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1. 发明授权

US09044409B2 Use of chromen-4-one derivatives 有权
标题翻译：使用色烯-4-酮衍生物
公开(公告)号：US09044409B2
公开(公告)日：2015-06-02
申请号：US11869192
申请日：2007-10-09
申请人： Christophe Carola , Herwig Buchholz , Sylvia Huber , Ralf Rosskopf
发明人： Christophe Carola , Herwig Buchholz , Sylvia Huber , Ralf Rosskopf
IPC分类号： A61K31/05 , A61K31/122 , A61K31/35 , A61K31/352 , A61K8/49 , A23L1/30 , A61K45/06 , A61Q5/00 , A61Q17/04 , A61Q19/00 , A61Q19/08 , A61Q11/00 , A61Q19/02
CPC分类号： A61K8/498 , A23L33/10 , A61K31/05 , A61K31/122 , A61K31/35 , A61K31/352 , A61K45/06 , A61K2800/782 , A61Q5/00 , A61Q11/00 , A61Q17/04 , A61Q19/00 , A61Q19/007 , A61Q19/02 , A61Q19/04 , A61Q19/08 , A61K2300/00
摘要： The invention relates to the use of chromen-4-one derivatives of the formula I where R1 and R2 may be identical or different and are selected from H, —C(═O)—R7, —C(═O)—OR7, alkyl groups, alkenyl groups, hydroxyalkyl groups and/or cycloalkyl groups and/or cycloalkenyl groups, R3 is H or alkyl groups, R4 is H or OR8, R5 and R6 are selected from —H, —OH, alkyl groups, alkenyl groups and hydroxyalkyl groups, and R7 is H, alkyl groups, a polyhydroxyl compound, such as, preferably, an ascorbic acid radical or glycosidic radicals, and R8 is H or alkyl groups, where at least two of the substituents R1, R2 and R4-R6 are different from H or at least one substituent from R1 and R2 is —C(═O)—R7 or —C(═O)—OR7, for the care, preservation or improvement of the general state of the skin or hair.
摘要翻译：本发明涉及式I的色烯-4-酮衍生物的用途，其中R 1和R 2可以相同或不同，并且选自H，-C（= O）-R 7，-C（= O）-OR 7，烷基，烯基，羟基烷基和/或环烷基和/或环烯基，R3是H或烷基，R4是H或OR8，R5和R6选自-H，-OH，烷基，烯基和羟基烷基，R7是H，烷基，多羟基化合物，例如优选抗坏血酸基团或糖苷基，R8是H或烷基，其中至少两个取代基R 1，R 2和R 4 -R 6 不同于H或R1的至少一个取代基，R2是-C（= O）-R7或-C（= O）-OR7），用于护理，保存或改善皮肤或头发的一般状态。

2. 发明申请

US20060178539A1 Catalyst and method for the hydration of carbonyl compounds 有权
公开(公告)号：US20060178539A1
公开(公告)日：2006-08-10
申请号：US10549140
申请日：2004-03-20
申请人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
发明人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
IPC分类号： C07C31/18
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.

3. 发明授权

US07084312B1 Catalyst and method for hydrogenating carbonyl compounds 有权
标题翻译：氢化羰基化合物的催化剂和方法
公开(公告)号：US07084312B1
公开(公告)日：2006-08-01
申请号：US10070275
申请日：2000-08-22
申请人： Sylvia Huber , Michael Jolyon Sprague , Boris Breitscheidel , Joachim Wulff-Döring , Michael Hesse , Rolf Pinkos , Shelue Liang , Otto Kumberger , Marc Walter
发明人： Sylvia Huber , Michael Jolyon Sprague , Boris Breitscheidel , Joachim Wulff-Döring , Michael Hesse , Rolf Pinkos , Shelue Liang , Otto Kumberger , Marc Walter
IPC分类号： C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/147
CPC分类号： B01J23/80 , C07C29/149 , C07C31/20
摘要： A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which (i) an oxidic material comprising copper oxide, zinc oxide and aluminum oxide is made available, (ii) pulverulent metallic copper or pulverulent cement or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to form a shaped body.
摘要翻译：氢化含有至少一个羰基的有机化合物的方法包括使氢存在下的有机化合物与成形体接触，成形体可以通过以下工艺制备，其中（i）包含氧化铜的氧化物，提供氧化锌和氧化铝，（ii）将粉末状金属铜或粉状水泥或其混合物加入到氧化物中，和（iii）由（ii）得到的混合物成形为成形体。

4. 发明申请

US20050176972A1 Catalytic hydrogenation over rhenium-containing catalysts supported on activated carbon 失效
标题翻译：通过负载在活性炭上的含铼催化剂进行催化氢化
公开(公告)号：US20050176972A1
公开(公告)日：2005-08-11
申请号：US11104408
申请日：2005-04-13
申请人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Schunk , Joachim Wulff-Doring , Frank Stein , Thomas Nobel , Sylvia Huber
发明人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Schunk , Joachim Wulff-Doring , Frank Stein , Thomas Nobel , Sylvia Huber
IPC分类号： B01J21/18 , B01J23/656 , B01J23/89 , C07C29/17 , C07D307/26 , C07C31/18
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated. It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭已经被非氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

5. 发明申请

US20050043398A1 Use of chromen-4-one derivatives 审中-公开
标题翻译：使用色烯-4-酮衍生物
公开(公告)号：US20050043398A1
公开(公告)日：2005-02-24
申请号：US10920202
申请日：2004-08-18
申请人： Christophe Carola , Herwig Buchholz , Sylvia Huber , Ralf Rosskopf
发明人： Christophe Carola , Herwig Buchholz , Sylvia Huber , Ralf Rosskopf
IPC分类号： C07D311/22 , A23L1/30 , A61K8/00 , A61K8/33 , A61K8/35 , A61K8/37 , A61K8/42 , A61K8/49 , A61K31/197 , A61K31/35 , A61K31/352 , A61K31/353 , A61K31/375 , A61K31/4188 , A61K31/4406 , A61K45/06 , A61P1/06 , A61P17/00 , A61P17/06 , A61P17/10 , A61P17/12 , A61P17/16 , A61P29/00 , A61P35/00 , A61P37/08 , A61P43/00 , A61Q5/00 , A61Q11/00 , A61Q17/00 , A61Q17/04 , A61Q19/00 , A61Q19/02 , A61Q19/08 , C07D407/12
CPC分类号： A61K8/498 , A23L33/10 , A61K31/05 , A61K31/122 , A61K31/35 , A61K31/352 , A61K45/06 , A61K2800/782 , A61Q5/00 , A61Q11/00 , A61Q17/04 , A61Q19/00 , A61Q19/007 , A61Q19/02 , A61Q19/04 , A61Q19/08 , A61K2300/00
摘要： The invention relates to the use of chrome-4-one derivatives of the formula I where R1 and R2 may be identical or different and are selected from H, —C(═O)—R7, —C(═O)—OR7, alkyl groups, alkenyl groups, hydroxyalkyl groups and/or cycloalkyl groups and/or cycloalkenyl groups, R3 is H or alkyl groups, R4 is H or OR8, R5 and R6 are selected from —H, —OH, alkyl groups, alkenyl groups and hydroxyalkyl groups, and R7 is H, alkyl groups, a polyhydroxyl compound, such as, preferably, an ascorbic acid radical or glycosidic radicals, and R8 is H or alkyl groups, where at least two of the substituents R1, R2 and R4—R6 are different from H or at least one substituent from R1 and R2 is —C(═O)—R7 or —C(═O)—OR7, for the care, preservation or improvement of the general state of the skin or hair.
摘要翻译：本发明涉及式I的铬-4-酮衍生物的用途，其中R 1和R 2可以相同或不同，并且选自H，-C（= O）-R 7， -C（= O）-OR 7，烷基，烯基，羟基烷基和/或环烷基和/或环烯基，R 3是H或烷基，R 4是H或OR， R 5，R 5和R 6选自-H，-OH，烷基，烯基和羟基烷基，R 7是H，烷基，多羟基化合物，抗坏血酸基团或糖苷基，R 8是H或烷基，其中至少两个取代基R 1，R 2和R 4 -R 6不同于H或 R 1和R 2中的至少一个取代基是-C（= O）-R 7或-C（= O）-OR 7，用于保护，保存或改善一般状态的皮肤或头发。

6. 发明授权

US06828464B2 Preparation of cyclopentenones 失效
标题翻译：环戊烯酮的制备
公开(公告)号：US06828464B2
公开(公告)日：2004-12-07
申请号：US10718795
申请日：2003-11-24
申请人： Shelue Liang , Rolf-Hartmuth Fischer , Sylvia Huber-Dirr , Andrea Haunert
发明人： Shelue Liang , Rolf-Hartmuth Fischer , Sylvia Huber-Dirr , Andrea Haunert
IPC分类号： C07C4554
CPC分类号： B01J23/04 , C07C45/48 , Y02P20/582 , C07C49/597
摘要： The present invention provides a process for preparing 2-cyclopentenones of the general formula: where R1 to R4 are each hydrogen atoms or are alkyl or alkenyl radicals having from 1 to 12 carbon atoms, cycloalkyl or cycloalkenyl radicals having from 5 to 7 carbon atoms, aralkylene or aryl radicals, by converting hexenedioic acids and/or their esters of the general formulae where R1 to R4 are each as defined above and R5 and R6 are each hydrogen atoms or are alkyl radicals having from 1 to 12 carbon atoms, cycloalkyl radicals having 5 or 6 carbon atoms, aralkyl or aryl radicals, at temperatures of from 150 to 450° C., over solid, oxidic catalysts, wherein the catalysts on an oxidic support material comprise from 0.01 to 5% by weight of at least one alkali metal oxide.
摘要翻译：本发明提供一种制备以下通式的2-环戊烯酮的方法：其中R 1至R 4各自为氢原子或具有1至12个碳原子的烷基或烯基，环烷基或环烯基具有 5-7个碳原子的亚芳基或芳基，通过将通式R 1至R 4的通式所示的己烯二酸和/或它们的酯各自如上所定义，R 5和R 6各自为氢原子或具有1至12个碳原子的烷基，具有5或6个碳原子的环烷基，芳烷基或芳基，在150-450℃的温度下，在固体，氧化催化剂上，其中催化剂在氧化载体材料包含0.01至5重量％的至少一种碱金属氧化物。

7. 发明授权

US06291715B1 Process for the preparation of alkanolamines having improved color quality 有权
标题翻译：具有改善颜色质量的烷醇胺的制备方法
公开(公告)号：US06291715B1
公开(公告)日：2001-09-18
申请号：US09643724
申请日：2000-08-23
申请人： Günther Ruider , Karl-Heinz Ross , Boris Breitscheidel , Heike Maier , Gerhard Schulz , Sylvia Huber
发明人： Günther Ruider , Karl-Heinz Ross , Boris Breitscheidel , Heike Maier , Gerhard Schulz , Sylvia Huber
IPC分类号： C07C20984
CPC分类号： C07C213/10 , C07C215/08 , C07C215/10 , C07C215/14
摘要： Preparation of alkanolamines having improved color quality by treating the alkanolamine with hydrogen in the presence of a hydrogenation catalyst at elevated temperature, by using, as hydrogenation catalyst, a heterogeneous catalyst comprising Re, Ru, Rh, Pd, Os, Ir, Pt and/or Ag and a support material chosen from the group consisting of activated carbon, alpha-aluminum oxide, zirconium dioxide and titanium dioxide, where the catalyst, in the case of activated carbon as support material, has a cutting hardness of at least 10 N, a side crushing strength of at least 30 N or a compressive strength of at least 25 N.
摘要翻译：通过在氢化催化剂存在下，在升高的温度下，用氢处理链烷醇胺，通过使用氢化催化剂，制备包含Re，Ru，Rh，Pd，Os，Ir，Pt和/ 或Ag和选自活性炭，α-氧化铝，二氧化锆和二氧化钛的载体材料，其中在活性炭作为载体材料的情况下，催化剂具有至少10N的切割硬度，至少30N的侧面抗压强度或至少25N的抗压强度。

8. 发明授权

US07867993B2 Preparation containing oxidized flavonoid derivatives 失效
标题翻译：含氧化黄酮衍生物的制剂
公开(公告)号：US07867993B2
公开(公告)日：2011-01-11
申请号：US11719712
申请日：2005-11-02
申请人： Christophe Carola , Sylvia Huber , Herwig Buchholz
发明人： Christophe Carola , Sylvia Huber , Herwig Buchholz
IPC分类号： A01N43/16 , A61K31/35
CPC分类号： A61K8/498 , A61K2800/522 , A61Q19/00 , A61Q19/08
摘要： The invention relates to novel compositions, in particular cosmetic and/or pharmaceutical compositions or food supplements, comprising at least one oxidized flavonoid derivative of the formula I, to novel oxidized flavonoid derivatives, and to novel uses of the oxidized flavonoid derivatives.
摘要翻译：本发明涉及新颖的组合物，特别是包含至少一种式I的氧化类黄酮衍生物，新氧化类黄酮衍生物的化妆品和/或药物组合物或食品补充剂，以及氧化类黄酮衍生物的新用途。

9. 发明授权

US07663003B2 Catalyst and method for the hydration of carbonyl compounds 有权
标题翻译：催化剂和羰基化合物水合方法
公开(公告)号：US07663003B2
公开(公告)日：2010-02-16
申请号：US11937537
申请日：2007-11-09
申请人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
发明人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
IPC分类号： B01J23/70 , B01J23/00 , C07C27/04 , C07C27/00 , C07C305/00
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.
摘要翻译：氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在氢气存在下与成形制品接触，成形制品可以在以下工艺中制备，其中（i）包含铜的氧化物质氧化物，氧化铝和镧，钨，钼，钛或锆的氧化物中的至少一种，（ii）将粉末状金属铜，铜片，粉末状水泥，石墨或其混合物加入氧化物中，（iii）由（ii）得到的混合物成型为成型制品。

10. 发明授权

US07510591B2 Catalyst and method for the hydration of carbonyl compounds 有权
标题翻译：催化剂和羰基化合物水合方法
公开(公告)号：US07510591B2
公开(公告)日：2009-03-31
申请号：US10549140
申请日：2004-03-20
申请人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
发明人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
IPC分类号： C22C29/12 , B01J23/72
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is brought into contact in the presence of hydrogen with a shaped article which can be produced in a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and at least one of the oxides of lanthanum, tungsten, molybdenum, titanium or zirconium is prepared, (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to a shaped article.
摘要翻译：氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在氢气存在下与成形制品接触，成形制品可以在以下工艺中制备，其中（i）包含铜的氧化物质氧化物，氧化铝和镧，钨，钼，钛或锆的氧化物中的至少一种，（ii）将粉末状金属铜，铜片，粉末状水泥，石墨或其混合物加入氧化物中，（iii）由（ii）得到的混合物成型为成型制品。

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