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1. 发明授权

US06784213B2 Method for preparation of strong acid cation exchange resins 有权
标题翻译：强酸阳离子交换树脂的制备方法
公开(公告)号：US06784213B2
公开(公告)日：2004-08-31
申请号：US10158664
申请日：2002-05-30
申请人： William Douglas Rohrbach , Bruce Maurice Rosenbaum
发明人： William Douglas Rohrbach , Bruce Maurice Rosenbaum
IPC分类号： C08F834
CPC分类号： B01J39/20 , C02F2001/427 , C02F2101/101 , C08F8/36 , C08J5/20 , C08F212/08 , C08F212/36
摘要： An improved process for preparing strong acid cation exchange resins by sulfonation of wet crosslinked copolymer in the absence of organic swelling solvents is disclosed. This process involves dewatering a crosslinked poly(vinylaromatic) copolymer to selected residual moisture levels of 3 to 35%, followed by non-solvent sulfonation, to provide strong acid cation exchange resins having enhanced physical stability and that are free of chlorinated-solvent contaminants.
摘要翻译：公开了通过在不存在有机溶胀溶剂的情况下磺化湿交联共聚物制备强酸阳离子交换树脂的改进方法。该方法包括将交联的聚（乙烯基芳族化合物）共聚物脱水至3至35％的选定残余水分含量，然后进行非溶剂磺化，以提供具有增强的物理稳定性且不含氯化溶剂污染物的强酸阳离子交换树脂。

2. 发明授权

US06548606B1 Method of forming grafted copolymers 有权
标题翻译：形成接枝共聚物的方法
公开(公告)号：US06548606B1
公开(公告)日：2003-04-15
申请号：US10055125
申请日：2002-01-23
申请人： Eleanor M. De Groot , Martin L. Hess , Robert B. Rhodes
发明人： Eleanor M. De Groot , Martin L. Hess , Robert B. Rhodes
IPC分类号： C08F834
CPC分类号： C08F291/00 , C08F287/00 , C08L51/006 , C08L2666/02
摘要： A process for preparing a grafted polymer in which a substrate polymer is graft reacted with a nitrogen-containing grafting monomer in the presence of a free radical initiator and an amide coupling inhibitor that reduces polymer crosslinking during the graft reaction.
摘要翻译：接枝聚合物的制备方法，其中底物聚合物与含氮接枝单体在自由基引发剂和酰胺偶联抑制剂的存在下接枝反应，其在接枝反应期间降低聚合物交联。

3. 发明授权

US06476154B1 Use of carbon black in curable rubber compounds 失效
标题翻译：在可固化橡胶混合物中使用炭黑
公开(公告)号：US06476154B1
公开(公告)日：2002-11-05
申请号：US09675079
申请日：2000-09-28
申请人： Neil Arthur Maly , Jerry Donald Hunt , Dennis Keith Romain
发明人： Neil Arthur Maly , Jerry Donald Hunt , Dennis Keith Romain
IPC分类号： C08F834
CPC分类号： B82Y30/00 , C08K3/04 , Y10S977/734 , Y10S977/753 , Y10S977/788 , C08L21/00
摘要： A rubber composition is provided comprising a diene-based elastomer, a vulcanizing agent, a vulcanizing accelerator and a reinforcement comprising a conical carbon. The conical carbon comprises cones, flat plates, nanotubes and fullerenes. Also provided is a tire having at least one component fabricated from the rubber composition.
摘要翻译：提供了一种橡胶组合物，其包含二烯类弹性体，硫化剂，硫化促进剂和包含圆锥形碳的增强剂。锥形碳包括锥体，平板，纳米管和富勒烯。还提供了具有由橡胶组合物制成的至少一种组分的轮胎。

4. 发明授权

US06437012B1 Low-swelling, macroporous polymer-supported reagents for organic synthesis and purification 失效
标题翻译：低膨胀，大孔聚合物负载的有机合成和纯化试剂
公开(公告)号：US06437012B1
公开(公告)日：2002-08-20
申请号：US09428162
申请日：1999-10-27
申请人： Qunjie Wang
发明人： Qunjie Wang
IPC分类号： C08F834
CPC分类号： C08F8/00 , C08F8/30 , C08F2810/20 , C08F212/14 , C08F8/34
摘要： A low-swelling, highly crosslinked, macroporous polystyrene resin containing functional groups which are capable of selectively binding to reaction impurities, such as excess reactant or reaction by-products, which are contained in a reaction medium. The reaction impurities can thereby be efficiently removed from the reaction medium, providing a convenient method for product purification.
摘要翻译：含有官能团的低膨胀，高度交联的大孔聚苯乙烯树脂，其能够选择性地结合反应介质中所含的反应杂质，例如过量的反应物或反应副产物。从而可以有效地从反应介质中除去反应杂质，提供方便的产物纯化方法。

5. 发明授权

US06252008B1 Solution rubbers containing hydroxyl groups 失效
标题翻译：含有羟基的溶液橡胶
公开(公告)号：US06252008B1
公开(公告)日：2001-06-26
申请号：US09350261
申请日：1999-07-08
申请人： Thomas Scholl , Ulrich Eisele , Jürgen Trimbach , Stefan Kelbch
发明人： Thomas Scholl , Ulrich Eisele , Jürgen Trimbach , Stefan Kelbch
IPC分类号： C08F834
CPC分类号： C08J3/212 , C08C19/20 , C08F236/10 , C08J2309/06 , C08L19/006 , Y02T10/862
摘要： The invention relates to rubber blends containing said at least one solution-polymerized rubber containing hydroxyl groups, synthesized from diolefins and vinylaromatic monomers, wherein said at least one solution-polymerized rubber containing hydroxyl groups contain in the region of 0.1 to 5wt.% of bonded hydroxyl groups, to a process for their preparation and to their use for the production of all kinds of moldings.
摘要翻译：本发明涉及含有由二烯烃和乙烯基芳族单体合成的含有羟基的所述至少一种溶液聚合橡胶的橡胶共混物，其中所述至少一种含羟基的溶液聚合橡胶含有0.1-5重量％羟基，其制备方法及其用于生产各种模塑品的用途。

6. 发明授权

US06833412B2 Acid functional fluoropolymer membranes and method of manufacture 有权
标题翻译：酸官能含氟聚合物膜及其制造方法
公开(公告)号：US06833412B2
公开(公告)日：2004-12-21
申请号：US10195221
申请日：2002-07-15
申请人： Steven J. Hamrock , Naiyong Jing , Shane S. Mao , L. Charles Hardy
发明人： Steven J. Hamrock , Naiyong Jing , Shane S. Mao , L. Charles Hardy
IPC分类号： C08F834
CPC分类号： C08L27/22 , C08F8/26 , C08J5/225 , C08L27/16 , C08L2205/02 , H01M8/1023 , H01M8/1039 , H01M8/1072 , Y02P70/56 , C08F14/18 , C08L2666/04
摘要： Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.
摘要翻译：提供通过以下方式制备酸官能含氟聚合物的方法：a）用脱氟化氢剂使起始含氟聚合物脱氟化氢以形成不饱和含氟聚合物; b）将可酸化的亲核官能化剂加入到不饱和含氟聚合物的双键中; 和c）酸化所添加的酸化功能。还提供了酸官能含氟聚合物及其离子传导膜，包括具有根据下式的侧基的酸官能含氟聚合物：-X-Ar-An，其中X选自O，S或NR，其中R选自H和C1 -C30烷基或芳基，其任选被取代，其中Ar是任选取代的C 6 -C 30芳族基团，其中A是酸性官能团或其盐，其中A可以独立地选择为1,2或3。

7. 发明授权

US06699913B1 Process for preparing monodisperse anion exchangers having strongly basic functional groups 失效
标题翻译：制备具有强碱性官能团的单分散阴离子交换剂的方法
公开(公告)号：US06699913B1
公开(公告)日：2004-03-02
申请号：US09642799
申请日：2000-08-21
申请人： Reinhold Klipper , Ulrich Schnegg , Rüdiger Seidel , Hans-Karl Soest , Alfred Mitschker , Holger Lütjens
发明人： Reinhold Klipper , Ulrich Schnegg , Rüdiger Seidel , Hans-Karl Soest , Alfred Mitschker , Holger Lütjens
IPC分类号： C08F834
CPC分类号： B01J41/04 , B01J41/14 , C02F1/42 , C08F8/44 , C08F2800/20 , C08F8/30 , C08F212/08
摘要： The present invention relates to a process for preparing novel, monodisperse anion exchangers having strongly basic functional groups either in the center of the resin particle or in the shell of the resin particle, as well as to their use.
摘要翻译：本发明涉及在树脂颗粒的中心或树脂颗粒的壳中制备具有强碱性官能团的新型单分散阴离子交换剂的方法及其用途。

8. 发明授权

US06649703B2 Cross-linked sulphonated polymers and their preparation process 有权
标题翻译：交联磺化聚合物及其制备方法
公开(公告)号：US06649703B2
公开(公告)日：2003-11-18
申请号：US10094047
申请日：2002-03-08
申请人： Christophe Michot , Michel Armand
发明人： Christophe Michot , Michel Armand
IPC分类号： C08F834
CPC分类号： C08J5/225 , C08F8/44 , C08F214/18 , C08J5/2218 , C08J2327/12
摘要： The present invention is concerned with cross-linked sulfonated polymers, eventually perfluorinated, and their preparation process. When molded in the form of membranes, the polymers are useful in electrochemical cells, in a chlorine-sodium electrolysis process, as separator in an electrochemical preparation or organic and inorganic compounds, as separators between an aqueous phase and an organic phase, or as catalyst for Diels-Alder additions, Friedel-Craft reactions, aldol concentrations, cationic polymerization, esterification, and acetal formation.
摘要翻译：本发明涉及最终全氟化的交联磺化聚合物及其制备方法。当以膜的形式成型时，聚合物可用于电化学电池，氯 - 钠电解方法中，作为电化学制剂中的分离剂或有机和无机化合物，作为水相和有机相之间的分离剂，或作为催化剂对于Diels-Alder添加物，Friedel-Craft反应，醛醇浓度，阳离子聚合，酯化和缩醛形成。

9. 发明授权

US06608145B1 Silica-reinforced rubber compounded with an organosilane tetrasulfide silica coupling agent at high mixing temperature 有权
标题翻译：二氧化硅增强橡胶与有机硅烷四硫化硅偶联剂在高混合温度下配混
公开(公告)号：US06608145B1
公开(公告)日：2003-08-19
申请号：US09687437
申请日：2000-10-13
申请人： Chenchy Jeffrey Lin , William L. Hergenrother , Ashley S. Hilton
发明人： Chenchy Jeffrey Lin , William L. Hergenrother , Ashley S. Hilton
IPC分类号： C08F834
CPC分类号： C08K3/36 , C08K5/372 , C08L21/00
摘要： Sulfur-vulcanizable elastomeric compounds and pneumatic tire components having improved tensile mechanical and dynamic viscoelastic properties are produced by compounding polymers with silica at a temperature of 165° C. to about 200° C., in the presence of a silica dispersing agent, and a very small amount (e.g., about 0.01% to about 1% by weight, based on the weight of the silica) of a bis(trialkoxysilylorgano) tetrasulfide silica coupling agent.
摘要翻译：具有改进的拉伸机械和动态粘弹性的硫磺可硫化弹性体组合物和充气轮胎组分通过在二氧化硅分散剂存在下在165℃至约200℃的温度下与二氧化硅混合来制备，非常少的量（例如，基于二氧化硅的重量计约0.01％至约1重量％）双（三烷氧基甲硅烷基有机基）四硫化硅偶联剂。

10. 发明授权

US06350818B1 Anti reflective coating polymers and the preparation method thereof 失效
标题翻译：防反射涂料聚合物及其制备方法
公开(公告)号：US06350818B1
公开(公告)日：2002-02-26
申请号：US09413679
申请日：1999-10-07
申请人： Sung-Eun Hong , Min-Ho Jung , Hyeong-Soo Kim , Ki-Ho Baik
发明人： Sung-Eun Hong , Min-Ho Jung , Hyeong-Soo Kim , Ki-Ho Baik
IPC分类号： C08F834
CPC分类号： C08F212/14 , C08F8/34 , G03F7/023 , G03F7/091 , C08F12/14 , C08F220/20
摘要： The present invention relates to organic anti-reflective coating polymers and preparation methods therefor. Anti-reflective coatings are used in a semiconductor device during photolithography processes to prevent the reflection of light from lower layers of the device, or resulting from changes in the thickness of the photoresist layer, and to eliminate the standing wave effect when ArF light is used. The present invention also relates to anti-reflective compositions and coatings containing these organic anti-reflective coating polymers, alone or in combination with certain light-absorbing compounds, and preparation methods therefor. When the polymers of the present invention are used in an anti-reflective coating in a photolithography process for forming submicro-patterns, the resultant elimination of changes in CD due to diffractive and reflective lights originating from lower layers increases the product yield in the formation of submicro-patterns during the manufacture of 64 M, 256 M, 1G, 4G and 16G DRAM semiconductor devices.
摘要翻译：本发明涉及有机抗反射涂层聚合物及其制备方法。在光刻工艺中，抗反射涂层用于半导体器件，以防止来自器件的下层的光的反射，或由于光致抗蚀剂层的厚度的变化而导致的，并且当使用ArF光时消除驻波效应。本发明还涉及包含这些有机抗反射涂层聚合物的抗反射组合物和涂层，其单独或与某些光吸收化合物组合，及其制备方法。当本发明的聚合物在用于形成亚微图案的光刻工艺中用于抗反射涂层中时，由于衍生于较低层的衍射和反射光引起的CD的变化的消除增加了在形成在64M，256M，1G，4G和16G DRAM半导体器件的制造期间的微小图案。

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