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    • 10. 发明申请
    • SEPARATION OF OXYGENATES FROM A HYDROCARBON STREAM
    • 从油气分离器中分离氧气
    • WO02031085A2
    • 2002-04-18
    • PCT/IB2001/001874
    • 2001-10-09
    • C10G21/04C10G21/14C10G53/04
    • C10G21/04
    • This invention relates to a method for separating olefins and paraffins from oxygenates in a liquid hydrocarbon stream containing a high proportion of olefins, paraffins and oxygenates (mainly alcohols). Typically, the hydrocarbon stream is obtained from a Fischer-Tropsch process. The organic counter-solvent has a boiling point which is less than the boiling point of the most volatile alcohol in the hydrocarbon stream. A raffinate from the liquid-liquid extractor is passed to a distillation column. A bottoms product from the distillation column comprises olefins and paraffins, and the overhead product comprising solvents is recycled. An extract from the liquid-liquid extractor is sent to a stripping column, where a bottoms product containing pure alcohol is obtained. The overhead product containing counter-solvent is recycled.
    • 本发明涉及在含有高比例的烯烃,链烷烃和含氧化合物(主要是醇)的液体烃流中从含氧化合物中分离烯烃和链烷烃的方法。 通常,烃流是从费 - 托方法获得的。 有机反溶剂的沸点小于烃流中最易挥发的醇的沸点。 来自液 - 液萃取器的萃余液通入蒸馏塔。 来自蒸馏塔的底部产物包括烯烃和链烷烃,并且包含溶剂的塔顶产物被再循环。 将来自液 - 液萃取器的提取物送到汽提塔,其中得到含有纯醇的底部产物。 含有反溶剂的塔顶产物被回收利用。