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1. 发明申请

US20070232833A1 Method for the Continuous Production of an Amine 失效
标题翻译：连续生产胺的方法
公开(公告)号：US20070232833A1
公开(公告)日：2007-10-04
申请号：US11596292
申请日：2005-05-04
申请人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Ross , Heinz Rutter , Shelue Liang , Stefan Rittinger
发明人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Ross , Heinz Rutter , Shelue Liang , Stefan Rittinger
IPC分类号： C07C209/60
CPC分类号： C07C209/26 , C07C209/16 , C07C213/02 , C07D295/027 , C07D295/03 , C07D295/088 , C08G59/50 , Y02P20/582 , C07C211/06 , C07C211/08 , C07C211/35 , C07C217/08
摘要： Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
摘要翻译：通过伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在60至300℃的温度下反应来连续制备胺的方法在含铜催化剂存在下，其中催化剂在用氢还原之前的催化活性组合物包含20至85重量％的氧化铝（Al 2 O 3） 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2），1至70重量％的以CuO计的含氧化合物的铜，0至50重量％的以氧化镁计的含氧化合物，以氧化铬计算的含铬化合物，以ZnO计算的含氧化合物锌，以BaO计的钡的含氧化合物和/ 或以CaO计的含氧化合物的钙，小于30重量％的按NiO计的含氧化合物的镍，以CuO计算的含氧化合物计算，并进行反应在管式反应器中在气相中等温。

2. 发明授权

US07405327B2 Method for the continuous production of an amine 失效
标题翻译：连续生产胺的方法
公开(公告)号：US07405327B2
公开(公告)日：2008-07-29
申请号：US11596292
申请日：2005-05-04
申请人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
发明人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Roβ , Heinz Rutter , Shelue Liang , Stefan Rittinger
IPC分类号： C07C209/26
CPC分类号： C07C209/26 , C07C209/16 , C07C213/02 , C07D295/027 , C07D295/03 , C07D295/088 , C08G59/50 , Y02P20/582 , C07C211/06 , C07C211/08 , C07C211/35 , C07C217/08
摘要： Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C. in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
摘要翻译：通过伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在60至300℃的温度下反应来连续制备胺的方法在含铜催化剂存在下，其中催化剂在用氢还原之前的催化活性组合物包含20至85重量％的氧化铝（Al 2 O 3 > 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2）），1至70重量％的以CuO计的铜的含氧化合物，0至50重量％的以MgO计的含氧化合物的镁，含氧化合物的铬，其计算为Cr 以ZnO计算的含氧化合物锌，以BaO表示的含氧化合物的钡，以BaO计算， /或以CaO计的钙的含氧化合物，以NiO计，以CuO计的含铜化合物计，小于30重量％的含氧化合物的镍，反应为在管式反应器中在气相中等温进行。

3. 发明授权

US08877965B2 Process for preparing formic acid by reaction of carbon dioxide with hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US08877965B2
公开(公告)日：2014-11-04
申请号：US13171928
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15 , C07F15/00 , C07C53/00 , C07C51/44 , C07C51/48
CPC分类号： C07C51/44 , C07C51/15 , C07C51/48 , C07C53/02
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where the work-up of the output (3) from the hydrogenation reactor (I) is carried out by addition of water so as to increase the distribution coefficient of the catalyst between the upper phase (4) and the lower phase.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子的极性溶剂和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中后处理通过加入水进行加氢反应器（I）的输出（3），以增加催化剂在上相（4）和下相之间的分配系数。

4. 发明授权

US08791297B2 Process for preparing formic acid by reaction of carbon dioxide with hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US08791297B2
公开(公告)日：2014-07-29
申请号：US13172123
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/44 , C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
CPC分类号： C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols and also water, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, with work-up of the output (3) from the hydrogenation reactor (I) in a plurality of process steps, where a tertiary amine-comprising stream (13) from the work-up is used as selective solvent for the catalyst, is proposed.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子，以及包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和极性溶剂的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，具有后处理提出了在多个工艺步骤中，来自加氢反应器（I）的输出物（3）的来自后处理的含叔胺的物流（13）用作催化剂的选择性溶剂。

5. 发明申请

US20130012739A1 PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN 审中-公开
标题翻译：通过用氢气反应二氧化碳制备形式酸的方法
公开(公告)号：US20130012739A1
公开(公告)日：2013-01-10
申请号：US13542791
申请日：2012-07-06
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Peter Bassler , Martin Schäfer , Stefan Rittinger
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Peter Bassler , Martin Schäfer , Stefan Rittinger
IPC分类号： C07C51/15
CPC分类号： C07C51/44 , C07C51/48 , C07C51/487 , C07C53/02
摘要： A process for preparing formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent to form formic acid-amine adducts which are subsequently dissociated thermally into formic acid and tertiary amine.
摘要翻译：在含有元素周期表第8,9或10族元素的催化剂存在下，在氢化反应器中使二氧化碳与氢反应制备甲酸的方法，叔胺和极性溶剂以形成甲酸 - 胺加成物随后被热分解成甲酸和叔胺。

6. 发明申请

US20070282135A1 Hydrogenation of methylolalkanals 有权
标题翻译：氢化甲羟烷醇
公开(公告)号：US20070282135A1
公开(公告)日：2007-12-06
申请号：US11447020
申请日：2006-06-06
申请人： Steffen Maas , Thorsten Johann , Michael Koch , Tilman Sirch , Stephan Schlitter , Stefan Rittinger , Michael Steiniger , Todd C. Spengeman
发明人： Steffen Maas , Thorsten Johann , Michael Koch , Tilman Sirch , Stephan Schlitter , Stefan Rittinger , Michael Steiniger , Todd C. Spengeman
IPC分类号： C07C45/62
CPC分类号： C07C29/141 , C07C31/20
摘要： Process for the catalytic hydrogenation of methylolalkanals of the general formula where R1 and R2 are each, independently of one another, a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase by means of hydrogen over a hydrogenation catalyst, wherein hydrogen is used in a molar ratio to methylolalkanal of greater than 1.
摘要翻译：用于通式的羟甲基烷烃的催化氢化方法其中R 1和R 2各自彼此独立地是另外的羟甲基或具有1个至22个碳原子或具有6至33个碳原子的芳基或芳烷基，在液相中通过氢气在氢化催化剂上氢化，其中氢以与羟甲基烷醛的摩尔比大于1。

7. 发明授权

US5414086A Preparation of 4-methylpyrimidines 失效
标题翻译： 4-甲基嘧啶的制备
公开(公告)号：US5414086A
公开(公告)日：1995-05-09
申请号：US199452
申请日：1994-02-22
申请人： Stefan Rittinger , Norbert Rieber
发明人： Stefan Rittinger , Norbert Rieber
IPC分类号： C07D239/26 , C07D239/42 , C07D295/104 , C07D239/34 , C07D239/38
CPC分类号： C07D239/26 , C07D239/42 , C07D295/104 , Y02P20/582
摘要： A process for the preparation of a 4-methylpyrimidine of the general formula I ##STR1## in which R.sup.1 denotes C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.8 cycloalkyl, aryl, C.sub.7 -C.sub.12 phenalkyl, C.sub.7 -C.sub.12 alkylphenyl, NH.sub.2, NHCN, OH, and SH,in which a 1-aminovinyl methyl ketone of the general formula II ##STR2## in which R.sup.2 and R.sup.3 denote C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.8 cycloalkyl, aryl, C.sub.7 -C.sub.12 phenylalkyl, C.sub.7 -C.sub.12 alkylphenyl, C.sub.1 -C.sub.20 hydroxyalkyl or together denote a C.sub.2 -C.sub.7 alkylene chain optionally mono- to tetra-substituted by C.sub.1 -C.sub.4 alkyl and optionally interrupted by oxygen, nitrogen, or sulfur, is caused to react with a carboxamide or amidine or a salt thereof of the general formula III ##STR3## in which R.sup.1 has the aforementioned meanings and x stands for oxygen or NH, at temperatures ranging from 20.degree. to 200.degree. C. and pressures ranging from 0.01 to 50 bar.
摘要翻译：制备通式I（I）的4-甲基嘧啶的方法，其中R1表示C1-C20烷基，C3-C8环烷基，芳基，C7-C12苯烷基，C7-C12烷基苯基，NH2，NHCN ，OH和SH，其中通式II的1-氨基乙烯基甲基酮（II）其中R2和R3表示C1-C20烷基，C3-C8环烷基，芳基，C7-C12苯基烷基，C7-C12 烷基苯基，C 1 -C 20羟基烷基或一起表示任选被C 1 -C 4烷基单取代和四取代并任选被氧，氮或硫中断的C 2 -C 7亚烷基链与羧酰胺或脒或盐反应其中R 1具有上述含义，x代表氧或NH，通常在20℃至200℃的温度和0.01至50巴的压力下进行。

8. 发明授权

US08901350B2 Process for the preparation of formic acid 有权
标题翻译：制备甲酸的方法
公开(公告)号：US08901350B2
公开(公告)日：2014-12-02
申请号：US13171598
申请日：2011-06-29
申请人： Daniel Schneider , Klaus-Dieter Mohl , Martin Schäfer , Karin Pickenäcker , Stefan Rittinger , Thomas Schaub , Joaquim Henrique Teles , Rocco Paciello , Gerd Kaibel
发明人： Daniel Schneider , Klaus-Dieter Mohl , Martin Schäfer , Karin Pickenäcker , Stefan Rittinger , Thomas Schaub , Joaquim Henrique Teles , Rocco Paciello , Gerd Kaibel
IPC分类号： C07C51/44 , C07C51/09
CPC分类号： C07C51/09 , C07C51/44 , C07C53/02
摘要： Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and a tertiary amine (I) in a molar ratio of from 0.5 to 5 is produced by combining tertiary amine (I) and a formic acid source, from 10 to 100% by weight of the secondary components present therein are separated off and formic acid is removed by distillation in a distillation apparatus at a bottom temperature of from 100 to 300° C. and a pressure of from 30 to 3000 hPa abs from the liquid stream obtained, the bottom discharge from the distillation apparatus being separated into two liquid phases and the upper liquid phase being recycled to the formic acid source and the lower liquid phase being recycled for separating off the secondary components and/or to the distillation apparatus.
摘要翻译：通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含摩尔比为0.5至5的甲酸和叔胺（I）的液体流通过组合分离叔胺（I）和甲酸源，10至100重量％存在于其中的次要组分，并在蒸馏装置中在100-300℃的底部温度下蒸馏除去甲酸。从得到的液体流中的压力为30〜3000hPa abs，将来自蒸馏装置的底部排出物分离成两液相，将上液相再循环至甲酸源，将下液相回收分离脱离第二组分和/或蒸馏装置。

9. 发明申请

US20120022290A1 Process for Preparing Formic Acid by Reaction of Carbon Dioxide with Hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US20120022290A1
公开(公告)日：2012-01-26
申请号：US13171928
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15
CPC分类号： C07C51/44 , C07C51/15 , C07C51/48 , C07C53/02
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where the work-up of the output (3) from the hydrogenation reactor (I) is carried out by addition of water so as to increase the distribution coefficient of the catalyst between the upper phase (4) and the lower phase.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子的极性溶剂和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中后处理通过加入水进行加氢反应器（I）的输出（3），以增加催化剂在上相（4）和下相之间的分配系数。

10. 发明申请

US20110272270A1 Process for Preparing Polymethylols 有权
标题翻译：制备多羟基睾酮的方法
公开(公告)号：US20110272270A1
公开(公告)日：2011-11-10
申请号：US13144124
申请日：2010-01-07
申请人： Stephan Schlitter , Michael Steiniger , Stefan Rittinger , Tilman Sirch , Steffen Maas
发明人： Stephan Schlitter , Michael Steiniger , Stefan Rittinger , Tilman Sirch , Steffen Maas
IPC分类号： B01D3/36
CPC分类号： C07C29/80 , C07C29/141 , C07C45/75 , C07C45/82 , C07C31/22 , C07C31/245 , C07C47/19
摘要： The present invention relates to a process for recovering components from a low boiler mixture which is obtained in the distillation of hydrogenation effluents from the preparation of polymethylols, by multistage distillation of the low boiler mixture comprising a tertiary amine, water, methanol, polymethylol of the formula (I) methylolalkanal of the formula (II) alcohol of the formula (III) and an alkanal with a methylene group in the α position to the carbonyl group, and in which each R is independently a further methylol group or an alkyl group having 1 to 22 carbon atoms or an aryl or aralkyl group having 6 to 22 carbon atoms, a first distillation stage involving separating the low boiler mixture into a higher-boiling, predominantly water-rich fraction and into a lower-boiling aqueous organic fraction comprising the tertiary amine, and the second distillation stage involving separating the aqueous organic fraction from the first distillation stage into a predominantly amine-containing fraction and a further amine-depleted fraction, wherein the tertiary amine is trimethylamine or triethylamine, and the bottom temperature in the second distillation stage is 110° C. and more.
摘要翻译：本发明涉及一种从低沸点混合物中回收组分的方法，该方法是从多羟甲基的制备中蒸馏氢化流出物获得的，通过多级蒸馏包含叔胺，水，甲醇，多羟甲基的低沸点混合物式（I）式（II）醇的式（I）的羟甲基烷醛和式（III）的醇的亚烷基与在羰基的α位上具有亚甲基的链烷醛，其中每个R独立地是另外的羟甲基或具有 1至22个碳原子或具有6至22个碳原子的芳基或芳烷基，第一蒸馏阶段包括将低锅炉混合物分离成较高沸点，主要是富水部分和低沸点含水有机部分，叔胺，第二蒸馏阶段将含水有机部分从第一蒸馏阶段分离成主要是胺其中叔胺为三甲胺或三乙胺，第二蒸馏阶段的底部温度为110℃以上。

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