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    • 8. 发明授权
    • Composition for photo imaging
    • 摄影成像的组成
    • US5264325A
    • 1993-11-23
    • US918304
    • 1992-07-21
    • Robert D. AllenRichard A. DayDonald H. GlatzelWilliam D. HinsbergJohn R. MertzDavid J. RussellGregory M. Wallraff
    • Robert D. AllenRichard A. DayDonald H. GlatzelWilliam D. HinsbergJohn R. MertzDavid J. RussellGregory M. Wallraff
    • G03F7/038G03F7/20H05K3/00H05K3/28D04H1/08
    • G03F7/2053G03F7/0385H05K3/0082H05K3/287
    • An improved photoimagable cationically polymerizable epoxy based coating material is provided, that is suitable for use on a variety of substrates. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which preferably is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; and between about 35% and 72% by weight of an epoxidized glycidyl ether of a brominated bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. A third resin, either an epoxy cresol novolak or a polyepoxy resin, is also added to the resin system. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.
    • 提供了一种改进的可光成像的可阳离子聚合的环氧基涂料,其适用于各种基材。 该材料包括基本上由约10重量%至约80重量%的多元醇树脂组成的环氧树脂体系,多元醇树脂优选为分子量为约40,000至130,000的表氯醇和双酚A的缩合产物; 和约35重量%至72重量%的软化点为约60℃至约110℃,分子量为约600至2,500的溴化双酚A的环氧化缩水甘油醚。 树脂体系中还加入第三树脂,环氧甲酚酚醛清漆或聚环氧树脂。 向该树脂体系中添加约0.1〜约15重量份/ 100份阳离子光引发剂的树脂,其能够在暴露于光化辐射下引发所述环氧化树脂体系的聚合; 该系统的特征还在于,对于2.0密耳厚的膜,在330至700nm区域中的光的吸光度小于0.1。 任选地,可加入光敏剂如苝及其衍生物或蒽及其衍生物。