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1. 发明申请

WO2014022377A1 MEMBRANES AND COATINGS MADE FROM MIXTURES INCLUDING IONIC LIQUIDS HAVING SILICON-BONDED HYDROLYZABLE GROUPS 审中-公开
标题翻译：混合物中的膜和涂层，包括具有硅键合的可水解组的离子液体
公开(公告)号：WO2014022377A1
公开(公告)日：2014-02-06
申请号：PCT/US2013/052701
申请日：2013-07-30
申请人： DOW CORNING CORPORATION
发明人： LU, Gang
IPC分类号： B01D53/14 , B01D71/70 , C08J3/075 , C08G77/26 , C08G77/28 , C08G77/30 , C08L83/04
CPC分类号： C09D183/08 , B01D53/228 , B01D71/70 , B01D2256/245 , B01D2257/504 , B01D2258/0283 , B01D2258/05 , C08G77/26 , C08G77/28 , C08G77/30 , C08J3/212 , C08J2383/00 , Y02C10/10 , Y02P20/152
摘要： The present invention relates to silicone compositions made from mixtures including ionic liquids having hydrolysable silyl groups. In various embodiments, the present invention provides a method of preparing a silicone composition, the method including reacting a mixture in a water-miscible solvent in the presence of a condensation catalyst to form a sol, concentrating the sol to form a wet gel, and drying the wet gel to form a silicone composition; the mixture including (a) an ionic liquid; optionally, (b) a silane; optionally, (c) a polysiloxane cross-linking agent; optionally, (d) a polydiorganosiloxane; and (e) water; wherein at least one of optional elements (b) and (c) is included in the mixture. In various embodiments, the present invention provides silicone compositions made by the method, membranes and coated substrates including the silicone composition, including supported and unsupported membranes, methods of making the membranes and coated substrates, and methods of using the membranes and coated substrates.
摘要翻译：本发明涉及由包含具有可水解甲硅烷基的离子液体的混合物制成的硅氧烷组合物。在各种实施方案中，本发明提供一种制备硅氧烷组合物的方法，所述方法包括在缩合催化剂存在下使水混溶性溶剂中的混合物反应形成溶胶，将溶胶浓缩以形成湿凝胶，以及干燥湿凝胶以形成硅氧烷组合物; 该混合物包括（a）离子液体; （b）硅烷; （c）聚硅氧烷交联剂; （d）聚二有机硅氧烷; 和（e）水; 其中选择性元素（b）和（c）中的至少一种包含在混合物中。在各种实施方案中，本发明提供了通过该方法制备的硅氧烷组合物，包括硅氧烷组合物的膜和涂覆的基材，包括负载和未负载的膜，制备膜和涂覆的基材的方法，以及使用膜和涂覆的基材的方法。

2. 发明申请

WO2010014537A1 RADICAL POLYMERIZABLE COMPOSITION 审中-公开
标题翻译：辐射可聚合组合物
公开(公告)号：WO2010014537A1
公开(公告)日：2010-02-04
申请号：PCT/US2009/051829
申请日：2009-07-27
申请人： DOW CORNING CORPORATION , AHN, Dongchan , LU, Gang
发明人： AHN, Dongchan , LU, Gang
IPC分类号： C07F5/02 , C08F4/52 , C08F220/00 , C08K5/55
CPC分类号： C09D4/00 , C08F4/52 , C08K5/55 , Y10T428/31935
摘要： A radical polymerizable composition includes a radical polymerizable compound and an organoborane-azole complex. The organoborane-azole complex includes an azole having at least two nitrogen atoms wherein at least one nitrogen atom is an sp 3 nitrogen atom and is substituted. A method of forming the composition includes the step of combining the radical polymerizable compound and the organoborane-azole complex to form the composition. The method also includes the step of polymerizing the composition. A composite article which includes a substrate and a cured composition disposed on the substrate is also provided. The cured composition is formed from polymerization of the composition.
摘要翻译：可自由基聚合的组合物包括自由基聚合性化合物和有机硼烷 - 唑类络合物。有机硼烷 - 唑类配合物包括具有至少两个氮原子的唑，其中至少一个氮原子是sp 3氮原子并被取代。形成组合物的方法包括将自由基聚合性化合物和有机硼烷 - 唑类复合物组合以形成组合物的步骤。该方法还包括使组合物聚合的步骤。还提供了一种复合制品，其包括基材和设置在基材上的固化组合物。固化的组合物由组合物的聚合形成。

3. 发明申请

WO2013192404A1 POLYHETEROSILOXANE COMPOSITION 审中-公开
标题翻译：聚硅氧烷组合物
公开(公告)号：WO2013192404A1
公开(公告)日：2013-12-27
申请号：PCT/US2013/046784
申请日：2013-06-20
申请人： DOW CORNING CORPORATION
发明人： DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn , SCHMIDT, Randall , SHAHINIAN, Katherine, Marie , SKINNER, Kwan , LU, Gang , CHOI, Jongwook
IPC分类号： C08G77/58 , C08L83/14
CPC分类号： C08G77/58 , C08L83/14
摘要： A polyheterosiloxane composition includes (A) a first metal (M1), (B) a second metal (M2), and (C) siloxy units having the formula (R 1 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 SiO 3/2 ), and/or (SiO 4/2 ). Each R 1 is independently a hydrocarbon or halogenated hydrocarbon group including 1 to 30 carbon atoms. The mole fractions of (A), (B), and (C) relative to each other is of the formula [(M1)] a [(M2)] b [R 1 3 SiO 1/2 ] m [R 1 2 SiO 2/2 ] d [R 1 SiO 3/2 ] t [SiO 4/2 ] q , wherein a and b are each independently from 0.001 to 0.9, m, d, t, and q are each independently from zero to 0.9, m, d, t, and q cannot all be zero, and the sum of a+b+m+d+t+q ≈ 1. At least one oxygen atom of the siloxy units is bonded to at least one of (M1) and/or (M2). The composition exhibits a quantum yield of at least 0.05% and at least one of (M1) and (M2) is a lanthanide metal.
摘要翻译：聚硅氧烷组合物包括（A）第一金属（M1），（B）第二金属（M2）和（C）具有式（R1 3SiO1 / 2），（R1SiO2 / 2），（R1SiO3 / 2），和/或（SiO 4/2）。每个R 1独立地是含有1至30个碳原子的烃或卤代烃基。（A），（B）和（C）相对于彼此的摩尔分数为式[（M1）] a [（M2）] b [R1 3SiO1 / 2] m [R1 2SiO2 / 2] d [R1SiO3 / 2] t [SiO4 / 2] q，其中a和b各自独立地为0.001至0.9，m，d，t和q各自独立地为0至0.9，m，d，t和q不能全部为零，并且a + b + m + d + t + q≈1的和。所述甲硅烷氧基单元的至少一个氧原子键合到（M1）和/或（M2）中的至少一个。该组合物显示至少0.05％的量子产率，并且（M1）和（M2）中的至少一种是镧系金属。

4. 发明申请

WO2013070912A1 SYNTHESIS OF SILICONE IONOMER MEMBRANES AND THE USE THEREOF 审中-公开
标题翻译：硅胶离子膜的合成及其用途
公开(公告)号：WO2013070912A1
公开(公告)日：2013-05-16
申请号：PCT/US2012/064146
申请日：2012-11-08
申请人： DOW CORNING CORPORATION
发明人： LU, Gang
IPC分类号： B01D67/00 , B01D69/14 , C08L83/04
CPC分类号： B01D67/0079 , B01D67/0006 , B01D69/148 , B01D71/70 , B01D2323/30 , B01D2323/34 , C08G77/20 , C08K5/0025 , C08K5/098 , C08K5/14 , C08L83/04
摘要： The present invention relates to membranes and methods of making and using the same. In some examples, the membrane can be supported or unsupported. The membrane includes a cured product of a modified silicone composition. The modified silicone composition includes (A) a curable silicone composition. The modified silicone composition also includes (B) a salt of a carboxylic acid.
摘要翻译：本发明涉及膜及其制造和使用方法。在一些实例中，膜可以被支撑或不支撑。膜包括改性有机硅组合物的固化产物。改性有机硅组合物包括（A）可固化的有机硅组合物。改性有机硅组合物还包括（B）羧酸的盐。

5. 发明申请

WO2014059132A2 MEMBRANES INCLUDING POLYSILOXANE-POLY(ALKYLENE OXIDE) COPOLYMERS AND METHODS OF USING THE SAME 审中-公开
标题翻译：包含多羟基聚（亚烷基氧化物）共聚物的膜及其使用方法
公开(公告)号：WO2014059132A2
公开(公告)日：2014-04-17
申请号：PCT/US2013/064318
申请日：2013-10-10
申请人： DOW CORNING CORPORATION
发明人： LU, Gang , GREINER, Aaron J. , AHN, Dongchan , MCQUISTON, Elizabeth , WIER, Kevin A. , PANDIT, Vinita , GIBSON, Gary
IPC分类号： B01D71/52
CPC分类号： B01D53/228 , B01D71/52 , B01D71/70 , B01D71/76 , B01D71/80 , B01D71/82 , C08G77/46 , C08L83/12 , Y02C10/10
摘要： The present invention provides membranes including a cured product of a silicone composition. The silicone composition includes a silicone-polyether copolymer having curable silicon-bonded groups. The membrane is either unsupported or supported on a porous substrate. The present invention also provides methods of using the membranes, including methods of using the membranes for separation of gases such as, for example, carbon dioxide from mixtures including carbon dioxide and methane.
摘要翻译：本发明提供了包括硅氧烷组合物的固化产物的膜。硅氧烷组合物包括具有可固化的硅键合基团的硅氧烷 - 聚醚共聚物。膜是无支撑的或支撑在多孔基底上。本发明还提供了使用膜的方法，包括使用膜分离气体的方法，例如来自包括二氧化碳和甲烷的混合物的二氧化碳。

6. 发明申请

WO2013096211A1 SILICONE-BASED IONIC LIQUIDS AND APPLICATIONS THEREOF 审中-公开
标题翻译：基于硅酮的离子液体及其应用
公开(公告)号：WO2013096211A1
公开(公告)日：2013-06-27
申请号：PCT/US2012/070122
申请日：2012-12-17
申请人： DOW CORNING CORPORATION , LU, Gang , AHN, Dongchan , WONG, Christopher
发明人： LU, Gang , AHN, Dongchan , WONG, Christopher
IPC分类号： C08J5/00
CPC分类号： C08G77/388 , B01D53/228 , B01D67/006 , B01D69/10 , B01D71/70 , C08G77/20 , C08G77/395
摘要： The present invention relates to silicone-based ionic liquids and methods of making the same, curable compositions that include the same, materials such as membranes made therefrom, and methods of using those materials. Various embodiments of the present invention provide a curable composition. The curable composition includes Component (A), an organic compound having at least one free-radical polymerizable group per molecule. The curable composition also includes Component (B), a mercapto-functional organic compound having an average of at least about three mercapto groups per molecule. The curable composition also includes Component (C), a polysiloxane having an average of at least about one phosphonium groups or ammonium groups per molecule, wherein the polysiloxane has an average of at least about five Si atoms per molecule. Additionally, the curable composition includes a catalytic amount of a free-radical initiator. In some embodiments, the present invention provides a cured product of the curable composition, a supported or unsupported membrane comprising the cured product, and a method of separating gas components in a feed gas mixture using the membrane.
摘要翻译：本发明涉及基于硅酮的离子液体及其制备方法，包括其的可固化组合物，由其制成的材料，以及使用这些材料的方法。本发明的各种实施方案提供可固化组合物。可固化组合物包括组分（A），每分子具有至少一个自由基可聚合基团的有机化合物。可固化组合物还包括组分（B），每分子平均具有至少约三个巯基的巯基官能的有机化合物。可固化组合物还包括组分（C），每分子平均具有至少约一个鏻基团或铵基团的聚硅氧烷，其中聚硅氧烷平均每分子具有至少约五个Si原子。另外，可固化组合物包括催化量的自由基引发剂。在一些实施方案中，本发明提供可固化组合物的固化产物，包含固化产物的负载或未负载的膜，以及使用该膜分离进料气体混合物中的气体组分的方法。

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