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1. 发明授权

US06569936B1 Rubber composition for a conveyor belt 有权
标题翻译：用于输送带的橡胶组合物
公开(公告)号：US06569936B1
公开(公告)日：2003-05-27
申请号：US09717275
申请日：2000-11-22
申请人： Masaaki Kawasaki , Takashi Hakuta , Hidenari Nakahama , Tetsuo Tojo
发明人： Masaaki Kawasaki , Takashi Hakuta , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08K304
CPC分类号： C08K5/01 , C08K3/04 , C08K5/14 , C08L23/16 , C08L91/00 , C08L2666/02
摘要： According to the present invention, there is provided a rubber composition for a conveyor belt comprising (A) 100 parts by weight of an ethylene/&agr;-olefin containing 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber containing a diene unit derived from special non-conjugated dienes, (B) 0.5 to 15 parts by weight of an organic peroxide, (C) 30 to 80 parts by weight of a carbon black and (D) 5 to 25 parts by weight of a softening agent. This rubber composition provides excellent mechanical strength, heat resistance (including heat aging resistance), abrasion resistance and roll processability. It is especially preferred to convey a sintered product, a coke, a cement, clinker and quicklime.
摘要翻译：根据本发明，提供了一种用于输送带的橡胶组合物，其包含（A）100重量份含有3-20个碳原子的乙烯/α-烯烃/非共轭多烯共聚物橡胶，其含有衍生自特殊的非共轭二烯，（B）0.5〜15重量份的有机过氧化物，（C）30〜80重量份的炭黑和（D）5〜25重量份的软化剂。组合物提供优异的机械强度，耐热性（包括耐热老化性），耐磨性和辊加工性。特别优选输送烧结产品，焦炭，水泥，熟料和生石灰。

2. 发明授权

US5869563A Ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition 失效
标题翻译：乙烯/α-烯烃/非共轭多烯共聚物橡胶组合物
公开(公告)号：US5869563A
公开(公告)日：1999-02-09
申请号：US661989
申请日：1996-06-12
申请人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
发明人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
IPC分类号： C08L23/02 , C08L23/16 , C08L23/26
CPC分类号： C08L23/02 , C08L23/16 , C08L2207/04
摘要： The ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition of the present invention comprises in specified proportions a crystalline polyolefin resin (A) and an ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) composed of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms and a specific branched chain polyene compound. The molar ratio of ethylene units to .alpha.-olefin units, iodine value and intrinsic viscosity �.eta.! of the ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) are within respective specified ranges. This rubber composition is excellent in low temperature properties. When the above olefinic thermoplastic elastomer composition is partially or entirely crosslinked, a molding can be provided which is superior to the conventional vulcanized rubbers in low temperature properties, tensile strength, elongation at break and rubber properties.
摘要翻译：本发明的乙烯/α-烯烃/非共轭多烯共聚物橡胶组合物以特定比例包含结晶聚烯烃树脂（A）和乙烯/α-烯烃/非共轭多烯共聚物橡胶（B），乙烯，α-烯烃具有3至20个碳原子和特定的支链多烯化合物。乙烯单元与α-烯烃单元的摩尔比，乙烯/α-烯烃/非共轭多烯共聚物橡胶（B）的碘值和特性粘度η在各自的特定范围内。该橡胶组合物的低温性能优异。当上述烯烃类热塑性弹性体组合物部分或全部交联时，可以提供在低温性能，拉伸强度，断裂伸长率和橡胶性能方面优于常规硫化橡胶的成型。

3. 发明授权

US5807948A Vulcanizable rubber composition containing ehtylene-.alpha.-olefin-nonconjugated polyene random copolymer 失效
标题翻译：含有乙烯-α-烯烃 - 非共轭多烯无规共聚物的可硫化橡胶组合物
公开(公告)号：US5807948A
公开(公告)日：1998-09-15
申请号：US783238
申请日：1997-01-14
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要翻译：公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在含有特定茂金属化合物的茂金属催化剂。通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下（iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。还公开了含有无规共聚物的可硫化橡胶组合物。乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。

4. 发明授权

US6111021A Rubber composition and process for the production thereof 失效
公开(公告)号：US6111021A
公开(公告)日：2000-08-29
申请号：US983023
申请日：1998-01-02
申请人： Hidenari Nakahama , Masaaki Kawasaki , Yuji Ishii , Tetsuo Tojo , Taku Koda , Yoshio Maejima , Yuji Miura , Yasuhiro Hosomi
发明人： Hidenari Nakahama , Masaaki Kawasaki , Yuji Ishii , Tetsuo Tojo , Taku Koda , Yoshio Maejima , Yuji Miura , Yasuhiro Hosomi
IPC分类号： C08L23/02 , C08L23/04 , C08L23/08 , C08L23/10 , C08L23/16
CPC分类号： C08L23/02 , C08L23/16 , C08L2205/18 , C08L23/04 , C08L23/0815 , C08L23/10
摘要： A vulcanizable rubber composition comprising a blend which is prepared by micro-dispersing a polyolefin resin (B) in an ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) comprising ethylene, a C.sub.3 -C.sub.20 .alpha.-olefin and a nonconjugated polyene in a molten state and in which the mean diameter of dispersed particles of the polyolefin resin (B) is 2 .mu.m or below and the (B) to (A) weight ratio ranges from 5/95 to 50/50. The micro-dispersion of a polyolefin resin (B) can easily be attained by kneading the components (A) and (B) together with compounding ingredients (such as reinforcement, filler, softener, vulcanization accelerator, vulcanizing agent and so on) in a rubber kneader, through the resin (B) is essentially difficult of micro-dispersion. Further, the composition enables the provision of rubber articles having a high and constant quality at a low cost, because the resin (B) can well be dispersed by conventional rubber kneaders in a short time without fail. The process for producing the above composition comprises introducing a rubber mixture (E) comprising 100 parts by weight of the copolymer rubber (B) and 3 to 10 parts by weight of an organic solvent (D) into a multi-stage vented extruder through a feed port, while introducing a polyolefin resin (B) thereinto in an inert gas atmosphere through another feed port, kneading the rubber mixture (E) and the polyolefin resin (B) with the removal of the solvent. This process can easily give nonblocking vulcanizable pellets of an ethylenic copolymer rubber composition comprising an ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) and a polyolefin resin (B) wherein the resin (B) is micro-dispersed in a good state.

5. 发明授权

US5912303A Ethylene/.alpha.-olefin/nonconjugated polyene terpolymer rubber composition and vulcanized rubber obtained therefrom 失效
标题翻译：乙烯/α-烯烃/非共轭多烯三元共聚物橡胶组合物和由其获得的硫化橡胶
公开(公告)号：US5912303A
公开(公告)日：1999-06-15
申请号：US652901
申请日：1996-05-23
申请人： Hidenari Nakahama , Masaaki Kawasaki , Tetsuo Tojo , Totshiyuki Tsutsui , Toshihiro Sagane
发明人： Hidenari Nakahama , Masaaki Kawasaki , Tetsuo Tojo , Totshiyuki Tsutsui , Toshihiro Sagane
IPC分类号： C08L9/02 , C08L23/16 , C08L9/00 , C08L47/00
CPC分类号： C08L9/02 , C08L23/16 , C08L23/083 , C08L2312/00 , C08L7/00
摘要： A terpolymer rubber prepared from ethylene, .alpha.-olefin having 3 to 20 carbon atoms and branched chain polyene of the formula ##STR1## wherein R.sup.1 represents C.sub.1 -C.sub.5 alkyl, and R.sup.2 and R.sup.3 represent hydrogen atom or C.sub.1 -C.sub.5 alkyl, such as, for example, 6,7-dimethyl-4-ethylidene-1,6-octadiene, 6,7-dimethyl-4-ethylidene-1,6-nonadiene, and 9-methyl-4-ethylidene-1,8-decadiene; when added to a rubber (diene rubber, nitrile rubber or random copolymer rubber from ethylene, C.sub.3 -C.sub.20 .alpha.-olefin, and optionally a nonconjugated diene) provides curable rubber compositions having rapid vulcanization rates, for example, as lows as about 7 to 10 seconds. The diene rubber compositions also have excellent resistances to weather,ozone and heat aging while maintaining excellent mechanical strength characteristics. The nitrile rubber compositions also have excellent oil resistance.
摘要翻译：由乙烯，具有3-20个碳原子的α-烯烃和下式的支链多烯制备的三元共聚物橡胶，其中R1代表C1-C5烷基，R2和R3代表氢原子或C1-C5烷基，例如， 6,7-二甲基-4-亚乙基-1,6-辛二烯，6,7-二甲基-4-亚乙基-1,6-辛二烯和9-甲基-4-亚乙基-1,8-癸二烯; 当加入到橡胶（二烯橡胶，丁腈橡胶或乙烯的无规共聚物橡胶，C 3 -C 20α-烯烃和任选的非共轭二烯）时，提供具有快速硫化速率的可固化橡胶组合物，例如低至约7至10 秒。二烯橡胶组合物还具有优异的耐候性，耐臭氧和热老化，同时保持优异的机械强度特性。丁腈橡胶组合物也具有优异的耐油性。

6. 发明授权

US5756575A Ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition 失效
公开(公告)号：US5756575A
公开(公告)日：1998-05-26
申请号：US661989
申请日：1996-06-12
申请人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
发明人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
IPC分类号： C08L23/02 , C08L23/16 , C08L23/26
CPC分类号： C08L23/02 , C08L23/16 , C08L2207/04
摘要： The ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition of the present invention comprises in specified proportions a crystalline polyolefin resin (A) and an ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) composed of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms and a specific branched chain polyene compound. The molar ratio of ethylene units to .alpha.-olefin units, iodine value and intrinsic viscosity �.eta.! of the ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) are within respective specified ranges. This rubber composition is excellent in low temperature properties. When the above olefinic thermoplastic elastomer composition is partially or entirely crosslinked, a molding can be provided which is superior to the conventional vulcanized rubbers in low temperature properties, tensile strength, elongation at break and rubber properties.

7. 发明授权

US5696214A Process for preparing ethylene-.alpha.-olefin-nonconjugated polyene random copolymer 失效
标题翻译：制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法
公开(公告)号：US5696214A
公开(公告)日：1997-12-09
申请号：US575678
申请日：1995-12-19
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要翻译：公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在含有特定茂金属化合物的茂金属催化剂。通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下（iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。还公开了含有无规共聚物的可硫化橡胶组合物。乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。

8. 再颁专利

USRE37527E1 Heat-resistant rubber composition 有权
标题翻译：耐热橡胶组合物
公开(公告)号：USRE37527E1
公开(公告)日：2002-01-22
申请号：US09538790
申请日：2000-03-29
申请人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
发明人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
IPC分类号： C08F800
CPC分类号： C08K5/14 , C08K5/0025 , C08L23/0815 , C08L2312/00 , C08L23/16 , C08L2666/04
摘要： A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
摘要翻译：本发明的耐热橡胶组合物是包含特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和有机过氧化物（B）的可硫化组合物。该耐热组合物具有由有机过氧化物和高模量赋予的高交联效率，并且可以提供耐环境劣化如耐热老化性优异的耐硫化橡胶模制产品。本发明的另一种耐热橡胶组合物是一种可硫化组合物，其包含100重量份由乙烯，α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和作为含有乙烯基端基的降冰片烯化合物的非共轭多烯，0.2〜5重量份的胺型防老化剂（C）和/或受阻酚型抗老化剂（D），1〜10重量份的硫型防老化剂（E）和有机过氧化物（B）。该耐热橡胶组合物可以提供硫化橡胶模制产品，其不仅具有优异的机械性能和电性能，而且显示出高显着高的耐热老化性。

9. 发明授权

US6140441A Ethylenic random copolymer, process for preparing the same, and rubber composition 失效
标题翻译：乙烯无规共聚物，其制备方法和橡胶组合物
公开(公告)号：US6140441A
公开(公告)日：2000-10-31
申请号：US983636
申请日：1998-03-30
申请人： Takashi Hakuta , Mikio Hosoya , Tetsuo Tojo , Masaaki Kawasaki
发明人： Takashi Hakuta , Mikio Hosoya , Tetsuo Tojo , Masaaki Kawasaki
IPC分类号： C08F4/68 , C08F210/18
CPC分类号： C08F210/18
摘要： A process for preparing an ethylene/.alpha.-olefin/norbornene nonconjugated polyene random copolymer, comprising preparing an ethylene random copolymer simultaneously meeting the following requirements (1) to (5):(1) the molar ratio of ethylene (a) to an .alpha.-olefin (b) having 3 to 20 carbon atoms ranges from 40:60 to 95:5;(2) a given amount of non conjugated polyene (c) has a norbornene skeleton;(3) the available network chain density .nu. is not less than 1.5.times.10.sup.20 /cm.sup.3 after press cross-linking of the copolymer using a dicumyl peroxyde;(4) the ratio of the rate .gamma.1 of shear showing a shearing stress of 0.4.times.10.sup.6 dyn/cm.sup.2 as determined from the melt flow curve at 100.degree. C. and the rate .gamma.2 of shear showing a shearing stress of 2.4.times.10.sup.6 dyn/cm.sup.2, that is .gamma.2/.gamma.1 and the available network chain density .nu. has a relationship represented by the following general formula: 0.04.times.10.sup.-19 .ltoreq.Log(.gamma.2/.gamma.1)/.nu..ltoreq.0.20.times.10.sup.-19 ; and(5) the intrinsic viscosity [.eta.] ranges from 0.5 to 10 dl/g as measured in decalin at 135.degree. C. The copolymer has excellent cross-linkability, can be cross-linked with a small amount of a peroxide or the like, and a cross-linked rubber composition prepared using this copolymer has excellent heat aging resistance, mechanical strength, weather resistance, and oxone resistance.
摘要翻译： PCT No.PCT / JP97 / 01815 Sec。 371日期1998年3月30日 102（e）1998年3月30日PCT PCT 1997年5月28日PCT公布。公开号WO97 / 45466 日期1997年12月4日制备乙烯/α-烯烃/降冰片烯非共轭多烯无规共聚物的方法，包括同时制备满足以下要求（1）至（5）的乙烯无规共聚物：（1）乙烯 a）具有3至20个碳原子的α-烯烃（b）的范围为40:60至95:5; （2）给定量的非共轭多烯（c）具有降冰片烯骨架; （3）使用二枯基过氧化物压制交联共聚物后，可用的网络链密度nu不小于1.5×10 20 / cm 3; （4）从100℃的熔体流动曲线确定的剪切应力为剪切应力为0.4×10 6 dyn / cm 2的剪切速率γ1与剪切应力为2.4×10 6 dyn / cm 2，即γ2 /γ1，可用的网络链密度nu具有由以下通式表示的关系：0.04×10-19

10. 发明授权

US06346577B1 Heat-resistant rubber composition 有权
标题翻译：耐热橡胶组合物
公开(公告)号：US06346577B1
公开(公告)日：2002-02-12
申请号：US09514161
申请日：2000-02-28
申请人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
发明人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
IPC分类号： C08F834
CPC分类号： C08K5/14 , C08K5/0025 , C08L23/0815 , C08L2312/00 , C08L23/16 , C08L2666/04
摘要： The heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
摘要翻译：本发明的耐热橡胶组合物是一种可硫化组合物，其包含100重量份由乙烯，α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和作为含有乙烯基端基的降冰片烯化合物的非共轭多烯，0.2〜5重量份的胺型防老化剂（C）和/或受阻酚型抗老化剂（D），1〜10重量份硫类抗老化剂（E）和有机过氧化物（B）的重量。该耐热橡胶组合物可以提供硫化橡胶模制产品，其不仅具有优异的机械性能和电性能，而且显示出高显着高的耐热老化性。

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