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    • 5. 发明授权
    • Cleaning device, cleaning system, treating device and cleaning method
    • 清洁装置,清洁系统,处理装置和清洁方法
    • US06478035B1
    • 2002-11-12
    • US09634005
    • 2000-08-07
    • Takayuki NiuyaMichihiro OnoHideto GotohHiroyuki Mori
    • Takayuki NiuyaMichihiro OnoHideto GotohHiroyuki Mori
    • B08B304
    • H01L21/67057B08B3/12H01L21/31133H01L21/76814Y10S134/902
    • There is provided a cleaning device capable of preventing a metal wiring layer or the like of an object to be treated, from being oxidized. The cleaning device comprises: a cleaning container 72 having a treating space S having a slightly larger volume than that of an object W to be treated; a fluid storage tank 30 for storing a cleaning fluid 32 for treating the object; supply lines 46A through 46D for supplying the cleaning fluid from the fluid storage tank to the cleaning container; and reflux lines 47A through 47D for returning the cleaning fluid from the cleaning container to the fluid storage tank, wherein the cleaning container, the fluid storage tank, the supply lines and the reflux lines are associated with each other for forming closed cleaning fluid circulating lines 51A through 51D. Thus, it is possible to prevent the metal wiring layer or the like of the object from being oxidized.
    • 提供了能够防止被处理物的金属布线层等被氧化的​​清洁装置。 清洁装置包括:具有处理空间S的清洁容器72,处理空间S具有比要处理的物体W的体积稍大的体积; 用于存储用于处理物体的清洁流体32的流体储存罐30; 供应管线46A至46D,用于将清洁流体从流体储存罐供应到清洁容器; 以及回流管线47A至47D,用于将清洁流体从清洁容器返回到流体储存罐,其中清洁容器,流体储存罐,供应管线和回流管线彼此相关联,用于形成封闭的清洁流体循环管线 51A至51D。 因此,可以防止物体的金属布线层等被氧化。
    • 6. 发明授权
    • Cleaning agent for a semiconductor device and a method of manufacturing a semiconductor device
    • 半导体装置用清洗剂及半导体装置的制造方法
    • US06462005B1
    • 2002-10-08
    • US08369215
    • 1995-01-05
    • Hideto GotohTetsuo AoyamaRieko NakanoHideki Fukuda
    • Hideto GotohTetsuo AoyamaRieko NakanoHideki Fukuda
    • C11D162
    • H01L21/02071G03F7/425H01L21/02052
    • A cleaning agent for use in the manufacture of a semiconductor device comprising an aqueous solution containing a quarternary ammonium salt and a fluoro compound, or an aqueous solution containing a quarternary ammonium salt and a fluoro compound, as well as an organic solvent selected from the group consisting of amides, lactones, nitriles, alcohols and esters. In the semiconductor device manufacturing process, after forming a mask with a photoresist, a wiring structure is formed by dry etching of a conductive layer, wherein a protecting deposition film has been formed on side walls of the conductive layer. Use of the cleaning agent enables the protecting deposition film to be removed in a highly reliable manner with the surface of the conductive layer being decontaminated and cleaned such that no corrosion of the conductive layer occurs.
    • 一种用于制造半导体器件的清洁剂,其包含含有季铵盐和氟化合物的水溶液,或含有季铵盐和氟化合物的水溶液,以及选自下组的有机溶剂 由酰胺,内酯,腈,醇和酯组成。 在半导体器件制造方法中,在用光致抗蚀剂形成掩模之后,通过干蚀刻导电层形成布线结构,其中在导电层的侧壁上形成保护沉积膜。 使用清洁剂能够以高度可靠的方式去除保护性沉积膜,同时导电层的表面被净化和清洁,使得不会发生导电层的腐蚀。
    • 8. 发明授权
    • Semiconductor device fabrication method
    • 半导体器件制造方法
    • US5650041A
    • 1997-07-22
    • US485541
    • 1995-06-07
    • Hideto GotohMasaru Utsugi
    • Hideto GotohMasaru Utsugi
    • H01L21/302H01L21/027H01L21/3065H01L21/308H01L21/311H01L21/321H01L21/3213H01L21/768
    • H01L21/02063H01L21/31116H01L21/31144H01L21/321H01L21/76802H01L21/76814Y10S438/906
    • An MLR (multilayer resist) 3 is formed on a BPSG layer 2 on top of a silicon wafer 1, then dry etched using an etching gas 8 to form a contact hole 2a on the BPSG layer 2. Next, the polymer residues 9a and 9b adhering to the side walls of the contact hole 2a and the surface of the BPSG layer 2 are subjected to a cleaning treatment using a cleaning treating liquid that contains 0.04-0.12 wt % hydrogen fluoride, thereby removing the polymer residues 9a and 9b.During etching the presence of the polymer residue layer 9 prevents etching in the horizontal direction, thereby allowing the formation of a highly precise contact hole 2a. In addition, because the treating liquid has the composition described above, the aforementioned polymer residues 9a and 9b are removed, thereby avoiding any degradation of the electrical characteristics. In addition, corrosion of the side walls of the contact hole due to the cleaning treating liquid is prevented, thereby maintaining the high level of contact hole precision. As a result good electrical characteristics are ensured even if the structure has an ultrafine-pitch pattern.
    • 在硅晶片1的顶部的BPSG层2上形成MLR(多层抗蚀剂)3,然后使用蚀刻气体8进行干蚀刻,在BPSG层2上形成接触孔2a。接着,将聚合物残渣9a,9b 使用含有0.04-0.12重量%氟化氢的清洗处理液对粘接在接触孔2a的侧壁和BPSG层2的表面上的清洁处理进行清洁处理,从而除去聚合物残渣9a和9b。 在蚀刻期间,聚合物残留层9的存在防止在水平方向上的蚀刻,从而形成高精度的接触孔2a。 此外,由于处理液具有上述组成,因此除去上述聚合物残渣9a和9b,从而避免电特性的任何劣化。 此外,防止由于清洁处理液引起的接触孔的侧壁的腐蚀,从而保持接触孔的高水平精度。 因此,即使结构具有超细间距图案,也能确保良好的电气特性。