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    • 2. 发明申请
    • PROCESS FOR THE PRODUCTION OF POLY(BUTYLENE TEREPHTHALATES)
    • 生产聚(对苯二甲酸丁二酯)的方法
    • WO2017140453A1
    • 2017-08-24
    • PCT/EP2017/051045
    • 2017-01-19
    • SABIC GLOBAL TECHNOLOGIES B.V.
    • KUMAR, PrashantALIDEDEOGLU, Husnu, Alp
    • C08G63/183C08G63/78C08G63/80C08G63/85
    • C08G63/183C08G63/78C08G63/785
    • The present invention relates to a process for the production of poly(butylene terephthalate) comprising the steps of: (i) providing a poly(butylene terephthalate) oligomer having an intrinsic viscosity (IV) of 0.25 – 0.35 dl/g, a carboxylic end group (CEG) content of 25-35 mmol/kg, and a ratio of IV : CEG of ≤ 15 dl/mmol; (ii) introducing said poly(butylene terephthalate) oligomer to a low-pressure reactor; and (iii) performing a polycondensation reaction in said low-pressure reactor by subjecting the poly(butylene terephthalate) oligomer to a pressure of ≥ 0.05 and ≤ 5.0 mbar at a temperature of 235 to 255 °C, for such average residence time to obtain a poly(butylene terephthalate) having a ratio of IV : CEG of ≥ 18 dl/mmol, preferably ≥ 25 dl/mmol and having an IV of ≥ 0.45 dl/g; wherein steps (i), (ii) and (iii) are conducted in that order. Such process allows for the production of poly(butylene terephthalates) having a desired low CEG at given, desired high, IV using a poly(butylene terephthalate) oligomer having a relatively high CEG at given IV. Such process allows for the production of poly(butylene terephthalates) using poly(butylene terephthalate) oligomers obtained from an esterification process using PTA and 1,4-butanediol.
    • 本发明涉及生产聚(对苯二甲酸丁二醇酯)的方法,其包括以下步骤:(i)提供特性粘度(IV)为0.25-1.5的聚(对苯二甲酸丁二醇酯)低聚物, 0.35dl / g,羧基端基(CEG)含量为25-35mmol / kg,IV:CEG比率≤15dl/ mmol; (ii)将所述聚(对苯二甲酸丁二醇酯)低聚物引入低压反应器; 和(iii)通过使所述聚(对苯二甲酸丁二醇酯)低聚物在235至255℃的温度下经受≥0.05且≤5毫巴的压力而在所述低压反应器中进行缩聚反应, 获得IV:CEG≥18dl/ mmol,优选≥25dl/ mmol且IV≥0.45dl/ g的聚对苯二甲酸丁二醇酯; 其中步骤(i),(ii)和(iii)以该顺序进行。 这种方法允许使用在给定的IV下具有相对高的CEG的聚(对苯二甲酸丁二醇酯)低聚物来生产具有期望的低CEG的聚(对苯二甲酸丁二醇酯)。 该方法允许使用由PTA和1,4-丁二醇的酯化方法获得的聚(对苯二甲酸丁二醇酯)低聚物生产聚(对苯二甲酸丁二醇酯)。