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1. 发明申请

WO2013192404A1 POLYHETEROSILOXANE COMPOSITION 审中-公开
标题翻译：聚硅氧烷组合物
公开(公告)号：WO2013192404A1
公开(公告)日：2013-12-27
申请号：PCT/US2013/046784
申请日：2013-06-20
申请人： DOW CORNING CORPORATION
发明人： DESHAZER, David , GRASMANN, Martin , LIU, Lizhi , LIU, Nanguo , MCQUISTON, Elizabeth , MEALEY, Shawn , SCHMIDT, Randall , SHAHINIAN, Katherine, Marie , SKINNER, Kwan , LU, Gang , CHOI, Jongwook
IPC分类号： C08G77/58 , C08L83/14
CPC分类号： C08G77/58 , C08L83/14
摘要： A polyheterosiloxane composition includes (A) a first metal (M1), (B) a second metal (M2), and (C) siloxy units having the formula (R 1 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 SiO 3/2 ), and/or (SiO 4/2 ). Each R 1 is independently a hydrocarbon or halogenated hydrocarbon group including 1 to 30 carbon atoms. The mole fractions of (A), (B), and (C) relative to each other is of the formula [(M1)] a [(M2)] b [R 1 3 SiO 1/2 ] m [R 1 2 SiO 2/2 ] d [R 1 SiO 3/2 ] t [SiO 4/2 ] q , wherein a and b are each independently from 0.001 to 0.9, m, d, t, and q are each independently from zero to 0.9, m, d, t, and q cannot all be zero, and the sum of a+b+m+d+t+q ≈ 1. At least one oxygen atom of the siloxy units is bonded to at least one of (M1) and/or (M2). The composition exhibits a quantum yield of at least 0.05% and at least one of (M1) and (M2) is a lanthanide metal.
摘要翻译：聚硅氧烷组合物包括（A）第一金属（M1），（B）第二金属（M2）和（C）具有式（R1 3SiO1 / 2），（R1SiO2 / 2），（R1SiO3 / 2），和/或（SiO 4/2）。每个R 1独立地是含有1至30个碳原子的烃或卤代烃基。（A），（B）和（C）相对于彼此的摩尔分数为式[（M1）] a [（M2）] b [R1 3SiO1 / 2] m [R1 2SiO2 / 2] d [R1SiO3 / 2] t [SiO4 / 2] q，其中a和b各自独立地为0.001至0.9，m，d，t和q各自独立地为0至0.9，m，d，t和q不能全部为零，并且a + b + m + d + t + q≈1的和。所述甲硅烷氧基单元的至少一个氧原子键合到（M1）和/或（M2）中的至少一个。该组合物显示至少0.05％的量子产率，并且（M1）和（M2）中的至少一种是镧系金属。

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