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1. 发明申请

US20050010057A1 Method for the continuous production of n-methyl-2-pyrrolidone (nmp) 有权
标题翻译：连续生产正甲基-2-吡咯烷酮（nmp）的方法
公开(公告)号：US20050010057A1
公开(公告)日：2005-01-13
申请号：US10495358
申请日：2002-11-15
申请人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkucher , Karl-Heinz Ross
发明人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkucher , Karl-Heinz Ross
IPC分类号： C07D207/26 , C07D207/267 , C07D207/12
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-methyl-2-pyrrolidone (NMP) by reacting gamma-butyrolactone (GBL) with monomethylamine (MMA) in the liquid phase, wherein GBL and MMA are used in a molar ratio of from 1:1.08 to 1:2 and the reaction is carried out at from 320 to 380° C. and an absolute pressure of from 70 to 120 bar.
摘要翻译：通过使γ-丁内酯（GBL）与一甲胺（MMA）在液相中连续制备N-甲基-2-吡咯烷酮（NMP）的方法，其中GBL和MMA的摩尔比为1:1.08至 1：2，反应在320〜380℃，绝对压力为70〜120巴下进行。

2. 发明授权

US07227029B2 Method for the continuous production of N-methyl-2-pyrrolidone (NMP) 有权
标题翻译：连续生产N-甲基-2-吡咯烷酮（NMP）的方法
公开(公告)号：US07227029B2
公开(公告)日：2007-06-05
申请号：US10495358
申请日：2002-11-15
申请人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkücher , Karl-Heinz Ross
发明人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkücher , Karl-Heinz Ross
IPC分类号： C07D207/12 , C07D307/20
CPC分类号： C07D207/267
摘要： Process for the continuous preparation of N-methyl-2-pyrrolidone (NMP) by reacting gamma-butyrolactone (GBL) with monomethylamine (MMA) in the liquid phase, wherein GBL and MMA are used in a molar ratio of from 1:1.08 to 1:2 and the reaction is carried out at from 320 to 380° C. and an absolute pressure of from 70 to 120 bar.
摘要翻译：通过使γ-丁内酯（GBL）与一甲胺（MMA）在液相中连续制备N-甲基-2-吡咯烷酮（NMP）的方法，其中GBL和MMA的摩尔比为1:1.08至 1：2，反应在320〜380℃，绝对压力为70〜120巴下进行。

3. 发明授权

US07164031B2 Method for the production of 2-pyrrolidone 有权
标题翻译： 2-吡咯烷酮生产方法
公开(公告)号：US07164031B2
公开(公告)日：2007-01-16
申请号：US10487452
申请日：2002-08-30
申请人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkücher , Karl-Heinz Ross
发明人： Martin Rudloff , Peter Stops , Erhard Henkes , Helmut Schmidtke , Rolf-Hartmuth Fischer , Manfred Julius , Rolf Lebkücher , Karl-Heinz Ross
IPC分类号： C07D207/267
CPC分类号： C07D207/267 , C07D201/08
摘要： A process for continuously preparing 2-pyrrolidone by reacting gamma-butyrolactone with ammonia in the liquid phase in the presence of water, wherein the reaction is carried out at a temperature of from 275 to 300° C. and an absolute pressure of from 140 to 180 bar.
摘要翻译：一种在水存在下使γ-丁内酯与氨在液相中反应连续制备2-吡咯烷酮的方法，其中反应在275-300℃的温度下进行，绝对压力为140〜 180吧。

4. 发明申请

US20110009627A1 REACTOR FOR CARRYING OUT HIGH PRESSURE REACTIONS, METHOD FOR STARTING AND METHOD FOR CARRYING OUT A REACTION 审中-公开
标题翻译：实施高压反应的反应器，起动方法和进行反应的方法
公开(公告)号：US20110009627A1
公开(公告)日：2011-01-13
申请号：US12864540
申请日：2009-01-21
申请人： Helmut Schmidtke , Wilhelm Ruppel , Helmut Berrsche , Johann-Peter Melder , Udo Rheude , Petr Kubanek , Gerhard Ruf , Wolfgang Gunkel , Wolfgang Mägerlein , Karl-Heinz Ross
发明人： Helmut Schmidtke , Wilhelm Ruppel , Helmut Berrsche , Johann-Peter Melder , Udo Rheude , Petr Kubanek , Gerhard Ruf , Wolfgang Gunkel , Wolfgang Mägerlein , Karl-Heinz Ross
IPC分类号： B01J19/00 , C07D265/30 , C07C209/04
CPC分类号： B01J8/067 , B01J8/008 , B01J2208/00539 , B01J2208/00796
摘要： The invention relates to a reactor for performing high-pressure reactions, comprising at least one tube (31) whose ends are each conducted through a tube plate (33) and which is bonded to the tube plate (33). The tube plates (33) and the at least one tube (31) are surrounded by an outer jacket, such that an outer space (39) is formed between the tube (31) and the outer jacket. The tube plates (33) each have at least one surface composed of a nickel-base alloy and the at least one tube (31) is in each case welded on to the surface composed of the nickel-base alloy. The surface composed of the nickel-base alloy points in each case in the direction of the particular reactor end. The outer jacket has a thickness which is sufficient to absorb tensile forces which occur between tube (31) and outer jacket owing to a temperature difference in the event of different expansion. The invention further relates to a process for starting up the reactor and for performing an exothermic reaction in the reactor.
摘要翻译：本发明涉及一种用于进行高压反应的反应器，包括至少一个管（31），其端部各自通过管板（33）导通，并连接到管板（33）。管板（33）和至少一个管（31）被外护套围绕，使得在管（31）和外护套之间形成外部空间（39）。管板（33）各自具有由镍基合金构成的至少一个表面，并且至少一个管（31）各自焊接在由镍基合金构成的表面上。由镍基合金组成的表面在每种情况下都指向特定反应器端的方向。外护套的厚度足以吸收由于在不同膨胀的情况下的温度差而在管（31）和外护套之间发生的张力。本发明还涉及一种启动反应器并在反应器中进行放热反应的方法。

5. 发明授权

US06348601B2 Preparation of N-methyl-2-pyrrolidone (NMP) 失效
标题翻译：制备N-甲基-2-吡咯烷酮（NMP）
公开(公告)号：US06348601B2
公开(公告)日：2002-02-19
申请号：US09774628
申请日：2001-02-01
申请人： Frank Ohlbach , Johann-Peter Melder , Karl-Heinz Ross , Martin Rudloff , Jörg Liebe
发明人： Frank Ohlbach , Johann-Peter Melder , Karl-Heinz Ross , Martin Rudloff , Jörg Liebe
IPC分类号： C07D207267
CPC分类号： C07D207/267
摘要： N-Methyl-2-pyrrolidone (NMP) is prepared by preparing a mixture comprising monomethylamine, dimethylamine and trimethylamine and ammonia in a first process step by reacting ammonia with methanol at elevated temperature in the presence of a catalyst, separating 10 off the ammonia, reacting the mixture comprising the methylamines with gamma-butyrolactone (&ggr;-BL), in a molar ratio of monomethylamine to &ggr;-BL of at least 1 in a second process step at elevated temperature and superatmospheric pressure, separating NMP and unreacted methylamines from the reaction product and returning unreacted methylamines to the first process step for reaction with methanol and ammonia.
摘要翻译：通过在第一工艺步骤中通过在升高的温度下在催化剂存在下使氨与甲醇反应制备包含单甲胺，二甲胺和三甲胺和氨的混合物来制备N-甲基-2-吡咯烷酮（NMP），从氨分离10，在高温和超大气压下，在第二工艺步骤中使包含甲胺的混合物与γ-丁内酯（γ-BL）以一甲基胺与γ-BL的摩尔比至少为1的反应物反应，从反应中分离NMP和未反应的甲胺产物并将未反应的甲胺返回到用于与甲醇和氨反应的第一工艺步骤。

6. 发明授权

US07309403B2 Method for avoiding corrosion 有权
标题翻译：避免腐蚀的方法
公开(公告)号：US07309403B2
公开(公告)日：2007-12-18
申请号：US10572783
申请日：2004-09-24
申请人： Werner Reutemann , Theodor Weber , Karl-Heinz Ross , Manfred Julius
发明人： Werner Reutemann , Theodor Weber , Karl-Heinz Ross , Manfred Julius
IPC分类号： B01D3/38 , B01D3/40 , C07C209/86 , C07C209/90
CPC分类号： C07C211/04 , C07C209/86 , Y10S203/20 , Y10S203/24
摘要： The invention relates to a method of avoiding corrosion in the separation of methylamine from a product stream (10) which is obtained in the preparation of methylamines by gas-phase reaction of methanol and ammonia and includes monomethylamine, dimethylamine, trimethylamine, ammonia and methanol as components, where ammonia is separated off by pure distillation in a first column (1), the remaining components of the product stream obtained as bottoms (12) are fed to a second column (2). Trimethylamine (14) is separated off in the second column (2) by extractive distillation with introduction of water. The further of the product stream obtained as bottoms (15) from the second column (2) are fed to a third column (3), in which monomethylamine and dimethylamine are separated off at the top. The monomethylamine and dimethylamine are separated by distillation in a fourth column (4). To avoid corrosion alkali metal hydroxide is added to the second or third column (3).
摘要翻译：本发明涉及一种避免在甲醇与甲醇与氨的气相反应制备甲胺中得到的产物流（10）中分离甲胺的腐蚀方法，包括一甲胺，二甲胺，三甲胺，氨和甲醇组分，其中在第一塔（1）中通过纯蒸馏分离氨，将作为塔底物（12）获得的产物流的剩余组分进料至第二塔（2）。通过萃取蒸馏引入三水胺（14）在第二塔（2）中分离。从第二塔（2）获得的作为塔底物（15）获得的产物流的其它组分进料到第三塔（3），其中一甲胺和二甲胺在顶部分离。在第四列（4）中通过蒸馏分离一甲胺和二甲胺。为了避免腐蚀，将碱金属氢氧化物加入到第二或第三塔（3）中。

7. 发明申请

US20060243584A1 Method for avoiding corrosion 有权
标题翻译：避免腐蚀的方法
公开(公告)号：US20060243584A1
公开(公告)日：2006-11-02
申请号：US10572783
申请日：2004-09-24
申请人： Werner Reutemann , Theodor Weber , Karl-Heinz Ross , Manfred Julius
发明人： Werner Reutemann , Theodor Weber , Karl-Heinz Ross , Manfred Julius
IPC分类号： B01D3/34
CPC分类号： C07C211/04 , C07C209/86 , Y10S203/20 , Y10S203/24
摘要： The invention relates to a method of avoiding corrosion in the separation of methylamine from a product stream (10) which is obtained in the preparation of methylamines by gas-phase reaction of methanol and ammonia and comprises monomethylamine, dimethylamine, trimethylamine, ammonia and methanol as components, where ammonia is separated off by pure distillation in a first column (1), the remaining components of the product stream obtained as bottoms (12) are fed to a second column (2). Trimethylamine (14) is separated off in the second column (2) by extractive distillation with introduction of water. The further components of the product stream obtained as bottoms (15) from the second column (2) are fed to a third column (3), in which monomethylamine and dimethylamine are separated off at the top. The monomethylamine and dimethylamine are separated by distillation in a fourth column (4). To avoid corrosion alkali metal hydroxide is added to the second or third column (3).
摘要翻译：本发明涉及一种避免在从甲醇和氨气相反应制备甲胺中得到的产物流（10）中甲胺分离腐蚀的方法，包括一甲胺，二甲胺，三甲胺，氨和甲醇组分，其中在第一塔（1）中通过纯蒸馏分离氨，将作为塔底物（12）获得的产物流的剩余组分进料至第二塔（2）。通过萃取蒸馏引入三水胺（14）在第二塔（2）中分离。从第二塔（2）获得的作为塔底物（15）获得的产物流的其它组分进料到第三塔（3），其中一甲胺和二甲胺在顶部分离。在第四列（4）中通过蒸馏分离一甲胺和二甲胺。为了避免腐蚀，将碱金属氢氧化物加入到第二或第三塔（3）中。

8. 发明申请

US20080255390A1 Shaped Body Comprising an Aluminosilicate and Aluminium Oxide and Process for the Continuous Preparation of Methylamines 有权
标题翻译：包含硅铝酸盐和氧化铝的成形体和用于连续制备甲胺的方法
公开(公告)号：US20080255390A1
公开(公告)日：2008-10-16
申请号：US12088743
申请日：2006-09-21
申请人： Marco Bosch , Roderich Rottger , Jan Eberhardt , Thomas Krug , Manfred Julius , Karl-Heinz Ross , Theodor Weber
发明人： Marco Bosch , Roderich Rottger , Jan Eberhardt , Thomas Krug , Manfred Julius , Karl-Heinz Ross , Theodor Weber
IPC分类号： B01J21/12 , B01J21/04 , B01J35/10 , C07C209/16
CPC分类号： C07C209/16 , B01J21/12 , B01J21/16 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/109 , B01J35/1095 , B01J37/0009 , B01J37/0018 , C07C211/04
摘要： Shaped body comprising an aluminosilicate and aluminum oxide, wherein the shaped body has a molar Al/Si ratio in the range from 10 to 30 and an at least bimodal pore distribution for pores having a diameter of greater than 1 nm, with the volume of the pores of the shaped body having a diameter of greater than 10 nm corresponding to at least 40% of the total pore volume of the shaped body, process for producing it and process for the continuous preparation of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the abovementioned shaped bodies are used as catalyst.
摘要翻译：包括铝硅酸盐和氧化铝的成形体，其中成形体的Al / Si摩尔比在10至30的范围内，并且对于具有大于1nm直径的孔的至少双峰孔分布，其体积成形体的孔径大于10nm，对应于成形体的总孔体积的至少40％，其生产方法和通过甲醇和/或二甲醚的反应连续制备甲胺的方法在存在非均相催化剂的情况下使用氨，其中上述成形体用作催化剂。

9. 发明申请

US20070270614A1 Method for Controlling the Reactor Admission Temperature During the Production of Methylamine 有权
标题翻译：控制甲胺生产过程中反应器进口温度的方法
公开(公告)号：US20070270614A1
公开(公告)日：2007-11-22
申请号：US10573185
申请日：2004-09-24
申请人： Werner Reutemann , Rolf Wambsganss , Frank Poplow , Theodor Weber , Karl-Heinz Ross , Manfred Julius
发明人： Werner Reutemann , Rolf Wambsganss , Frank Poplow , Theodor Weber , Karl-Heinz Ross , Manfred Julius
IPC分类号： C07C209/14
CPC分类号： C07C209/16 , C07C211/04
摘要： The invention relates to a process for preparing methylamines by gas-phase reaction of methanol and ammonia as starting materials at a pressure in the range from 15 to 30 bar in the presence of heterogeneous catalyst. The starting materials are vaporized in one or more heat exchangers (1, 2, 3), superheated to produce a feed gas stream and subsequently fed into a reactor (4), with the mixing of the starting materials being able to be carried out in the feed stream to one of the heat exchangers (1, 2, 3) or at any desired position in a heat exchanger (1, 2, 3). A product gas stream comprising monomethylamine, dimethylamine and trimethylamine and also reaction by-products is taken off from the reactor (4). To control the reactor inlet temperature of the starting materials to a temperature in the range from 360° C. to 370° C., all or some of the feed gas stream or the product gas stream is passed through an adjustable valve (5) in order to vary the pressure and thus the condensation temperature.
摘要翻译：本发明涉及通过甲醇和氨作为起始原料在非均相催化剂存在下在15至30巴的压力下气相反应制备甲胺的方法。起始材料在一个或多个热交换器（1,2,3）中蒸发，过热以产生进料气流，并随后进料到反应器（4）中，原料的混合能够进行到一个热交换器（1,2,3）或在热交换器（1,2,3）中的任何期望位置的进料流。从反应器（4）中取出包含一甲胺，二甲胺和三甲胺以及反应副产物的产物气流。为了将原料的反应器入口温度控制在360℃至370℃的温度范围内，所有或一些进料气流或产物气流通过可调节阀（5），其中以改变压力，从而改变冷凝温度。

10. 发明申请

US20080103336A1 Method for producing N, N-Dimethylacetamide (Dmac) 审中-公开
标题翻译：制备N，N-二甲基乙酰胺（Dmac）的方法
公开(公告)号：US20080103336A1
公开(公告)日：2008-05-01
申请号：US11720791
申请日：2005-12-03
申请人： Horst Grafmans , Steffen Maas , Alexander Weck , Heinz Rutter , Michael Schulz , Karl-Heinz Ross
发明人： Horst Grafmans , Steffen Maas , Alexander Weck , Heinz Rutter , Michael Schulz , Karl-Heinz Ross
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , C07C233/05
摘要： A process for preparing N,N-dimethylacetamide (DMAC) by continuously reacting methyl acetate (MeOAc) with dimethylamine (DMA) in the presence of a basic catalyst, wherein MeOAc is used in the form of a methanolic solution and in the range from 0.0002 to 0.09 mol of catalyst per mole of MeOAc, and performing the reaction at a temperature in the range from 90 to 140° C. and at an absolute pressure in the range from 10 to 30 bar.
摘要翻译：在碱性催化剂存在下，通过使乙酸甲酯（MeOAc）与二甲胺（DMA）连续反应制备N，N-二甲基乙酰胺（DMAC）的方法，其中MeOAc以甲醇溶液的形式使用，范围为0.0002 至0.09摩尔催化剂/摩尔MeOAc，并在90至140℃的温度和10至30巴的绝对压力下进行反应。

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