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1. 发明授权

US08981041B2 Production process of poly(arylene sulfide) and production apparatus thereof 有权
标题翻译：聚（亚芳基硫醚）的生产工艺及其生产设备
公开(公告)号：US08981041B2
公开(公告)日：2015-03-17
申请号：US13809505
申请日：2011-07-06
申请人： Takayuki Kimura , Tomoyoshi Koizumi , Mitsuhiro Matsuzaki
发明人： Takayuki Kimura , Tomoyoshi Koizumi , Mitsuhiro Matsuzaki
IPC分类号： C08G75/14 , C08G75/02
CPC分类号： C08G75/14 , C08G75/0213 , C08G75/0254 , C08G75/0259 , C08G75/0281
摘要： A production process of a poly(arylene sulfide) (PAS), including a polymerization step of forming a PAS from a sulfur source that is an alkali metal (hydro)sulfides and a dihalo-aromatic compound in an organic amide solvent; a separation step of PAS particles; a countercurrent washing step that is a step of washing the PAS particles with water and/or an organic solvent, wherein a downward current of a PAS particle-containing aqueous slurry is continuously brought into countercurrent contact with an upward current of a washing liquid; a PAS particle re-separation step of capturing a washing waste liquid by a PAS particle re-separating unit, in which a micro-slit filter has been installed, and then re-separating the PAS particles from the micro-slit filter, preferably using a backwashing unit, to discharge them; and a collecting step of the PAS particles discharged, and a production apparatus of a poly(arylene sulfide).
摘要翻译：一种聚（亚芳基硫醚）（PAS）的生产方法，包括在有机酰胺溶剂中由作为碱金属（氢）硫化物的硫源和二卤代芳族化合物形成PAS的聚合步骤; PAS颗粒的分离步骤; 逆流洗涤步骤，其是用水和/或有机溶剂洗涤PAS颗粒的步骤，其中含有PAS颗粒的含水浆料的向下电流连续地与洗涤液的向上流动接触; PAS粒子重新分离步骤，其中已经安装了微缝隙过滤器的PAS粒子重新分离单元捕获洗涤废液，然后从微缝隙过滤器重新分离PAS颗粒，优选使用反冲洗单元，以排放它们; 以及排出的PAS颗粒的收集步骤和聚（亚芳基硫醚）的生产装置。

2. 发明授权

US08211997B2 Process for producing polyarylene sulfide 有权
标题翻译：生产聚芳硫醚的方法
公开(公告)号：US08211997B2
公开(公告)日：2012-07-03
申请号：US11661753
申请日：2005-08-31
申请人： Mitsuhiro Matsuzaki , Katsumi Horikoshi , Masanori Kobayashi
发明人： Mitsuhiro Matsuzaki , Katsumi Horikoshi , Masanori Kobayashi
IPC分类号： C08G75/00
CPC分类号： C08G75/0254 , C08G75/02
摘要： In a process for producing polyarylene sulfide, comprising: reacting an alkali sulfide source and an aromatic dihalide compound in a polar organic solvent to obtain a polymerizate slurry containing polyarylene sulfide particles, by-produced alkali metal salt fine particles and the polar organic solvent, and recovering the polyarylene sulfide particles washed from the polymerizate slurry; the polymerizate slurry is separated by sieving into the polyarylene sulfide particles and a slurry containing the alkali metal salt fine particles, and the separated polyarylene sulfide particles are subjected to a washing step wherein the polyarylene sulfides are introduced into a countercurrent washing apparatus enclosing a movable part and subjected therein to continuous countercurrent contact with a washing liquid. As a result, polyarylene sulfide particles of good quality are produced at a good yield, while pursuing process rationalization.
摘要翻译：在制备聚芳硫醚的方法中，包括：将碱金属硫化物源和芳族二卤化物在极性有机溶剂中反应，得到含有聚芳硫醚颗粒，副产的碱金属盐微粒和极性有机溶剂的聚合物淤浆，以及回收从聚合物浆料洗涤的聚芳硫醚颗粒; 将聚合物浆料通过筛分分离成聚芳硫醚颗粒和含有碱金属盐微粒的浆料，并将分离的聚芳硫醚颗粒进行洗涤步骤，其中将聚亚芳基硫化物引入到包围可动部分的逆流洗涤装置中并与其进行与洗涤液的连续逆流接触。结果，在追求工艺合理化的同时，以良好的产率生产质量好的聚芳硫醚颗粒。

3. 发明授权

US08058320B2 Thermally foamable microsphere, production method thereof, use thereof, composition containing the same, and article 有权
标题翻译：热发泡性微球，其制造方法，其用途，含有它们的组合物和制品
公开(公告)号：US08058320B2
公开(公告)日：2011-11-15
申请号：US11662658
申请日：2005-09-13
申请人： Tetsuo Ejiri , Mitsuhiro Matsuzaki , Shunzo Endo
发明人： Tetsuo Ejiri , Mitsuhiro Matsuzaki , Shunzo Endo
IPC分类号： C08J9/16 , C08J9/22 , C08J9/18
CPC分类号： B01J13/14
摘要： A thermally foamable microsphere having a structure that a foaming agent is encapsulated in an outer shell formed from a polymer, wherein the foaming agent contains isododecane, and a production process of the thermally foamable microsphere by a suspension polymerization process using a polymerizable monomer and a foaming agent containing dodecane.
摘要翻译：一种热发泡性微球，其具有发泡剂封装在由聚合物形成的外壳中的结构，其中发泡剂含有异十二烷，并且通过使用可聚合单体的悬浮聚合方法和发泡性微球的制备方法含有十二烷的试剂。

4. 发明申请

US20090156780A1 Poly (Arylene Sulfide) and Production Process Thereof 有权
标题翻译：聚（亚硫酰亚胺）及其制备方法
公开(公告)号：US20090156780A1
公开(公告)日：2009-06-18
申请号：US12370201
申请日：2009-02-12
申请人： Hirohito Kawama , Mitsuhiro Matsuzaki , Michihisa Miyahara , Koichi Suzuki , Hiroyuki Sato
发明人： Hirohito Kawama , Mitsuhiro Matsuzaki , Michihisa Miyahara , Koichi Suzuki , Hiroyuki Sato
IPC分类号： C08G75/14
CPC分类号： C08G75/0259
摘要： A dehydration step is conducted by heating a mixture containing an organic amide solvent and a sulfur source including an alkali metal hydrosulfide, and a part of an overall charged amount of an alkali metal hydroxide as needed. The mixture remaining within the system after the dehydration step is mixed with a dihalo-aromatic compound, the resultant mixture is heated to conduct a polymerization reaction, and the alkali metal hydroxide is added to the mixture for polymerization reaction continuously or in portions to control the pH of the mixture for polymerization reaction within a range of from 7 to 12.5 from the beginning to the end of the polymerization reaction. The poly(arylene sulfide) according to the present invention has a nitrogen content of at most 800 ppm.
摘要翻译：通过根据需要加热含有有机酰胺溶剂和包含碱金属氢硫化物的硫源的混合物和总量的碱金属氢氧化物的一部分来进行脱水步骤。将脱水步骤后残留在体系内的混合物与二卤代芳族化合物混合，加热所得混合物进行聚合反应，并将碱金属氢氧化物连续地或部分加入到混合物中用于聚合反应，以控制从聚合反应的开始到结束，聚合反应的混合物的pH在7至12.5的范围内。本发明的聚（亚芳基硫醚）的氮含量为800ppm以下。

5. 发明申请

US20080097075A1 Process for Producing Polyarylene Sulfide 有权
标题翻译：生产聚亚芳基硫化物的方法
公开(公告)号：US20080097075A1
公开(公告)日：2008-04-24
申请号：US11661753
申请日：2005-08-31
申请人： Mitsuhiro Matsuzaki , Katsumi Horikoshi , Masanori Kobayashi
发明人： Mitsuhiro Matsuzaki , Katsumi Horikoshi , Masanori Kobayashi
IPC分类号： C08G75/14
CPC分类号： C08G75/0254 , C08G75/02
摘要： In a process for producing polyarylene sulfide, comprising: reacting an alkali sulfide source and an aromatic dihalide compound in a polar organic solvent to obtain a polymerizate slurry containing polyarylene sulfide particles, by-produced alkali metal salt fine particles and the polar organic solvent, and recovering the polyarylene sulfide particles washed from the polymerizate slurry; the polymerizate slurry is separated by sieving into the polyarylene sulfide particles and a slurry containing the alkali metal salt fine particles, and the separated polyarylene sulfide particles are subjected to a washing step wherein the polyarylene sulfides are introduced into a countercurrent washing apparatus enclosing a movable part and subjected therein to continuous countercurrent contact with a washing liquid. As a result, polyarylene sulfide particles of good quality are produced at a good yield, while pursuing process rationalization.
摘要翻译：在制备聚芳硫醚的方法中，包括：将碱金属硫化物源和芳族二卤化物在极性有机溶剂中反应，得到含有聚芳硫醚颗粒，副产的碱金属盐微粒和极性有机溶剂的聚合物淤浆，以及回收从聚合物浆料洗涤的聚芳硫醚颗粒; 将聚合物浆料通过筛分分离成聚芳硫醚颗粒和含有碱金属盐微粒的浆料，并将分离的聚芳硫醚颗粒进行洗涤步骤，其中将聚亚芳基硫化物引入到包围可动部分的逆流洗涤装置中并与其进行与洗涤液的连续逆流接触。结果，在追求工艺合理化的同时，以良好的产率生产质量好的聚芳硫醚颗粒。

6. 发明授权

US07220817B2 Process for producing polyarylene sulfide 有权
标题翻译：生产聚芳硫醚的方法
公开(公告)号：US07220817B2
公开(公告)日：2007-05-22
申请号：US10520620
申请日：2003-07-11
申请人： Mitsuhiro Matsuzaki , Masaru Kagoshima
发明人： Mitsuhiro Matsuzaki , Masaru Kagoshima
IPC分类号： C08G75/00 , C08G75/14
CPC分类号： C08G75/0254 , C08G75/0213 , C08G75/0281
摘要： A process for producing polyarylene sulfide includes: steps of reacting an aromatic dihalide compound and an alkaline metal compound in a polar organic solvent for polymerization under heating and cooling a system including the reaction mixture to recover particulate polyarylene sulfide (PAS). The system after the reaction is gradually cooled at an average cooling speed of 0.2 to 1.0 deg. C./min. selectively in a temperature range of from 1 deg. C. below to 1 deg. C. above a maximum system-viscosity temperature. As a result, the process can be operated at a relatively short polymerization cycle and yet provides the product PAS particles with a high and stable bulk density as to exhibit good processability in the transportation and storage, and excellent transportability in a hopper or a screw of an extruder or a molding machine.
摘要翻译：制备聚芳硫醚的方法包括：在极性有机溶剂中使芳族二卤化物和碱金属化合物在加热和冷却包括反应混合物的体系进行聚合反应以回收颗粒状聚芳硫醚（PAS）的步骤。反应后的体系以0.2〜1.0度的平均冷却速度逐渐冷却。 C./min。选择性地在1度的温度范围内。 C.低于1度 C.高于最大系统粘度温度。因此，该方法可以在相对较短的聚合循环下操作，并且为产品PAS颗粒提供高且稳定的堆积密度，以便在运输和储存中表现出良好的加工性，并且在料斗或螺杆中具有良好的可运输性挤出机或成型机。

7. 发明授权

US06540473B2 Robot vehicle for hot-line job 失效
标题翻译：机器人车辆用于热线工作
公开(公告)号：US06540473B2
公开(公告)日：2003-04-01
申请号：US09880317
申请日：2001-06-13
申请人： Hirofumi Inokuchi , Toshihide Tomiyama , Yoshihiro Yurita , Shinji Murai , Yusuke Hirano , Shinji Harada , Kengo Tsuruta , Youichi Motomura , Kazutoshi Imai , Yoshiaki Haga , Yoshikatsu Nakamura , Yukio Hashiguchi , Mitsuhiro Matsuzaki , Hiromichi Yamada , Akihiko Mishima , Yoshinaga Maruyama , Kyoji Yano , Moriyuki Nakashima , Osamu Yamashita
发明人： Hirofumi Inokuchi , Toshihide Tomiyama , Yoshihiro Yurita , Shinji Murai , Yusuke Hirano , Shinji Harada , Kengo Tsuruta , Youichi Motomura , Kazutoshi Imai , Yoshiaki Haga , Yoshikatsu Nakamura , Yukio Hashiguchi , Mitsuhiro Matsuzaki , Hiromichi Yamada , Akihiko Mishima , Yoshinaga Maruyama , Kyoji Yano , Moriyuki Nakashima , Osamu Yamashita
IPC分类号： B65G100
CPC分类号： B25J5/06 , B25J9/0084 , B25J15/04 , B66F11/046 , H02G1/02 , Y10T483/15
摘要： A robot vehicle for hot-line job for transmission and distribution lines which comprises an insulating boom formed of an insulating material at a tip end stage of multiple stage booms, a base end of which is supported on an elevated work vehicle to be capable of swinging, pivoting up and down, and extending and contracting, and a frame provided on the tip end of the insulating boom, the frame mounting thereon double arm manipulators of multishaft construction for performing a distribution work, a slide device for sliding independently these right and left double arm manipulators front to rear, and lifting arms of multishaft construction having a function of lifting a heavy article, so as to allow an operator to perform remote control. An electric actuator is used for driving the double arm manipulators and the slide device, and hydraulic manipulators for driving the lifting arms. Accordingly, a robot vehicle for hot-line job is provided to mount thereon a third arm which enables highly accurate positioning of the manipulators, remote control by an operator and automatic operation through a teaching-playback, has a function of lifting a heavy article, and is small-sized and lightweight.
摘要翻译：一种用于输配电线路的热线工作的机器人车辆，其包括由多级起重臂的末端阶段由绝缘材料形成的绝缘臂，其基端支撑在升高的作业车辆上以能够摆动，上下摆动和伸缩，以及设置在绝缘吊杆末端的框架，框架上安装有用于进行分配工作的多层结构的双臂操纵器，用于独立地左右滑动的滑动装置从前到后的双臂操纵器以及具有抬起重物品的功能的多层结构的提升臂，以允许操作者进行远程控制。电动执行器用于驱动双臂操纵器和滑动装置，以及用于驱动提升臂的液压操纵器。因此，提供了一种用于热线作业的机器人车辆，其上安装有能够高精度地定位操纵器的第三臂，通过操作者的遥控和通过教学重放的自动操作具有提起重物品的功能，并且体积小巧轻便。

8. 发明授权

US06325749B1 Robot vehicle for hot-line job 失效
标题翻译：机器人车辆用于热线工作
公开(公告)号：US06325749B1
公开(公告)日：2001-12-04
申请号：US09284674
申请日：1999-05-17
申请人： Hirofumi Inokuchi , Toshihide Tomiyama , Yoshihiro Yurita , Shinji Murai , Yusuke Hirano , Shinji Harada , Kengo Tsuruta , Youichi Motomura , Kazutoshi Imai , Yoshiaki Haga , Yoshikatsu Nakamura , Yukio Hashiguchi , Mitsuhiro Matsuzaki , Hiromichi Yamada , Akihiko Mishima , Yoshinaga Maruyama , Kyoji Yano , Moriyuki Nakashima , Osamu Yamashita
发明人： Hirofumi Inokuchi , Toshihide Tomiyama , Yoshihiro Yurita , Shinji Murai , Yusuke Hirano , Shinji Harada , Kengo Tsuruta , Youichi Motomura , Kazutoshi Imai , Yoshiaki Haga , Yoshikatsu Nakamura , Yukio Hashiguchi , Mitsuhiro Matsuzaki , Hiromichi Yamada , Akihiko Mishima , Yoshinaga Maruyama , Kyoji Yano , Moriyuki Nakashima , Osamu Yamashita
IPC分类号： B23Q3155
CPC分类号： B25J5/06 , B25J9/0084 , B25J15/04 , B66F11/046 , H02G1/02 , Y10T483/15
摘要： A robot vehicle for hot-line job for transmission and distribution lines which comprises an insulating boom formed of an insulating material at a tip end stage of multiple stage booms, a base end of which is supported on an elevated work vehicle to be capable of swinging, pivoting up and down, and extending and contracting, and a frame provided on the tip end of the insulating boom, the frame mounting thereon double arm manipulators of multishaft construction for performing a distribution work, a slide device for sliding independently these right and left double arm manipulators front to rear, and lifting arms of multishaft construction having a function of lifting a heavy article, so as to allow an operator to perform remote control. An electric actuator is used for driving the double arm manipulators and the slide device, and hydraulic manipulators for driving the lifting arms. Accordingly, a robot vehicle for hot-line job is provided to mount thereon a third arm which enables highly accurate positioning of the manipulators, remote control by an operator and automatic operation through a teaching-playback, has a function of lifting a heavy article, and is small-sized and lightweight.
摘要翻译：一种用于输配电线路的热线工作的机器人车辆，其包括由多级起重臂的末端阶段由绝缘材料形成的绝缘臂，其基端支撑在升高的作业车辆上以能够摆动，上下摆动和伸缩，以及设置在绝缘吊杆末端的框架，框架上安装有用于进行分配工作的多层结构的双臂操纵器，用于独立地左右滑动的滑动装置从前到后的双臂操纵器以及具有抬起重物品的功能的多层结构的提升臂，以允许操作者进行远程控制。电动执行器用于驱动双臂操纵器和滑动装置，以及用于驱动提升臂的液压操纵器。因此，提供了一种用于热线作业的机器人车辆，其上安装有能够高精度地定位操纵器的第三臂，通过操作者的遥控和通过教学重放的自动操作具有提起重物品的功能，并且体积小巧轻便。

9. 发明申请

US20130065054A1 Process for Producing Poly(Arylene Sulfide), and Poly(Arylene Sulfide) 有权
标题翻译：生产聚（亚硫酰亚胺）和聚（亚硫酰亚胺）的方法
公开(公告)号：US20130065054A1
公开(公告)日：2013-03-14
申请号：US13698600
申请日：2011-04-21
申请人： Yoshihiro Ichinose , Masanori Kobayashi , Tomoyoshi Koizumi , Mitsuhiro Matsuzaki
发明人： Yoshihiro Ichinose , Masanori Kobayashi , Tomoyoshi Koizumi , Mitsuhiro Matsuzaki
IPC分类号： C08G75/16
CPC分类号： C08G75/0254 , C08G75/0213 , C08G75/0259 , C08G75/0281 , Y10T428/2982
摘要： Disclosed is a process for producing poly(arylene sulfide) which includes: a polymerization step of polymerizing a dihalogenated aromatic compound and at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrogen sulfides in an organic amide solvent, preferably in the presence of a phase separating agent; a separation step of separating a polymer from a reaction liquid containing a produced polymer after the polymerization step; a washing step of washing the polymer with a washing liquid that consists of water and/or an organic solvent; and a separated liquid treatment step of bringing both a separated liquid that has been recovered after the separation of the polymer in the separation step and a separated liquid containing a wash waste liquid that has been recovered after the separation of the polymer in the washing step into contact with an alkaline compound. Also disclosed is poly(arylene sulfide).
摘要翻译：公开了一种生产聚（亚芳基硫醚）的方法，其包括：在有机酰胺溶剂中聚合二卤代芳族化合物和至少一种选自碱金属硫化物和碱金属硫化氢的硫源的聚合步骤，优选在相分离剂的存在下; 在聚合步骤之后从含有生成的聚合物的反应液中分离聚合物的分离步骤; 用由水和/或有机溶剂组成的洗涤液洗涤聚合物的洗涤步骤; 以及分离液体处理步骤，在分离步骤中分离聚合物之后已经回收的分离液体和在洗涤步骤中分离聚合物之后已经回收的含有洗涤废液的分离液体进入与碱性化合物接触。还公开了聚（亚芳基硫醚）。

10. 发明申请

US20100060112A1 ENCODER WITH MOTOR 有权
标题翻译：编码器与电机
公开(公告)号：US20100060112A1
公开(公告)日：2010-03-11
申请号：US12538169
申请日：2009-08-10
申请人： Yoshiyuki NAGAMATSU , Mitsuhiro MATSUZAKI , Yukio TSUTSUI , Shirou YOSHIDOMI
发明人： Yoshiyuki NAGAMATSU , Mitsuhiro MATSUZAKI , Yukio TSUTSUI , Shirou YOSHIDOMI
IPC分类号： H02K11/00
CPC分类号： H02K11/22
摘要： With a motor with an encoder of the invention, a stopper gap formed between a stopper formed on an outer circumferential surface of a hub of the encoder and a bearing cover of an anti-load side bracket is set smaller than an encoder gap to prevent that a rotating disk is made contact with a fixed slit even when an excessive force is applied to an output shaft of the motor with the encoder.
摘要翻译：利用具有本发明的编码器的电动机，形成在编码器的轮毂的外周面上的止动件与防负载侧支架的轴承盖之间形成的止动器间隙被设定为小于编码器间隙，以防止即使当用编码器对马达的输出轴施加过大的力时，旋转盘也与固定狭缝接触。

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