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    • 3. 发明申请
    • EASILY FIBRILLABLE FIBER
    • 易弯曲纤维
    • WO1997044511A1
    • 1997-11-27
    • PCT/JP1996001322
    • 1996-05-20
    • KURARAY CO., LTD.OHMORY, AkioYOSHIMOCHI, HayamiSANO, TomoyukiKOBAYASHI, SatoruNARAMURA, SyunpeiSATOH, Masahiro
    • KURARAY CO., LTD.
    • D01F08/02
    • D01F8/10D01F8/02Y10T428/2924Y10T428/2929
    • A fiber of a sea-island phase separation structure in which the sea phase is made of a highly orientable and highly crystalline polyvinyl alcohol polymer, the island phase is made of a water-insoluble cellulosic polymer excellent in alkaline liquid absorbing capacity, heat resistance and difficulty of melting, the size of the island is 0.03 to 10 mu m and the strength is 3 g/d or above and which can easily be separated into fibrils 0.05 to 8 mu m in diameter by wetting the fiber and applying a mechanical stress to the resulting fiber. The above fibril is a hydrophilic and high-strength one which is excellent in the property of capturing fine particles, reinforcing effects, alkaline liquid absorption, and the resistances to heating and melting, does not cause the elution of fiber components in fibrillation, and is freed from the problematic bubbling in beating or the problem of environmental pollution due to a heating solution. The fibril is extremely useful as the separator paper for alkaline batteries, the reinforcing fiber for cement slates, the reinforcing fiber for friction materials, or the like.
    • 海相分离结构的纤维,其中海相由高取向性和高度结晶的聚乙烯醇聚合物制成,岛相由碱性液体吸收能力,耐热性和耐热性优异的水不溶性纤维素聚合物制成, 熔化困难,岛的尺寸为0.03〜10μm,强度为3g / d以上,通过润湿纤维并施加机械应力,容易将其直径分割成直径为0.05〜8μm的纤维 所得纤维。 上述原纤维是捕获微粒,增强效果,碱液吸收和耐热熔融性优异的亲水性,高强度性,不会引起纤维成分在纤维化中的洗脱,并且是 摆脱了有问题的泡泡或由于加热溶液引起的环境污染问题。 原纤维作为碱性电池用隔膜纸,水泥板状增强纤维,摩擦材料用增强纤维等非常有用。
    • 4. 发明申请
    • PROCESS FOR PRODUCING POLYMER TERMINATED WITH OPTIONALLY PROTECTED FUNCTIONAL GROUP
    • 用可选择保护的功能组终止聚合物的方法
    • WO1995025753A1
    • 1995-09-28
    • PCT/JP1995000499
    • 1995-03-20
    • KURARAY CO., LTD.MAEKAWA, KazuhikoSATO, Toshiaki
    • KURARAY CO., LTD.
    • C08F04/00
    • C08F2/38
    • A process for producing a polymer terminated with optionally protected functional group(s), which comprises conducting free-radical polymerization of a radical-polymerizable monomer by using a polymerization initiator comprising at least one member selected from the group (A) consisting of thiocarboxylic acids of general formula (1) and dithiocarboxylic acids of general formula (2) and at least one member selected from the group (B) consisting of polysulfides of general formula (3), polysulfides of the general formula (4): R -(S)m-R , and sulfoxides of general formula (5). In formula (1) R represents a hydrocarbon group which may have a substituent containing a functional group. In formula (2) R represents a hydrocarbon group which may have a substituent containing a functional group. In formula (3) R and R represent each a hydrocarbon group which may have a substituent containing a functional group; and n represents an integer of 2 or above. In formula (4) R and R represent each a hydrocarbon group having a functional group; and m represents an integer of 2 or above. In formula (5) R and R represent each a hydrocarbon group having a functional group. The process enables a polymer having a high content of functional groups introduced into one or both of its terminals to be produced independently of the rate of polymerization and the degree of polymerization of the product.
    • 一种制备用任选保护的官能团封端的聚合物的方法,其包括通过使用包含至少一种选自由以下组成的组的聚合引发剂进行自由基聚合单体的自由基聚合:(A) 通式(1)的二硫代羧酸和通式(2)的二硫代羧酸和选自由通式(3)的多硫化物组成的组(B)中的至少一种,通式(4)的多硫化物:R 5 - (S)mR 6,和通式(5)的亚砜。 式(1)中,R 1表示可具有含有官能团的取代基的烃基。 式(2)中,R 2表示可具有含有官能团的取代基的烃基。 在式(3)中,R 3和R 4各自表示可以具有含有官能团的取代基的烃基; n表示2以上的整数。 在式(4)中,R 5和R 6各自表示具有官能团的烃基; m表示2以上的整数。 在式(5)中,R 7和R 8各自表示具有官能团的烃基。 该方法使得能够独立于聚合速率和产物的聚合度而制备引入其一个或两个末端的高官能团含量的聚合物。
    • 8. 发明申请
    • THERMOPLASTIC POLYURETHANE COMPOSITION
    • 热塑性聚氨酯组合物
    • WO1994025529A1
    • 1994-11-10
    • PCT/JP1994000717
    • 1994-04-28
    • KURARAY CO., LTD.ISHIGURO, MichihiroOSHITA, TatuyaONO, HiroyukiNAKAYAMA, KimioHIRAI, Koji
    • KURARAY CO., LTD.
    • C08L75/04
    • C08G18/664C08G18/24C08G18/4238D01F6/70
    • A thermoplastic polyurethane composition comprising a thermoplastic polyurethane and a tin compound in an amount of 0.3-15 ppm (in terms of tin atom) based on the polyurethane. The composition has a retention of the long-chain hard segment of the polyurethane of 85 % or above when melt treated at 220 DEG C for 60 minutes. Further it has a retention of the logarithmic viscosity of 85 % or above when melt treated at 220 DEG C for 6 minutes, melt extruded and left to stand at 20 DEG C and 60 % R.H. for 24 hours. The composition is so excellent in moldability that it can provide moldings excellent in various properties such as tenacity and elongation, thermal resistance, compression set and hydrolysis resistance, thus being useful as the material of various moldings. Further it is so excellent in spinnability that it can provide fibers excellent in various properties such as thermal resistance, hydrolysis resistance and unwindability, thus being useful also as the material of elastic fibers.
    • 一种热塑性聚氨酯组合物,其包含基于聚氨酯的0.3-15ppm(以锡原子计)的热塑性聚氨酯和锡化合物。 当在220℃下熔融处理60分钟时,该组合物具有85%或更高的聚氨酯的长链硬链段的保留。 此外,当在220℃下熔融处理6分钟时,其对数粘度保持在85%以上,熔融挤出并在20℃和60%R.H.静置24小时。 组合物的成型性优异,能够提供强度和伸长性,耐热性,压缩变形性和耐水解性等各种性能优异的模制品,因此可用作各种模制品的材料。 此外,其可纺性如此优异,可以提供各种性能如耐热性,耐水解性和展开性优异的纤维,因此也可用作弹性纤维的材料。
    • 9. 发明申请
    • POLYURETHANE AND LEATHERLIKE SHEET MADE THEREFROM
    • POLYURETHANE AND LEATHERLIKE SHEET MUDE THEREFROM
    • WO1994010220A1
    • 1994-05-11
    • PCT/JP1993001528
    • 1993-10-22
    • KURARAY CO., LTD.AKASAWA, Toshiyuki
    • KURARAY CO., LTD.
    • C08G18/10
    • D06N3/14C08G18/12C08G18/6622C08G18/3203C08G18/7671
    • A polyurethane suitable for producing leatherlike sheets, which is prepared by the reaction among a diol (A) having a tertiary amino group, a polymer diol (B) having the number-average molecular weight of 500 to 3,000 and selected from the group consisting of polyesters, polycarbonates, polylactones and polyethers, and an organic diisocyanate (C1) each in such an amount that the equivalent ratio of the NCO groups to the OH groups will range from 0.5 to 0.99 to thereby prepare an intermediate diol (D) substantially terminated by OH groups, followed by the reaction among the diol (D), a low-molecular-weight diol (E) and diphenylmethane 4,4'-diisocyanate (C2); and a leatherlike sheet composed of the polyurethane and a fibrous base material, which is soft to the touch, excellent in durability, and dyeable with acid dyes.
    • 适用于通过具有叔氨基的二醇(A)与数均分子量为500〜3000的聚合物二醇(B)的反应而制备的皮革状片材的聚氨酯,其选自 聚酯,聚碳酸酯,聚内酯和聚醚以及有机二异氰酸酯(C1),其量使得NCO基与OH基的当量比范围为0.5至0.99,从而制备基本上以 OH,二醇(D),低分子量二醇(E)和二苯基甲烷4,4'-二异氰酸酯(C2)之间的反应。 和由聚氨酯和纤维基材组成的皮革片,其触感柔软,耐久性优异,可用酸性染料染色。