出含有碳酸亚烃酯和催化剂的产物流，（b）碳酸亚烷基酯和碳酸亚烃酯和鏻催化剂的混合物与产物流分离，和（c）在步骤（b）中分离的碳酸亚烃酯是作为产物回收，和（d）碳酸亚烷基酯和鏻催化剂的混合物连续循环到反应区。这样制得的碳酸亚烃酯适当地与烷醇反应生成烷烃二醇和碳酸二烷基酯。

9. 发明申请

WO2005051939A1 PROCESS FOR THE PREPARATION OF PROPYLENE CARBONATE 审中-公开
标题翻译：制备丙烯碳酸酯的方法
公开(公告)号：WO2005051939A1
公开(公告)日：2005-06-09
申请号：PCT/EP2004/053085
申请日：2004-11-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BECKERS, Johannes, Gerhardus, Joseph , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus, Martinus, Maria , LANGE, Jean-Paul
发明人： BECKERS, Johannes, Gerhardus, Joseph , VAN DER HEIDE, Evert , VAN KESSEL, Gerardus, Martinus, Maria , LANGE, Jean-Paul
IPC分类号： C07D317/36
CPC分类号： C07C29/12 , C07C68/065 , C07D317/36 , C07C69/96 , C07C31/205
摘要： A process comprising contacting a propylene oxide feed with carbon dioxide in the presence of a suitable catalyst to obtain a reaction mixture comprising propylene carbonate in which process the propylene oxide feed comprises at least 50 ppmw of acids and/or carbonyls.
摘要翻译：一种方法包括在合适的催化剂存在下使环氧丙烷进料与二氧化碳接触以获得包含碳酸丙烯酯的反应混合物，其中环氧丙烷进料包含至少50ppmw的酸和/或羰基。

10. 发明申请

WO2004085375A1 PROCESS FOR THE PREPARATION OF PROPYLENE GLYCOL 审中-公开
标题翻译：制备丙二醇的方法
公开(公告)号：WO2004085375A1
公开(公告)日：2004-10-07
申请号：PCT/EP2004/050364
申请日：2004-03-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIDE, Evert , LANGE, Jean-Paul , MIEDEMA, Arjen
发明人： VAN DER HEIDE, Evert , LANGE, Jean-Paul , MIEDEMA, Arjen
IPC分类号： C07C68/06
CPC分类号： C07C29/12 , C07C31/205
摘要： Process for the preparation of propylene glycol from propylene oxide, which process comprises: (a) contacting propylene oxide with carbon dioxide in the presence of catalyst to obtain a first reaction mixture containing propylene carbonate, and (b) contacting at least part of the first reaction mixture with water in the presence of catalyst to obtain a second reaction mixture containing propylene glycol and carbon dioxide, in which process a substantial amount of propylene oxide is present in step (b).
摘要翻译：用于从环氧丙烷制备丙二醇的方法，该方法包括：（a）在催化剂存在下使环氧丙烷与二氧化碳接触，得到含有碳酸亚丙酯的第一反应混合物，和（b）使第一在催化剂存在下与水反应，得到含有丙二醇和二氧化碳的第二反应混合物，其中步骤（b）中存在大量的环氧丙烷。

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