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1. 发明授权

US5756845A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine 失效
标题翻译： 3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US5756845A
公开(公告)日：1998-05-26
申请号：US608485
申请日：1996-02-28
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Wolfgang Harder , Hermann Luyken , Axel Paul , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Wolfgang Harder , Hermann Luyken , Axel Paul , Karl-Heinz Ross , Peter Wahl
IPC分类号： B01J23/46 , B01J23/75 , B01J23/755 , C07B61/00 , C07C209/48 , C07C211/36
CPC分类号： C07C209/48 , C07C2101/14
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethylcyclohexanone which requires three spatially separated reaction spaces, in order to carry out the following three steps in sequence: a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20.degree. to 150.degree. C. and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia and preferably liquid ammonia on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 50.degree. to 100.degree. C. and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen and also ammonia in a third reaction space on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 110.degree. to 160.degree. C. and at from 150 to 300 bar.These three steps in sequence provide a substantially complete reaction of the original 3-cyano-3,3,5-trimethylcyclohexanone reactant with a yield of 96% of the desired diamino product in which the cis-content of the diamine is 70%.
摘要翻译：从3-氰基-3,5,5-三甲基环己酮制备3-氨基甲基-3,5,5-三甲基环己胺的方法，其需要三个空间分离的反应空间，以便按顺序进行以下三个步骤：a ）在20至150℃和50至300巴的第一反应空间中使3-氰基-3,5,5-三甲基环己酮与过量的氨在酸性金属氧化物催化剂上反应，b）将所得反应物氢化在氢化催化剂存在下，在过量氨和优选液氨存在下在第二反应空间中使用氢的产物，任选使用碱性组分或在中性或碱性载体上在50至100℃和50至300巴条件下，以及 c）在氢化催化剂的第三反应空间中，在氢气和氨的存在下氢化所得反应产物，任选使用碱性组分或在中性或碱性载体上在110至160℃和150至300b ar。这三个步骤依次提供原始3-氰基-3,3,5-三甲基环己酮反应物的基本上完全的反应物，其中二胺的顺式含量为70％的所需二氨基产物的产率为96％。

2. 发明授权

US6022999A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 有权
标题翻译：具有顺式/反式异构体比例为70:30以上的3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US6022999A
公开(公告)日：2000-02-08
申请号：US207623
申请日：1998-12-09
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
IPC分类号： C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36 , C07C209/22
CPC分类号： C07C209/26 , C07C209/48 , C07C209/52
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 bya) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degree. C. and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclo-hexanone imine followed byb) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree. C. and under a pressure of from 5 to 30 MPa,wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to give an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.
摘要翻译：一种制备顺式/反式异构体比例至少为70:30的3-氨基甲基-3,5,5-三甲基环己胺的制备方法，通过以下步骤：a）将3-氰基-3,5,5-三甲基环己酮与氨在在20至150℃的温度和1.5至30MPa的压力下存在仿制催化剂以形成3-氰基-3,5,5-三甲基环己酮亚胺，随后b）氢化3-氰基 -3,5,5-三甲基环己酮亚胺在含有铜和/或Ⅷ族金属的催化剂的存在下在80至160℃的温度和5至30MPa的压力下进行，其中 3-氰基-3,5,5-三甲基环己酮亚胺的催化氢化在酸的存在下进行，所用酸的用量使得酸值为0.1-2，基于3-氰基-3 ，使用5,5-三甲基环己酮。

3. 发明授权

US06291715B1 Process for the preparation of alkanolamines having improved color quality 有权
标题翻译：具有改善颜色质量的烷醇胺的制备方法
公开(公告)号：US06291715B1
公开(公告)日：2001-09-18
申请号：US09643724
申请日：2000-08-23
申请人： Günther Ruider , Karl-Heinz Ross , Boris Breitscheidel , Heike Maier , Gerhard Schulz , Sylvia Huber
发明人： Günther Ruider , Karl-Heinz Ross , Boris Breitscheidel , Heike Maier , Gerhard Schulz , Sylvia Huber
IPC分类号： C07C20984
CPC分类号： C07C213/10 , C07C215/08 , C07C215/10 , C07C215/14
摘要： Preparation of alkanolamines having improved color quality by treating the alkanolamine with hydrogen in the presence of a hydrogenation catalyst at elevated temperature, by using, as hydrogenation catalyst, a heterogeneous catalyst comprising Re, Ru, Rh, Pd, Os, Ir, Pt and/or Ag and a support material chosen from the group consisting of activated carbon, alpha-aluminum oxide, zirconium dioxide and titanium dioxide, where the catalyst, in the case of activated carbon as support material, has a cutting hardness of at least 10 N, a side crushing strength of at least 30 N or a compressive strength of at least 25 N.
摘要翻译：通过在氢化催化剂存在下，在升高的温度下，用氢处理链烷醇胺，通过使用氢化催化剂，制备包含Re，Ru，Rh，Pd，Os，Ir，Pt和/ 或Ag和选自活性炭，α-氧化铝，二氧化锆和二氧化钛的载体材料，其中在活性炭作为载体材料的情况下，催化剂具有至少10N的切割硬度，至少30N的侧面抗压强度或至少25N的抗压强度。

4. 发明授权

US5663444A Preparation of a pure dialkylaminoethanol stable against discoloration 失效
标题翻译：制备纯二烷基氨基乙醇稳定防变色
公开(公告)号：US5663444A
公开(公告)日：1997-09-02
申请号：US497072
申请日：1995-06-30
申请人： Johann-Peter Melder , Gunther Ruider , Tom Witzel , Karl-Heinz Ross , Gunter Boettger
发明人： Johann-Peter Melder , Gunther Ruider , Tom Witzel , Karl-Heinz Ross , Gunter Boettger
IPC分类号： C07C213/04 , C07C213/10 , C07C215/08 , C07C209/02
CPC分类号： C07C213/04
摘要： A process for the preparation of a color-stable dialkylaminoethanol of the formula ##STR1## in which R.sup.1 and R.sup.2 independently are C.sub.1 -C.sub.20 -alkyl, by reacting ethylene oxide with a dialkylamine of the formula HNR.sup.1 R.sup.2, in which R.sup.1 and R.sup.2 have the same meaning, in the presence of from 2.5 to 50% by weight of water, based on the reaction mixture, at a temperature of from 95.degree. to 170.degree. C., and separating off the water and high-boiling constituents by distillation under a reduced pressure and at a temperature of from 40.degree. to 90.degree. C. at the column bottom.
摘要翻译：制备式“IMAGE”的颜色稳定的二烷基氨基乙醇的方法，其中R 1和R 2各自独立地为C 1 -C 20 - 烷基，其中环氧乙烷与式HNR 1 R 2的二烷基胺反应，其中R 1和R 2具有相同意思是，在95至170℃的温度下，基于反应混合物，在2.5至50重量％的水存在下，通过在减压下蒸馏除去水和高沸点组分压力，并在塔底处于40℃至90℃的温度。

5. 发明申请

US20080103336A1 Method for producing N, N-Dimethylacetamide (Dmac) 审中-公开
标题翻译：制备N，N-二甲基乙酰胺（Dmac）的方法
公开(公告)号：US20080103336A1
公开(公告)日：2008-05-01
申请号：US11720791
申请日：2005-12-03
申请人： Horst Grafmans , Steffen Maas , Alexander Weck , Heinz Rutter , Michael Schulz , Karl-Heinz Ross
发明人： Horst Grafmans , Steffen Maas , Alexander Weck , Heinz Rutter , Michael Schulz , Karl-Heinz Ross
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , C07C233/05
摘要： A process for preparing N,N-dimethylacetamide (DMAC) by continuously reacting methyl acetate (MeOAc) with dimethylamine (DMA) in the presence of a basic catalyst, wherein MeOAc is used in the form of a methanolic solution and in the range from 0.0002 to 0.09 mol of catalyst per mole of MeOAc, and performing the reaction at a temperature in the range from 90 to 140° C. and at an absolute pressure in the range from 10 to 30 bar.
摘要翻译：在碱性催化剂存在下，通过使乙酸甲酯（MeOAc）与二甲胺（DMA）连续反应制备N，N-二甲基乙酰胺（DMAC）的方法，其中MeOAc以甲醇溶液的形式使用，范围为0.0002 至0.09摩尔催化剂/摩尔MeOAc，并在90至140℃的温度和10至30巴的绝对压力下进行反应。

6. 发明申请

US20050010057A1 Method for the continuous production of n-methyl-2-pyrrolidone (nmp) 有权
标题翻译：连续生产正甲基-2-吡咯烷酮（nmp）的方法
公开(公告)号：US20050010057A1
公开(公告)日：2005-01-13
申请号：US10495358
申请日：2002-11-15
申请人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkucher , Karl-Heinz Ross
发明人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkucher , Karl-Heinz Ross
IPC分类号： C07D207/26 , C07D207/267 , C07D207/12
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-methyl-2-pyrrolidone (NMP) by reacting gamma-butyrolactone (GBL) with monomethylamine (MMA) in the liquid phase, wherein GBL and MMA are used in a molar ratio of from 1:1.08 to 1:2 and the reaction is carried out at from 320 to 380° C. and an absolute pressure of from 70 to 120 bar.
摘要翻译：通过使γ-丁内酯（GBL）与一甲胺（MMA）在液相中连续制备N-甲基-2-吡咯烷酮（NMP）的方法，其中GBL和MMA的摩尔比为1:1.08至 1：2，反应在320〜380℃，绝对压力为70〜120巴下进行。

7. 发明授权

US06348601B2 Preparation of N-methyl-2-pyrrolidone (NMP) 失效
标题翻译：制备N-甲基-2-吡咯烷酮（NMP）
公开(公告)号：US06348601B2
公开(公告)日：2002-02-19
申请号：US09774628
申请日：2001-02-01
申请人： Frank Ohlbach , Johann-Peter Melder , Karl-Heinz Ross , Martin Rudloff , Jörg Liebe
发明人： Frank Ohlbach , Johann-Peter Melder , Karl-Heinz Ross , Martin Rudloff , Jörg Liebe
IPC分类号： C07D207267
CPC分类号： C07D207/267
摘要： N-Methyl-2-pyrrolidone (NMP) is prepared by preparing a mixture comprising monomethylamine, dimethylamine and trimethylamine and ammonia in a first process step by reacting ammonia with methanol at elevated temperature in the presence of a catalyst, separating 10 off the ammonia, reacting the mixture comprising the methylamines with gamma-butyrolactone (&ggr;-BL), in a molar ratio of monomethylamine to &ggr;-BL of at least 1 in a second process step at elevated temperature and superatmospheric pressure, separating NMP and unreacted methylamines from the reaction product and returning unreacted methylamines to the first process step for reaction with methanol and ammonia.
摘要翻译：通过在第一工艺步骤中通过在升高的温度下在催化剂存在下使氨与甲醇反应制备包含单甲胺，二甲胺和三甲胺和氨的混合物来制备N-甲基-2-吡咯烷酮（NMP），从氨分离10，在高温和超大气压下，在第二工艺步骤中使包含甲胺的混合物与γ-丁内酯（γ-BL）以一甲基胺与γ-BL的摩尔比至少为1的反应物反应，从反应中分离NMP和未反应的甲胺产物并将未反应的甲胺返回到用于与甲醇和氨反应的第一工艺步骤。

8. 发明授权

US4994603A Preparation of methyl formate 失效
标题翻译：甲酸甲酯的制备
公开(公告)号：US4994603A
公开(公告)日：1991-02-19
申请号：US299544
申请日：1981-09-04
申请人： Franz-Josef Mueller , Wolfgang Steiner , Karl-Heinz Ross , Otto Kratzer
发明人： Franz-Josef Mueller , Wolfgang Steiner , Karl-Heinz Ross , Otto Kratzer
IPC分类号： C07C69/06 , B01J31/00 , B01J31/16 , C07B61/00 , C07C67/36 , C07C67/37
CPC分类号： B01J31/2213 , B01J31/0212 , C07C67/36 , B01J2531/11 , B01J2531/20
摘要： A process for the preparation of methyl formate by reacting methanol and carbon monoxide in the presence of an alkali metal alcoholate or alkaline earth metal alcoholate at from 30.degree. to 150.degree. C. and from 50 to 300 bar, wherein a nonionic complexing agent is used to bind the alkali metal cations or alkaline earth metal cations.
摘要翻译：一种在碱金属醇盐或碱土金属醇盐存在下，在30至150℃和50至300巴条件下使甲醇和一氧化碳反应制备甲酸甲酯的方法，其中使用非离子络合剂以结合碱金属阳离子或碱土金属阳离子。

9. 发明授权

US07309403B2 Method for avoiding corrosion 有权
标题翻译：避免腐蚀的方法
公开(公告)号：US07309403B2
公开(公告)日：2007-12-18
申请号：US10572783
申请日：2004-09-24
申请人： Werner Reutemann , Theodor Weber , Karl-Heinz Ross , Manfred Julius
发明人： Werner Reutemann , Theodor Weber , Karl-Heinz Ross , Manfred Julius
IPC分类号： B01D3/38 , B01D3/40 , C07C209/86 , C07C209/90
CPC分类号： C07C211/04 , C07C209/86 , Y10S203/20 , Y10S203/24
摘要： The invention relates to a method of avoiding corrosion in the separation of methylamine from a product stream (10) which is obtained in the preparation of methylamines by gas-phase reaction of methanol and ammonia and includes monomethylamine, dimethylamine, trimethylamine, ammonia and methanol as components, where ammonia is separated off by pure distillation in a first column (1), the remaining components of the product stream obtained as bottoms (12) are fed to a second column (2). Trimethylamine (14) is separated off in the second column (2) by extractive distillation with introduction of water. The further of the product stream obtained as bottoms (15) from the second column (2) are fed to a third column (3), in which monomethylamine and dimethylamine are separated off at the top. The monomethylamine and dimethylamine are separated by distillation in a fourth column (4). To avoid corrosion alkali metal hydroxide is added to the second or third column (3).
摘要翻译：本发明涉及一种避免在甲醇与甲醇与氨的气相反应制备甲胺中得到的产物流（10）中分离甲胺的腐蚀方法，包括一甲胺，二甲胺，三甲胺，氨和甲醇组分，其中在第一塔（1）中通过纯蒸馏分离氨，将作为塔底物（12）获得的产物流的剩余组分进料至第二塔（2）。通过萃取蒸馏引入三水胺（14）在第二塔（2）中分离。从第二塔（2）获得的作为塔底物（15）获得的产物流的其它组分进料到第三塔（3），其中一甲胺和二甲胺在顶部分离。在第四列（4）中通过蒸馏分离一甲胺和二甲胺。为了避免腐蚀，将碱金属氢氧化物加入到第二或第三塔（3）中。

10. 发明申请

US20070232833A1 Method for the Continuous Production of an Amine 失效
标题翻译：连续生产胺的方法
公开(公告)号：US20070232833A1
公开(公告)日：2007-10-04
申请号：US11596292
申请日：2005-05-04
申请人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Ross , Heinz Rutter , Shelue Liang , Stefan Rittinger
发明人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Ross , Heinz Rutter , Shelue Liang , Stefan Rittinger
IPC分类号： C07C209/60
CPC分类号： C07C209/26 , C07C209/16 , C07C213/02 , C07D295/027 , C07D295/03 , C07D295/088 , C08G59/50 , Y02P20/582 , C07C211/06 , C07C211/08 , C07C211/35 , C07C217/08
摘要： Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
摘要翻译：通过伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在60至300℃的温度下反应来连续制备胺的方法在含铜催化剂存在下，其中催化剂在用氢还原之前的催化活性组合物包含20至85重量％的氧化铝（Al 2 O 3） 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2），1至70重量％的以CuO计的含氧化合物的铜，0至50重量％的以氧化镁计的含氧化合物，以氧化铬计算的含铬化合物，以ZnO计算的含氧化合物锌，以BaO计的钡的含氧化合物和/ 或以CaO计的含氧化合物的钙，小于30重量％的按NiO计的含氧化合物的镍，以CuO计算的含氧化合物计算，并进行反应在管式反应器中在气相中等温。

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