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    • 2. 发明申请
    • COMPOSITION INCLUDING A POLYHETEROSILOXANE AND AN ORGANOSILOXANE BLOCK COPOLYMER
    • 组合物,包括聚硅氧烷和有机硅氧烷嵌段共聚物
    • WO2014152392A1
    • 2014-09-25
    • PCT/US2014/027290
    • 2014-03-14
    • DOW CORNING CORPORATION
    • DESHAZER, DavidGRASMANN, MartinHORSTMAN, John, B.LIU, LizhiLIU, NanguoMCQUISTON, ElizabethMEALEY, ShawnSCHMIDT, RandallSKINNER, KwanSWIER, Steven
    • C08G77/58C08L83/14C08L83/04C08G77/00C08G77/04
    • C08G77/58C08G77/70C08L83/14
    • A composition includes a combination of a (I) polyheterosiloxane composition and a (II) organosiloxane block copolymer. The (I) polyheterosiloxane composition includes at least one lanthanide metal and siloxy units having the formula (R 1 3 SiO 1/2 ), (R 1 2 SiO 2/2 ), (R 1 SiO 3/2 ), and/or (SiO 4/2 ). Each R 1 is independently a hydrocarbon or halogenated hydrocarbon group comprising 1 to 30 carbon atoms. The (II) organosiloxane block copolymer includes 40 to 90 mole percent dlsiloxy units of the formula [R a 2 SiO 2/2 ] arranged in linear blocks each having an average of from 10 to 400 disiloxy units [R a 2 SiO 2/2 ] per linear block. The (II) organosiloxane block copolymer also includes 10 to 60 mole percent siloxy units arranged in non-linear blocks each having a weight average molecular weight of at least 500 g/mol wherein at least one siloxy unit is a trisiloxy unit of die formula [R b SiO 3/2 ]. R a is independently a C 1 to C 30 hydrocarbyl and R b is independently a C 1 to C 20 hydrocarbyl.
    • 组合物包括(I)聚醚砜硅氧烷组合物和(II)有机硅氧烷嵌段共聚物的组合。 (I)多嵌段硅氧烷组合物包括至少一种镧系元素金属和具有式(R1 3SiO1 / 2),(R1SiO2 / 2),(R1SiO3 / 2)和/或(SiO4 / 2)的甲硅烷氧基单元。 每个R 1独立地是含有1至30个碳原子的烃或卤代烃基。 (II)有机硅氧烷嵌段共聚物包含40〜90摩尔%的以[R a 2SiO 2/2]为单位的直链嵌段平均每个线性嵌段平均具有10-400个二甲硅烷基单元[Ra 2 SiO 2/2]的式[ (II)有机硅氧烷嵌段共聚物还包括以非直链嵌段排列的重量平均分子量至少为500g / mol的10至60mol%的甲硅烷氧基单元,其中至少一个甲硅烷氧基单元是模具式[ RbSiO3 / 2]。 R a独立地为C 1至C 30烃基,R b独立地为C 1至C 20烃基。