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1. 发明申请

WO2013192404A1 POLYHETEROSILOXANE COMPOSITION 审中-公开
标题翻译：聚硅氧烷组合物
公开(公告)号：WO2013192404A1
公开(公告)日：2013-12-27
申请号：PCT/US2013/046784
申请日：2013-06-20
申请人： DOW CORNING CORPORATION
发明人： DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn , SCHMIDT, Randall , SHAHINIAN, Katherine, Marie , SKINNER, Kwan , LU, Gang , CHOI, Jongwook
IPC分类号： C08G77/58 , C08L83/14
CPC分类号： C08G77/58 , C08L83/14
摘要： A polyheterosiloxane composition includes (A) a first metal (M1), (B) a second metal (M2), and (C) siloxy units having the formula (R 1 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 SiO 3/2 ), and/or (SiO 4/2 ). Each R 1 is independently a hydrocarbon or halogenated hydrocarbon group including 1 to 30 carbon atoms. The mole fractions of (A), (B), and (C) relative to each other is of the formula [(M1)] a [(M2)] b [R 1 3 SiO 1/2 ] m [R 1 2 SiO 2/2 ] d [R 1 SiO 3/2 ] t [SiO 4/2 ] q , wherein a and b are each independently from 0.001 to 0.9, m, d, t, and q are each independently from zero to 0.9, m, d, t, and q cannot all be zero, and the sum of a+b+m+d+t+q ≈ 1. At least one oxygen atom of the siloxy units is bonded to at least one of (M1) and/or (M2). The composition exhibits a quantum yield of at least 0.05% and at least one of (M1) and (M2) is a lanthanide metal.
摘要翻译：聚硅氧烷组合物包括（A）第一金属（M1），（B）第二金属（M2）和（C）具有式（R1 3SiO1 / 2），（R1SiO2 / 2），（R1SiO3 / 2），和/或（SiO 4/2）。每个R 1独立地是含有1至30个碳原子的烃或卤代烃基。（A），（B）和（C）相对于彼此的摩尔分数为式[（M1）] a [（M2）] b [R1 3SiO1 / 2] m [R1 2SiO2 / 2] d [R1SiO3 / 2] t [SiO4 / 2] q，其中a和b各自独立地为0.001至0.9，m，d，t和q各自独立地为0至0.9，m，d，t和q不能全部为零，并且a + b + m + d + t + q≈1的和。所述甲硅烷氧基单元的至少一个氧原子键合到（M1）和/或（M2）中的至少一个。该组合物显示至少0.05％的量子产率，并且（M1）和（M2）中的至少一种是镧系金属。

2. 发明申请

WO2016126326A1 TREATED FILLERS AND USES THEREOF 审中-公开
标题翻译：处理过滤器及其用途
公开(公告)号：WO2016126326A1
公开(公告)日：2016-08-11
申请号：PCT/US2015/064641
申请日：2015-12-09
申请人： DOW CORNING CORPORATION
发明人： LIU, Lizhi , SWIER, Steven , WEI, Yanhu
IPC分类号： H01L23/29 , C08K5/3465 , C08L83/04
CPC分类号： C09K11/7734 , C08G77/08 , C08G77/44 , C09C1/3669 , C09C3/08 , C09K11/02 , C09K11/025 , C09K11/7721 , H01L33/502 , H01L33/507 , H01L33/56
摘要： The various embodiments of the present invention relate to condensation curable silicone compositions comprising: a condensation curable polyorganosiloxane; and treated particles comprising a particulate solid having an effective amount of nitrogen-containing base (e.g., a nitrogen-containing superbase) disposed thereon. Other embodiments of the present invention relate to methods for preparing the aforementioned treated particles; the treated particles themselves; and methods of using the treated particles and compositions of the various embodiments of the present invention.
摘要翻译：本发明的各种实施方案涉及可缩合固化的硅氧烷组合物，其包含：可缩合固化的聚有机硅氧烷; 以及包含具有有效量的置于其上的含氮碱（例如，含氮超碱性）的颗粒状固体的处理颗粒。本发明的其它实施方案涉及制备上述处理过的颗粒的方法; 处理过的颗粒本身; 以及使用本发明的各种实施方案的经处理的颗粒和组合物的方法。

3. 发明申请

WO2013192419A1 POLYHETEROSILOXANE COMPOSITION 审中-公开
标题翻译：聚硅氧烷组合物
公开(公告)号：WO2013192419A1
公开(公告)日：2013-12-27
申请号：PCT/US2013/046813
申请日：2013-06-20
申请人： DOW CORNING CORPORATION
发明人： DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn , SCHMIDT, Randall , SKINNER, Kwan
IPC分类号： C08G77/58 , C08L83/14
CPC分类号： C08G77/58 , C08L83/14
摘要： This disclosure provides a polyheterosiloxane composition including (A) a first metal (Ml), (B) a second metal (M2), and (C) siloxy units having the formula (R 2 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 Si0 3/2 ), and/or (Si0 4/2 ), wherein each R 1 is independently a hydrocarbon or halogenated hydrocarbon group comprising 1 to 30 carbon atoms, and wherein each R 2 is independently a hydrocarbyl group having from 1 to 20 carbon atoms or an organosiloxane having at least one disiloxy unit. The mole fractions of (A), (B), and (C) relative to each other are of the formula [(M1)]a[(M2)]b[R 2 3 Si0 1/2 ]m[R 1 2 Si0 2/2 ]d[R 1 Si0 3/2 ]t[Si0 4/2 ] q , wherein a is from 0.001 to 0.9, b is from 0.001 to 0.9, m is from 0.001 to 0.9, d is from zero to 0.9, t is from zero to 0.9, and q is from zero to 0.9. In this formula, d, t, and q cannot all be zero and the sum of a+b+m+d+t+q ≈ 1.
摘要翻译：本公开内容提供了包含（A）第一金属（M1），（B）第二金属（M2）和（C）具有式（R2 3SiO1 / 2），（R1SiO2 / 2），（R 1 SiO 3/2）和/或（SiO 4/2），其中每个R 1独立地是含有1至30个碳原子的烃或卤代烃基，并且其中每个R 2独立地是具有1至20个碳原子的烃基或具有至少一个disiloxy单元的有机硅氧烷。（A），（B）和（C）相对于彼此的摩尔分数具有式[（M1）] a [（M2）] b [R2 3Si01 / 2] m [R1 2Si02 / 2] d [R1SiO3 / 2] t [Si04 / 2] q，其中a为0.001至0.9，b为0.001至0.9，m为0.001至0.9，d为0至0.9，t为0至0.9， q为0〜0.9。在该公式中，d，t和q不能全部为零，并且a + b + m + d + t + q≈1的和。

4. 发明申请

WO2012088439A1 POLYHETEROSILOXANE COMPOSITION INCLUDING LANTHANIDE METAL 审中-公开
标题翻译：聚硅氧烷组合物，包括兰德金属
公开(公告)号：WO2012088439A1
公开(公告)日：2012-06-28
申请号：PCT/US2011/066890
申请日：2011-12-22
申请人： DOW CORNING CORPORATION , DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn, Keith , SCHMIDT, Randall
发明人： DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn, Keith , SCHMIDT, Randall
IPC分类号： C08G77/58
CPC分类号： C09K11/06 , C08G77/58 , C08L83/04
摘要： A polyheterosiloxane composition includes (A) a first metal (Ml), (B) a second metal (M2), and (C) siloxy units having the formula (R 1 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 SiO 3/2 ), and/or (S1O 4/2 ). R 1 is independently a hydrocarbon or halogenated hydrocarbon group including 1 to 30 carbon atoms. The mole fractions of (A), (B), and (C) relative to each other is of the formula [(Ml)] a [(M2)] b [R 1 3 SiO 1/2 ] m [R 1 2 SiO 2/2 ] d [R 1 SiO 3/2 ] t [SiO 4/2 ] q , wherein a and b are each independently from 0.001 to 0.9, each of m, d, t, and q are independently from zero to 0.9 so long as m, d, t, and q are not all zero and the sum of a+b+m+d+t+q ≈ 1. At least one of (M1) and (M2) is a lanthanide metal. The composition exhibits a quantum yield of at least 0.05% and is formed using a method including reacting (Α') a metal (M3) alkoxide, (Β') an optional hydrolyzable metal (M4) salt, (C') a silicon-containing material and (D) water.
摘要翻译：聚硅氧烷组合物包括（A）第一金属（M1），（B）第二金属（M2）和（C）具有式（R1 3SiO1 / 2），（R1SiO2 / 2），（R1SiO3 / 2），和/或（S1O4 / 2）。 R1独立地是含有1至30个碳原子的烃或卤代烃基。（A），（B）和（C）相对于彼此的摩尔分数具有式[（M1）] a [（M2）] b [R1 3SiO1 / 2] m [R1 2SiO2 / 2] d [R1SiO3 / 2] t [SiO4 / 2] q，其中a和b各自独立地为0.001至0.9，m，d，t和q各自独立地为0至0.9，只要m，d，t，和q不是全零，a + b + m + d + t + q〜1的和。（M1）和（M2）中的至少一个是镧系金属。该组合物显示出至少0.05％的量子产率，并且使用包括使（α'）金属（M3）醇盐，（α'）任选的可水解金属（M4）盐，（C'）硅 - （D）水。

5. 发明申请

WO2014152392A1 COMPOSITION INCLUDING A POLYHETEROSILOXANE AND AN ORGANOSILOXANE BLOCK COPOLYMER 审中-公开
标题翻译：组合物，包括聚硅氧烷和有机硅氧烷嵌段共聚物
公开(公告)号：WO2014152392A1
公开(公告)日：2014-09-25
申请号：PCT/US2014/027290
申请日：2014-03-14
申请人： DOW CORNING CORPORATION
发明人： DESHAZER, David , GRASMANN, Martin , HORSTMAN, John, B. , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn , SCHMIDT, Randall , SKINNER, Kwan , SWIER, Steven
IPC分类号： C08G77/58 , C08L83/14 , C08L83/04 , C08G77/00 , C08G77/04
CPC分类号： C08G77/58 , C08G77/70 , C08L83/14
摘要： A composition includes a combination of a (I) polyheterosiloxane composition and a (II) organosiloxane block copolymer. The (I) polyheterosiloxane composition includes at least one lanthanide metal and siloxy units having the formula (R 1 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 SiO 3/2 ), and/or (SiO 4/2 ). Each R 1 is independently a hydrocarbon or halogenated hydrocarbon group comprising 1 to 30 carbon atoms. The (II) organosiloxane block copolymer includes 40 to 90 mole percent dlsiloxy units of the formula [R a 2 SiO 2/2 ] arranged in linear blocks each having an average of from 10 to 400 disiloxy units [R a 2 SiO 2/2 ] per linear block. The (II) organosiloxane block copolymer also includes 10 to 60 mole percent siloxy units arranged in non-linear blocks each having a weight average molecular weight of at least 500 g/mol wherein at least one siloxy unit is a trisiloxy unit of die formula [R b SiO 3/2 ]. R a is independently a C 1 to C 30 hydrocarbyl and R b is independently a C 1 to C 20 hydrocarbyl.
摘要翻译：组合物包括（I）聚醚砜硅氧烷组合物和（II）有机硅氧烷嵌段共聚物的组合。（I）多嵌段硅氧烷组合物包括至少一种镧系元素金属和具有式（R1 3SiO1 / 2），（R1SiO2 / 2），（R1SiO3 / 2）和/或（SiO4 / 2）的甲硅烷氧基单元。每个R 1独立地是含有1至30个碳原子的烃或卤代烃基。（II）有机硅氧烷嵌段共聚物包含40〜90摩尔％的以[R a 2SiO 2/2]为单位的直链嵌段平均每个线性嵌段平均具有10-400个二甲硅烷基单元[Ra 2 SiO 2/2]的式[ （II）有机硅氧烷嵌段共聚物还包括以非直链嵌段排列的重量平均分子量至少为500g / mol的10至60mol％的甲硅烷氧基单元，其中至少一个甲硅烷氧基单元是模具式[ RbSiO3 / 2]。 R a独立地为C 1至C 30烃基，R b独立地为C 1至C 20烃基。

6. 发明申请

WO2014152824A1 POLYHETEROSILOXANE COMPOSITION AND SILICONE COMPOSITION INCLUDING A POLYHETEROSILOXANE 审中-公开
标题翻译：聚硅氧烷组合物和含硅酮组合物，包括聚硅氧烷
公开(公告)号：WO2014152824A1
公开(公告)日：2014-09-25
申请号：PCT/US2014/027892
申请日：2014-03-14
申请人： DOW CORNING CORPORATION
发明人： LIU, Lizhi , DESHAZER, David , GRASMANN, Martin , LIU, Nanguo , SHAHINIAN, Katherine, M.
IPC分类号： C08G77/58 , C08L83/14
CPC分类号： C08G77/58 , C08G77/70 , C08L83/14
摘要： A sensitized polyheterosiloxane composition includes at least one non-lanthanide metal, siloxy units, and a photosensitizer. Each R 1 is independently a hydrocarbon or halogenated hydrocarbon group comprising 1 to 30 carbon atoms. The mole fractions of the at least one non- lanthanide metal and the siloxy units relative to each other is of the formula: [at least one non- lanthanide metal] a [R 1 3 SiO 1/2 ] m [R 1 2 Si0 2/2 ] d [R 1 Si0 3/2 ] t [Si0 4/2 ] q , wherein a is from 0.001 to 0.9, m is from zero to 0.9, d is from zero to 0.9, t is from zero to 0.9, and q is from zero to 0.9, and wherein m, d, t, and q cannot all be zero and the sum of a+m+d+t+q ≈ 1. The photosensitizer is present in an amount of less than 3 moles of photosensitizer per one mole of the at least one non-lanthanide metal. Moreover, the sensitized polyheterosiloxane composition is free of lanthanide metals. A silicone composition includes a curable silicone and the sensitized polyheterosiloxane composition. Moreover, the silicone composition is free of lanthanide metals.
摘要翻译：致敏的聚杂硅氧烷组合物包括至少一种非镧系金属，甲硅烷氧基单元和光敏剂。每个R 1独立地是含有1至30个碳原子的烃或卤代烃基。至少一种非镧系金属和甲硅烷氧基单元相对于彼此的摩尔分数具有下式：[至少一种非镧系元素金属] a [R1 3 SiO 1/2] m [R 1 SiO 2/2] d [ R1SiO3 / 2] t [Si04 / 2] q，其中a为0.001至0.9，m为0至0.9，d为0至0.9，t为0至0.9，q为0至0.9，其中m，d，t和q不能全部为零，并且a + m + d + t + q≈1的总和。光敏剂的存在量为每摩尔至少3摩尔以上的光敏剂一种非镧系金属。此外，致敏的聚杂硅氧烷组合物不含镧系金属。有机硅组合物包括可固化的硅氧烷和敏化的聚杂硅氧烷组合物。此外，硅氧烷组合物不含镧系金属。

7. 发明公开

EP2655482A1 POLYHETEROSILOXANE COMPOSITION INCLUDING LANTHANIDE METAL 审中-公开
标题翻译：包含稀土金属的聚硅氧烷组合物
公开(公告)号：EP2655482A1
公开(公告)日：2013-10-30
申请号：EP11810762.2
申请日：2011-12-22
申请人： Dow Corning Corporation
发明人： DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn, Keith , SCHMIDT, Randall
IPC分类号： C08G77/58
CPC分类号： C09K11/06 , C08G77/58 , C08L83/04
摘要： A polyheterosiloxane composition includes (A) a first metal (M1), (B) a second metal (M2), and (C) siloxy units having the formula (R13SiO1/2), (R12SiO2/2), (R1SiO3/2), and/or (S1O4/2). R1 is independently a hydrocarbon or halogenated hydrocarbon group including 1 to 30 carbon atoms. The mole fractions of (A), (B), and (C) relative to each other is of the formula [(M1)]a[(M2)]b[R13SiO1/2]m[R12SiO2/2]d[R1SiO3/2]t[SiO4/2]q, wherein a and b are each independently from 0.001 to 0.9, each of m, d, t, and q are independently from zero to 0.9 so long as m, d, t, and q are not all zero and the sum of a+b+m+d+t+q≈1. At least one of (M1) and (M2) is a lanthanide metal. The composition exhibits a quantum yield of at least 0.05% and is formed using a method including reacting (A') a metal (M3) alkoxide, (B') an optional hydrolyzable metal (M4) salt, (C') a silicon-containing material and (D) water.
摘要翻译：（A）第一金属（M1），（B）第二金属（M2）和（C）具有式（R 13 SiO 1/2），（R 12 SiO 2/2），（R 1 SiO 3/2），和/或（S1O4 / 2）。 R 1独立地为包含1至30个碳原子的烃或卤代烃基。（A），（B）和（C）相对于彼此的摩尔分数为式[（M1）] a [（M2）] b [R13SiO1 / 2] m [R12SiO2 / 2] d [R1SiO3 / 2] t [SiO 4/2] q，其中a和b各自独立地为0.001至0.9，m，d，t和q各自独立地为0至0.9，只要m，d，t和q 并非全部为零并且a + b + m + d + t + q＆ap; 1的总和。（M1）和（M2）中的至少一个是镧系金属。（A'）金属（M3）醇盐，（B'）任选的可水解金属（M4）盐，（C'）硅 - 含有物质和（D）水。

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