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1. 发明授权

US6140441A Ethylenic random copolymer, process for preparing the same, and rubber composition 失效
标题翻译：乙烯无规共聚物，其制备方法和橡胶组合物
公开(公告)号：US6140441A
公开(公告)日：2000-10-31
申请号：US983636
申请日：1998-03-30
申请人： Takashi Hakuta , Mikio Hosoya , Tetsuo Tojo , Masaaki Kawasaki
发明人： Takashi Hakuta , Mikio Hosoya , Tetsuo Tojo , Masaaki Kawasaki
IPC分类号： C08F4/68 , C08F210/18
CPC分类号： C08F210/18
摘要： A process for preparing an ethylene/.alpha.-olefin/norbornene nonconjugated polyene random copolymer, comprising preparing an ethylene random copolymer simultaneously meeting the following requirements (1) to (5):(1) the molar ratio of ethylene (a) to an .alpha.-olefin (b) having 3 to 20 carbon atoms ranges from 40:60 to 95:5;(2) a given amount of non conjugated polyene (c) has a norbornene skeleton;(3) the available network chain density .nu. is not less than 1.5.times.10.sup.20 /cm.sup.3 after press cross-linking of the copolymer using a dicumyl peroxyde;(4) the ratio of the rate .gamma.1 of shear showing a shearing stress of 0.4.times.10.sup.6 dyn/cm.sup.2 as determined from the melt flow curve at 100.degree. C. and the rate .gamma.2 of shear showing a shearing stress of 2.4.times.10.sup.6 dyn/cm.sup.2, that is .gamma.2/.gamma.1 and the available network chain density .nu. has a relationship represented by the following general formula: 0.04.times.10.sup.-19 .ltoreq.Log(.gamma.2/.gamma.1)/.nu..ltoreq.0.20.times.10.sup.-19 ; and(5) the intrinsic viscosity [.eta.] ranges from 0.5 to 10 dl/g as measured in decalin at 135.degree. C. The copolymer has excellent cross-linkability, can be cross-linked with a small amount of a peroxide or the like, and a cross-linked rubber composition prepared using this copolymer has excellent heat aging resistance, mechanical strength, weather resistance, and oxone resistance.
摘要翻译： PCT No.PCT / JP97 / 01815 Sec。 371日期1998年3月30日 102（e）1998年3月30日PCT PCT 1997年5月28日PCT公布。公开号WO97 / 45466 日期1997年12月4日制备乙烯/α-烯烃/降冰片烯非共轭多烯无规共聚物的方法，包括同时制备满足以下要求（1）至（5）的乙烯无规共聚物：（1）乙烯 a）具有3至20个碳原子的α-烯烃（b）的范围为40:60至95:5; （2）给定量的非共轭多烯（c）具有降冰片烯骨架; （3）使用二枯基过氧化物压制交联共聚物后，可用的网络链密度nu不小于1.5×10 20 / cm 3; （4）从100℃的熔体流动曲线确定的剪切应力为剪切应力为0.4×10 6 dyn / cm 2的剪切速率γ1与剪切应力为2.4×10 6 dyn / cm 2，即γ2 /γ1，可用的网络链密度nu具有由以下通式表示的关系：0.04×10-19

2. 再颁专利

USRE37527E1 Heat-resistant rubber composition 有权
标题翻译：耐热橡胶组合物
公开(公告)号：USRE37527E1
公开(公告)日：2002-01-22
申请号：US09538790
申请日：2000-03-29
申请人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
发明人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
IPC分类号： C08F800
CPC分类号： C08K5/14 , C08K5/0025 , C08L23/0815 , C08L2312/00 , C08L23/16 , C08L2666/04
摘要： A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
摘要翻译：本发明的耐热橡胶组合物是包含特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和有机过氧化物（B）的可硫化组合物。该耐热组合物具有由有机过氧化物和高模量赋予的高交联效率，并且可以提供耐环境劣化如耐热老化性优异的耐硫化橡胶模制产品。本发明的另一种耐热橡胶组合物是一种可硫化组合物，其包含100重量份由乙烯，α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和作为含有乙烯基端基的降冰片烯化合物的非共轭多烯，0.2〜5重量份的胺型防老化剂（C）和/或受阻酚型抗老化剂（D），1〜10重量份的硫型防老化剂（E）和有机过氧化物（B）。该耐热橡胶组合物可以提供硫化橡胶模制产品，其不仅具有优异的机械性能和电性能，而且显示出高显着高的耐热老化性。

3. 发明授权

US06346577B1 Heat-resistant rubber composition 有权
标题翻译：耐热橡胶组合物
公开(公告)号：US06346577B1
公开(公告)日：2002-02-12
申请号：US09514161
申请日：2000-02-28
申请人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
发明人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
IPC分类号： C08F834
CPC分类号： C08K5/14 , C08K5/0025 , C08L23/0815 , C08L2312/00 , C08L23/16 , C08L2666/04
摘要： The heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
摘要翻译：本发明的耐热橡胶组合物是一种可硫化组合物，其包含100重量份由乙烯，α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和作为含有乙烯基端基的降冰片烯化合物的非共轭多烯，0.2〜5重量份的胺型防老化剂（C）和/或受阻酚型抗老化剂（D），1〜10重量份硫类抗老化剂（E）和有机过氧化物（B）的重量。该耐热橡胶组合物可以提供硫化橡胶模制产品，其不仅具有优异的机械性能和电性能，而且显示出高显着高的耐热老化性。

4. 发明授权

US5733983A Heat-resistant rubber composition 失效
标题翻译：耐热橡胶组合物
公开(公告)号：US5733983A
公开(公告)日：1998-03-31
申请号：US750821
申请日：1996-12-10
申请人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
发明人： Takashi Hakuta , Tetsuo Tojo , Masaaki Kawasaki , Mikio Hosoya
IPC分类号： C08K5/00 , C08K5/14 , C08L23/08 , C08F8/00
CPC分类号： C08K5/14 , C08K5/0025 , C08L23/0815 , C08L2312/00
摘要： A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an .alpha.-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.
摘要翻译： PCT No.PCT / JP96 / 00991 Sec。 371日期1996年12月10日第 102（e）日期1996年12月10日PCT 1996年4月11日PCT PCT。出版物WO96 / 32442 日期1996年10月17日本发明的耐热橡胶组合物是包含特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和有机过氧化物（B）的可硫化组合物。该耐热组合物具有由有机过氧化物和高模量赋予的高交联效率，并且可以提供耐环境劣化如耐热老化性优异的耐硫化橡胶模制产品。本发明的另一种耐热橡胶组合物是一种可硫化组合物，其包含100重量份由乙烯，α-烯烃或3至20个碳原子组成的特定乙烯-α-烯烃 - 非共轭多烯共聚物橡胶（A）和作为含有乙烯基端基的降冰片烯化合物的非共轭多烯，0.2〜5重量份的胺型防老化剂（C）和/或受阻酚型抗老化剂（D），1〜10重量份的硫型防老化剂（E）和有机过氧化物（B）。该耐热橡胶组合物可以提供硫化橡胶模制产品，其不仅具有优异的机械性能和电性能，而且显示出高显着高的耐热老化性。

5. 发明授权

US06864315B1 Crosslinkable rubber compositions and use thereof 有权
标题翻译：可交联橡胶组合物及其用途
公开(公告)号：US06864315B1
公开(公告)日：2005-03-08
申请号：US09673608
申请日：2000-03-14
申请人： Takashi Hakuta , Masaaki Kawasaki , Yoshiharu Kikuchi , Hidenari Nakahama , Taku Koda , Hiroshi Kameda , Shuichi Nonaka , Mikio Hosoya , Yuji Ishii , Mitsunao Arino , Tsutomu Nakamura , Satao Hirabayashi , Takeo Yoshida
发明人： Takashi Hakuta , Masaaki Kawasaki , Yoshiharu Kikuchi , Hidenari Nakahama , Taku Koda , Hiroshi Kameda , Shuichi Nonaka , Mikio Hosoya , Yuji Ishii , Mitsunao Arino , Tsutomu Nakamura , Satao Hirabayashi , Takeo Yoshida
IPC分类号： C08K5/00 , C08L23/16 , C08L83/04 , C08L47/00
CPC分类号： C08K5/0025 , C08L23/16 , C08L83/04 , C08L2312/08 , C08L2314/02 , C08L83/00
摘要： The crosslinkable rubber composition of the invention is crosslinkable by hot air, and a hot-air crosslinked rubber sheet thereof has no scratch on the surface in a hardness test using a pencil of HB and has a compression set of not more than 70% after a heat treatment at 150° C. for 22 hours. The rubber composition comprises an ethylene/α-olefin/non-conjugated polyene random copolymer rubber comprising a specific vinyl end group-containing norbornene compound, a SiH group-containing compound having at least two SiH groups in one molecule, and if necessary, an addition reaction catalyst comprising a platinum group element and a reaction inhibitor. The automobile weatherstrip, hose, rubber vibration insulator, belt, sealing material, expanded product, covered electric wire, electric wire joint, electric insulating part and household rubber product according to the invention comprise the above-mentioned rubber composition. The rubber composition has a high crosslinking rate and excellent productivity to produce crosslinked rubber molded products, is capable of undergoing hot-air crosslinking such as HAV or UHF and is capable of providing crosslinked rubber molded products having excellent compression set resistance, strength properties, heat resistance, weathering resistance and abrasion resistance.
摘要翻译：本发明的交联性橡胶组合物可以通过热风进行交联，在使用HB的铅笔的硬度试验中，热风交联橡胶片在表面没有刮痕，并且在a后的压缩永久变形为70％以上在150℃下热处理22小时。该橡胶组合物包含一个乙烯/α-烯烃/非共轭多烯无规共聚物橡胶，其包含特定的含乙烯基端基的降冰片烯化合物，在一个分子中具有至少两个SiH基团的含SiH基化合物，如果需要，包含铂族元素和反应抑制剂的加成反应催化剂。根据本发明的汽车密封条，软管，橡胶振动绝缘子，带，密封材料，膨胀产品，包覆电线，电线接头，电绝缘部件和家用橡胶制品包括上述橡胶组合物。橡胶组合物具有高交联率和优异的生产交联橡胶成型体的生产率，能够进行热风交联如HAV或UHF，并且能够提供具有优异的耐压缩变形性，强度性能，热性能的交联橡胶模制产品耐电阻，耐候性和耐磨性。

6. 发明授权

US06599984B1 Rubber modified with ethylene/&agr;-olefin(/diene) rubber(s) 有权
标题翻译：用乙烯/α-烯烃（/二烯）橡胶改性的橡胶
公开(公告)号：US06599984B1
公开(公告)日：2003-07-29
申请号：US09556936
申请日：2000-04-21
申请人： Masaaki Kawasaki , Taku Koda , Takashi Hakuta , Tetsuo Tojo
发明人： Masaaki Kawasaki , Taku Koda , Takashi Hakuta , Tetsuo Tojo
IPC分类号： C08L2308
CPC分类号： C08L23/16 , C08L2205/02 , C08L2666/04
摘要： A blend of a rubber and a rubber modifier, the rubber modifier comprising an ethylene/&agr;-olefin copolymer rubber (A) composed of one or more copolymers selected from the group consisting of a copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and a copolymer of ethylene, an &agr;-olefin having 3-20 carbon atoms and a non-conjugated polyene, the copolymer rubber (A) having the parameters: an ethylene/&agr;-olefin mole ratio in the range of 51/49 to 87/13, an intrinsic viscosity [&eegr;] determined in decahydronaphthalene at 135° C. in the range of 0.8 to 2.5 dl/g and an iodine value in the range of 0 to 40.
摘要翻译：橡胶和橡胶改性剂的共混物，橡胶改性剂包括由一种或多种共聚物组成的乙烯/α-烯烃共聚物橡胶（A），所述共聚物选自乙烯和具有3-20的α-烯烃的共聚物碳原子和乙烯，具有3-20个碳原子的α-烯烃和非共轭多烯的共聚物，共聚物橡胶（A）具有参数：乙烯/α-烯烃摩尔比在51/49范围内至87/13，在十氢萘中在135℃下测定的特性粘度在0.8至2.5dl / g的范围内，碘值在0至40的范围内。

7. 发明授权

US06458894B1 Rubber modifier of ethylene/&agr;-olefin (/diene) copolymer rubber(s) 失效
标题翻译：乙烯/α-烯烃（/二烯）共聚物橡胶的橡胶改性剂
公开(公告)号：US06458894B1
公开(公告)日：2002-10-01
申请号：US08927893
申请日：1997-09-11
申请人： Masaaki Kawasaki , Taku Koda , Takashi Hakuta , Tetsuo Tojo
发明人： Masaaki Kawasaki , Taku Koda , Takashi Hakuta , Tetsuo Tojo
IPC分类号： C08L2308
CPC分类号： C08L23/16 , C08L2205/02 , C08L2666/04
摘要： A rubber modifier comprises an ethylene/&agr;-olefin copolymer rubber (A) composed of one or more copolymers selected from the group consisting of a copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and a copolymer of ethylene, an &agr;-olefin having 3-20 carbon atoms and a non-conjugated polyene, the copolymer rubber (A) having the parameters: an ethylene/&agr;-olefin mole ratio in the range of 51/49 to 87/13, an intrinsic viscosity [&eegr;] determined in decahydronaphthalene at 135° C. in the range of 0.8 to 2.5 dl/g and an iodine value in the range of 0 to 40.
摘要翻译：橡胶改性剂包括由一种或多种共聚物组成的乙烯/α-烯烃共聚物橡胶（A），所述共聚物选自由乙烯和具有3-20个碳原子的α-烯烃的共聚物和乙烯的共聚物，α 具有3-20个碳原子的α-烯烃和非共轭多烯，所述共聚物橡胶（A）具有以下参数：乙烯/α-烯烃摩尔比在51/49至87/13的范围内，特性粘度[η ]在十氢萘中在135℃下测定，在0.8至2.5dl / g的范围内，碘值在0至40的范围内。

8. 发明授权

US06569936B1 Rubber composition for a conveyor belt 有权
标题翻译：用于输送带的橡胶组合物
公开(公告)号：US06569936B1
公开(公告)日：2003-05-27
申请号：US09717275
申请日：2000-11-22
申请人： Masaaki Kawasaki , Takashi Hakuta , Hidenari Nakahama , Tetsuo Tojo
发明人： Masaaki Kawasaki , Takashi Hakuta , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08K304
CPC分类号： C08K5/01 , C08K3/04 , C08K5/14 , C08L23/16 , C08L91/00 , C08L2666/02
摘要： According to the present invention, there is provided a rubber composition for a conveyor belt comprising (A) 100 parts by weight of an ethylene/&agr;-olefin containing 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber containing a diene unit derived from special non-conjugated dienes, (B) 0.5 to 15 parts by weight of an organic peroxide, (C) 30 to 80 parts by weight of a carbon black and (D) 5 to 25 parts by weight of a softening agent. This rubber composition provides excellent mechanical strength, heat resistance (including heat aging resistance), abrasion resistance and roll processability. It is especially preferred to convey a sintered product, a coke, a cement, clinker and quicklime.
摘要翻译：根据本发明，提供了一种用于输送带的橡胶组合物，其包含（A）100重量份含有3-20个碳原子的乙烯/α-烯烃/非共轭多烯共聚物橡胶，其含有衍生自特殊的非共轭二烯，（B）0.5〜15重量份的有机过氧化物，（C）30〜80重量份的炭黑和（D）5〜25重量份的软化剂。组合物提供优异的机械强度，耐热性（包括耐热老化性），耐磨性和辊加工性。特别优选输送烧结产品，焦炭，水泥，熟料和生石灰。

9. 发明授权

US5698651A Ethylene copolymer rubber, vulcanizable rubber composition containing the copolymer rubber, and process for preparing the copolymer rubber 失效
标题翻译：含有共聚物橡胶的乙烯共聚物橡胶，可硫化橡胶组合物，以及共聚物橡胶的制备方法
公开(公告)号：US5698651A
公开(公告)日：1997-12-16
申请号：US665342
申请日：1996-06-17
申请人： Masaaki Kawasaki , Toshiyuki Tsutsui , Tetsuo Tojo , Takashi Hakuta
发明人： Masaaki Kawasaki , Toshiyuki Tsutsui , Tetsuo Tojo , Takashi Hakuta
IPC分类号： C08F4/64 , C08F4/6592 , C08F210/18 , C08F236/20
CPC分类号： C08F210/18 , C08F4/65927 , Y10S526/943
摘要： Disclosed is an ethylene copolymer rubber which is a random copolymer rubber of (a) ethylene, (b) an .alpha.-olefin of 3 to 20 carbon atoms, (c) a nonconjugated polyene containing, in one molecule, one carbon-to-carbon double bond polymerizable by a metallocene catalyst among carbon-to-carbon double bonds, and (d) a nonconjugated polyene containing, in one molecule, two carbon-to-carbon double bonds polymerizable by the metallocene catalyst among carbon-to-carbon double bonds. The ethylene copolymer rubber has excellent moldability, high vulcanization rate, good mechanical properties such as high vulcanization strength, excellent low-temperature flexibility and thermal aging resistance. Also disclosed is a process for preparing the ethylene copolymer rubber with high activity, high conversion ratio of .alpha.-olefin and high random copolymerizability.
摘要翻译：公开了一种乙烯共聚物橡胶，它是（a）乙烯，（b）3-20个碳原子的α-烯烃的无规共聚物橡胶，（c）一个分子中含有一个碳 - 碳的非共轭多烯通过茂金属催化剂在碳 - 碳双键中可聚合的双键，和（d）在一个分子中含有由碳 - 碳双键中的茂金属催化剂可聚合的两个碳 - 碳双键的非共轭多烯。乙烯共聚物橡胶具有优异的成型性，高硫化速度，良好的机械性能，如高硫化强度，优异的低温柔韧性和耐热老化性。还公开了一种制备具有高活性，高转化率的α-烯烃和高无规共聚性的乙烯共聚物橡胶的方法。

10. 发明申请

US20070015893A1 Curable composition and its use 审中-公开
公开(公告)号：US20070015893A1
公开(公告)日：2007-01-18
申请号：US11515318
申请日：2006-09-05
申请人： Takashi Hakuta , Masaaki Kawasaki , Yoshiharu Kikuchi , Mitsunao Arino , Mitsuko Nagai , Hiroaki Sakaguchi , Masaki Sugawara , Masao Kishi , Kaoru Ueno , Takashi Abe , Michio Sekine
发明人： Takashi Hakuta , Masaaki Kawasaki , Yoshiharu Kikuchi , Mitsunao Arino , Mitsuko Nagai , Hiroaki Sakaguchi , Masaki Sugawara , Masao Kishi , Kaoru Ueno , Takashi Abe , Michio Sekine
IPC分类号： C08G77/60
CPC分类号： C09D123/16 , B32B17/1055 , C08F210/18 , C08F230/08 , C08L23/16 , C08L83/00 , C08L83/04 , C08L2312/08 , C09J123/16 , C08F210/06 , C08F2500/25 , C08F2500/21
摘要： The curable composition of the present invention contains (A1) a silyl-containing ethylene/α-olefin/non-conjugated polyene random copolymer rubber which has a structural unit derived from a norbornene compound as the non-conjugated polyene with at least one specific vinyl group at the terminal and contains a specific hydrolyzable silyl group, and (B) a compound, other than the rubber (A1), having a hydroxyl group and/or a hydrolyzable group, e.g., (B1) a compound having a silanol group and/or a compound which can react with moisture to form a compound having a silanol group in the molecule. This compound improves elongation of the cured product and residual surface tackiness, and, at the same time, is high in curing speed and capable of giving the cured product of high resistance to weather. It is suitable for, e.g., adhesives, tackifiers, paints, sealants, waterproof materials, spray materials, shaping materials and casting rubber materials.

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