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    • 5. 发明授权
    • Vulcanizable rubber composition containing
ehtylene-.alpha.-olefin-nonconjugated polyene random copolymer
    • 含有乙烯-α-烯烃 - 非共轭多烯无规共聚物的可硫化橡胶组合物
    • US5807948A
    • 1998-09-15
    • US783238
    • 1997-01-14
    • Toshihiro SaganeToshiyuki TsutsuiMasaaki KawasakiKeiji OkadaHidenari NakahamaTetsuo Tojo
    • Toshihiro SaganeToshiyuki TsutsuiMasaaki KawasakiKeiji OkadaHidenari NakahamaTetsuo Tojo
    • C08F4/64C08F4/659C08F4/6592C08F210/18C08L23/16C08F236/20
    • C08F210/18C08L23/16C08F4/65912C08F4/65927C08L2312/00Y10S526/943
    • Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
    • 公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法,包括(a)乙烯,(b)3个或更多个碳原子的α-烯烃和(c)非共轭多烯在 含有特定茂金属化合物的茂金属催化剂。 通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性:(i)共聚物含有衍生自乙烯(a)的单元和衍生自3个或更多个碳原子的(b)的α-烯烃的单元 摩尔比为40/60〜95/5 [(a)/(b)],(ii)碘值为1〜50,(iii)特性粘度(η)大于0.1dl / g以下 (iv)13 C-NMR光谱中的Tαβ与Tαα的强度比D(Tαβ/Tαα)不大于0.5,(v)B值为 1.00至1.50,(vi)玻璃化转变温度Tg不高于-50℃,(vii)上述定义的共聚物的特性粘度(η)与特性粘度(η)的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔%(eta)/(η)空白的直链乙烯 - 丙烯共聚物大于0.9。 还公开了含有无规共聚物的可硫化橡胶组合物。 乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度,耐候性,耐臭氧性,加工性,低温柔韧性和耐热性都优异。
    • 8. 发明授权
    • Process for preparing ethylene-.alpha.-olefin-nonconjugated polyene
random copolymer
    • 制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法
    • US5696214A
    • 1997-12-09
    • US575678
    • 1995-12-19
    • Toshihiro SaganeToshiyuki TsutsuiMasaaki KawasakiKeiji OkadaHidenari NakahamaTetsuo Tojo
    • Toshihiro SaganeToshiyuki TsutsuiMasaaki KawasakiKeiji OkadaHidenari NakahamaTetsuo Tojo
    • C08F4/64C08F4/659C08F4/6592C08F210/18C08L23/16C08F236/20
    • C08F210/18C08L23/16C08F4/65912C08F4/65927C08L2312/00Y10S526/943
    • Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
    • 公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法,包括(a)乙烯,(b)3个或更多个碳原子的α-烯烃和(c)非共轭多烯在 含有特定茂金属化合物的茂金属催化剂。 通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性:(i)共聚物含有衍生自乙烯(a)的单元和衍生自3个或更多个碳原子的(b)的α-烯烃的单元 摩尔比为40/60〜95/5 [(a)/(b)],(ii)碘值为1〜50,(iii)特性粘度(η)大于0.1dl / g以下 (iv)13 C-NMR光谱中的Tαβ与Tαα的强度比D(Tαβ/Tαα)不大于0.5,(v)B值为 1.00至1.50,(vi)玻璃化转变温度Tg不高于-50℃,(vii)上述定义的共聚物的特性粘度(η)与特性粘度(η)的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔%(eta)/(η)空白的直链乙烯 - 丙烯共聚物大于0.9。 还公开了含有无规共聚物的可硫化橡胶组合物。 乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度,耐候性,耐臭氧性,加工性,低温柔韧性和耐热性都优异。
    • 10. 发明授权
    • Foam processable rubber compositions and vulcanized rubber foam molded
products of the same
    • 泡沫加工橡胶组合物和硫化橡胶发泡成型制品相同
    • US5962543A
    • 1999-10-05
    • US971107
    • 1997-11-14
    • Masaaki KawasakiShuichi NonakaMasao KunizaneTaku KodaTetsuo Tojo
    • Masaaki KawasakiShuichi NonakaMasao KunizaneTaku KodaTetsuo Tojo
    • C08L23/16C08J9/00
    • C08L23/16C08L2203/14C08L2312/00
    • Disclosed is a foam processable rubber composition which comprises an ethylene/.alpha.-olefin of 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber (A), a crystalline polyolefin resin (B) having a melting point of 100 to 150.degree. C. and a foaming agent (C), in specific proportions. The copolymer rubber (A) has an ethylene/.alpha.-olefin molar ratio of 60/40 to 80/20, an intrinsic viscosity (.eta.), as measured in decalin at 135.degree. C., of 0.7 to 2 dl/g, and an iodine value of 10 to 50. A vulcanized rubber foam-molded product can be obtained by vulcanizing and foaming the rubber composition. The rubber composition can provide vulcanized rubber foam-molded products having excellent vulcanization properties such as weathering resistance, heat resistance, ozone resistance and tear strength. Besides, the rubber composition exhibits excellent precision moldability and productivity of vulcanized rubber foam-molded products in transfer molding, injection molding and cast molding.
    • 公开了一种可发泡加工的橡胶组合物,其包含3至20个碳原子的乙烯/α-烯烃/非共轭多烯共聚物橡胶(A),熔点为100-150℃的结晶聚烯烃树脂(B) 和发泡剂(C)。 共聚物橡胶(A)的乙烯/α-烯烃摩尔比为60/40至80/20,在135℃萘烷中测定的特性粘度(η)为0.7-2dl / g,和 碘值为10〜50。通过硫化和发泡橡胶组合物可以获得硫化橡胶发泡成型产品。 橡胶组合物可以提供具有优异的硫化性能如耐候性,耐热性,耐臭氧性和撕裂强度的硫化橡胶发泡成型产品。 此外,橡胶组合物在传递成型,注射成型和铸造成型中表现出优异的成型性和硫化橡胶发泡成型体的生产率。