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    • 3. 发明申请
    • CU INTERCONNECTS WITH COMPOSITE BARRIER LAYERS FOR WAFER-TO-WAFER UNIFORMITY
    • 具有复合阻挡层的CU互连用于波形到波长均匀性
    • US20050224979A1
    • 2005-10-13
    • US10811860
    • 2004-03-30
    • Amit MaratheConnie WangChristy Woo
    • Amit MaratheConnie WangChristy Woo
    • H01L21/768H01L23/48H01L29/40
    • H01L21/76846
    • A composite α-Ta/graded tantalum nitride/TaN barrier layer is formed in Cu interconnects with a structure designed for improved wafer-to-wafer uniformity, electromigration resistance and reliability, reduced contact resistance, and increased process margin. Embodiments include a dual damascene structure in a low-k interlayer dielectric comprising Cu and a composite barrier layer comprising an initial layer of TaN on the low-k material, a graded layer of tantalum nitride on the initial TaN layer and a continuous α-Ta layer on the graded tantalum nitride layer. Embodiments include forming the initial TaN layer at a thickness sufficient to ensure deposition of α-Ta, e.g., as at a thickness of bout 50 Å to about 100 Å. Embodiments include composite barrier layers having a thickness ratio of α-Ta and graded tantalum nitride: initial TaN of about 2.5:1 to about 3.5:1 for improved electromigration resistance and wafer-to-wafer uniformity.
    • 在Cu互连中形成复合α-Ta /分级氮化钽/ TaN阻挡层,其具有为提高晶片到晶片的均匀性,电迁移电阻和可靠性,降低的接触电阻和增加的工艺裕度而设计的结构。 实施例包括在包含Cu的低k层间电介质中的双镶嵌结构和在低k材料上包含TaN的初始层的复合势垒层,初始TaN层上的氮化钽梯度层和连续的α-Ta 层叠在梯度氮化钽层上。 实施方案包括以足以确保α-Ta沉积的厚度形成初始TaN层,例如在50至大约的厚度。 实施例包括厚度比为α-Ta和梯度氮化钽的复合阻挡层:初始TaN为约2.5:1至约3.5:1,以提高电迁移阻力和晶片与晶片的均匀性。
    • 5. 发明授权
    • Formation of self-aligned passivation for interconnect to minimize electromigration
    • 形成用于互连的自对准钝化,以最小化电迁移
    • US06309959B1
    • 2001-10-30
    • US09630943
    • 2000-08-03
    • Pin-Chin C. WangLu YouJoffre BernardAmit Marathe
    • Pin-Chin C. WangLu YouJoffre BernardAmit Marathe
    • H01L214763
    • H01L21/76843H01L21/76838H01L21/76849H01L21/76867H01L21/76873H01L21/76886H01L21/76888
    • An interconnect opening of an integrated circuit is filled with a conductive fill with the interconnect opening being within an insulating layer on a semiconductor wafer. A seed layer of a first conductive material is deposited conformally onto sidewalls and a bottom wall of the interconnect opening. The interconnect opening is further filled with a second conductive material by growing the second conductive material from the seed layer to form a conductive fill of the first conductive material and the second conductive material within the interconnect opening. The first conductive material and the second conductive material are comprised of a bulk metal, and at least one of the first conductive material and the second conductive material is a metal alloy having an alloy dopant in the bulk metal. In addition, a plasma treatment process is performed to remove any metal oxide or metal hydroxide from a top surface of the conductive fill. A self-aligned passivation material of an intermetallic compound or a metal oxide is formed at the top surface of the conductive fill with the alloy dopant that segregates out and to the top surface of the conductive fill. The intermetallic compound or the metal oxide is an additional passivation material between the top surface of the conductive fill and a layer of bulk passivation material deposited over the semiconductor wafer to prevent drift of the bulk metal, such as copper, of the conductive fill along a bottom surface of the layer of bulk passivation material.
    • 集成电路的互连开口填充有导电填料,其中互连开口位于半导体晶片上的绝缘层内。 第一导电材料的籽晶层保形地沉积在互连开口的侧壁和底壁上。 通过从种子层生长第二导电材料以形成互连开口内的第一导电材料和第二导电材料的导电填料,互连开口进一步填充有第二导电材料。 第一导电材料和第二导电材料由体金属组成,并且第一导电材料和第二导电材料中的至少一个是在本体金属中具有合金掺杂剂的金属合金。 此外,进行等离子体处理工艺以从导电填料的顶表面去除任何金属氧化物或金属氢氧化物。 在导电填料的顶表面上形成金属间化合物或金属氧化物的自对准钝化材料,其中合金掺杂剂分离出导电填料的顶表面。 金属间化合物或金属氧化物是在导电填料的顶表面和沉积在半导体晶片上的体积钝化材料层之间的另外的钝化材料,以防止导电填料的体金属(例如铜)沿着 底部表面堆积钝化材料层。