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1. 发明申请

WO2017081638A1 VANADIUM PYRIDINE-IMINE COMPLEX, CATALYTIC SYSTEM COMPRISING SAID VANADIUM PYRIDINE-IMMINE COMPLEX AND A (CO) POLYMERIZATION PROCESS OF CONJUGATED DIENES 审中-公开
标题翻译：钒吡啶 - 亚胺络合物，包含所述钒吡啶 - 胺络合物和共轭二烯的（共）聚合方法的催化体系
公开(公告)号：WO2017081638A1
公开(公告)日：2017-05-18
申请号：PCT/IB2016/056775
申请日：2016-11-10
申请人： VERSALIS S.P.A.
发明人： RICCI, Giovanni , LEONE, Giuseppe , SOMMAZZI, Anna , MASI, Francesco
IPC分类号： B01J23/22 , C07F9/00 , C08F210/16 , C08F10/00
CPC分类号： C07F9/005 , B01J31/1815 , C08F136/06 , C08F136/08 , C08F4/68034
摘要： Vanadium pyridine-imine complex having general formula (I), wherein : - R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , equal to or different from each other, represent a hydrogen atom; or are selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - X 1 , X 2 and X 3 , equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 , -OCOR 7 groups or -OR 7 groups wherein R 7 is selected from linear or branched C 1 -C 20 alkyl groups, preferably C 1 -C 15 ; - Y is selected from ethers such as, for example, diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably is etrahydrofuran (THF); - n is 0 or 1. Said vanadium pyridine-imine complex having general formula (I) can be advantageously used in a catalytic system for the (co) polymerization of conjugated dienes.
摘要翻译：具有通式（I）的钒吡啶 - 亚胺配合物，其中：-R 1，R 2，R 3， R 4，R 5和R 6彼此相同或不同，表示氢原子; R 4，R 5和R 6彼此相同或不同。或选自直链或支链的C 1 -C 20烷基，优选C 1 -C 15的烷基，任选卤代的，任选取代的环烷基，任选取代的芳基; -X 1，X 2和X 3彼此相同或不同，代表卤素原子，例如氯，溴，碘，优选氯; 或选自直链或支链的C 1 -C 20烷基，优选C 1 -C 15的烷基， -OCOR 7基团或-OR 7基团，其中R 7选自直链或支链C 1 -C 3 - 20个烷基，优选C 1 -C 15烷基; -Y选自醚例如二乙醚，四氢呋喃（THF），二甲氧基乙烷，优选四氢呋喃（THF）; n为0或1.所述具有通式（I）的钒吡啶 - 亚胺配合物可有利地用于共轭二烯（共）聚合的催化体系中。

2. 发明申请

WO1996023010A2 'alpha'-OLEFINS AND OLEFIN POLYMERS AND PROCESSES THEREFOR 审中-公开
标题翻译： α-烯烃和烯烃聚合物及其制备方法
公开(公告)号：WO1996023010A2
公开(公告)日：1996-08-01
申请号：PCT/US1996001282
申请日：1996-01-24
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL
发明人： E.I. DU PONT DE NEMOURS AND COMPANY , UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL , JOHNSON, Lynda, Kaye , KILLIAN, Christopher, Moore , ARTHUR, Samuel, David , FELDMAN, Jerald , McCORD, Elizabeth, Forrester , McLAIN, Stephan, James , KREUTZER, Kristina, Ann , BENNETT, Margaret, Anne , COUGHLIN, Edward, Bryan , ITTEL, Steven, Dale , PARTHASARATHY, Anju , TEMPEL, Daniel, Joseph , BROOKHART, Maurice, S.
IPC分类号： C08F210/16
CPC分类号： C09J123/06 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , C09J123/20 , C08F4/7006 , C08F4/64013 , C08F4/80 , C08F4/76 , C08F4/68034 , C08F4/69034
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalysed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear alpha -olefins by the oligomerization of ethylene using as a catalyst system a combination of a nickel compound having a selected alpha -diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected DOLLAR (a)-diimine nickel complexes with ethylene.
摘要翻译：本文公开了聚合乙烯，无环烯烃和/或选择的环状烯烃以及任选选择的烯属酯或羧酸和其它单体的方法。聚合反应由选择的过渡金属化合物，有时是其他助催化剂催化。由于一些聚合表现出活性聚合的一些特征，因此可以容易地制备嵌段共聚物。所生产的许多聚合物通常是新颖的，特别是关于它们的微结构，这给出了其中一些不寻常的性质。公开了许多新颖的催化剂，以及一些制备它们的新方法。制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，该组合具有选择的α-二亚胺配体或选择的Lewis或布朗斯台德酸，或通过使选择的DOLLAR（a） - 二亚镍络合物与乙烯接触。

3. 发明申请

WO2017109767A1 PROCESS FOR THE PREPARATION OF (CO) POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A VANADIUM BIS-IMINE COMPLEX 审中-公开
标题翻译：在含有钒双亚胺配合物的催化体系存在下制备共轭二烯的（共）聚合物的方法
公开(公告)号：WO2017109767A1
公开(公告)日：2017-06-29
申请号：PCT/IB2016/057991
申请日：2016-12-23
申请人： VERSALIS S.P.A.
发明人： RICCI, Giovanni , LEONE, Giuseppe , SOMMAZZI, Anna , MASI, Francesco
IPC分类号： C08F136/06 , C08F136/08 , C08F36/06 , C08F36/08
CPC分类号： C08F136/06 , C08F136/08 , C08F4/68034
摘要： Process for the preparation of (co) polymers of conjugated dienes comprising polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one vanadium bis-imine complex having the general formula (I) : wherein : m is 0 or 1; Z represents a -CR 5 R 6 group wherein R 5 and R 6 , equal to or different from each other, represent a hydrogen atom; or a C 1 -C 20 alkyl group, preferably C 1 -C 15 , linear or branched; or a bivalent aromatic group optionally substituted; R 1 and R 2 equal to or different from each other, represent a hydrogen atom; or they are selected from C 1 -C 20 alkyl groups, preferably C 1 -C 15 , linear or branched, optionally halogenated, cycloalkyl groups optionally substituted; or R 1 and R 2 , may be optionally bound each other so as to form, together with the other atoms which they are bound to, a cycle containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted by C 1 -C 20 alkyl groups, preferably C 1 -C 15 , linear or branched, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; R 3 and R 4 , equal to or different from each other, represent a hydrogen atom; or they are selected from C 1 -C 20 alkyl groups, preferably C 1 -C 15 , linear or branched, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or R 2 and R 4 , may be optionally bound each other so as to form, together with the other atoms which they are bound to, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted by C 1 -C 20 alkyl groups, preferably C 1 -C 15 , linear or branched, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; or R 1 and R 3 , may be optionally bound each other so as to form, together with other atoms which they are bound to, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted by C 1 -C 20 alkyl groups, preferably C 1 -C 1 , linear or branched, said cycle optionally containing other heteroatoms such as oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; X 1 , X 2 and X 3 , equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or they are selected from C 1 -C 20 alkyl groups, preferably C 1 -C 15 , linear or branched, -OCOR 7 groups or -OR 7 groups wherein R 7 is selected from C 1 -C 20 alkyl groups, preferably C 1 -C 15 , linear or branched; Y is selected from ethers such as, for example, diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably is tetrahydrofuran (THF); n is 0 or 1.
摘要翻译：用于制备共轭二烯的（共）聚合物的方法包括在包含至少一种具有通式（I）的钒双亚胺配合物的催化体系存在下聚合至少一种共轭二烯，：其中：m是0或1; Z代表-CR 5 R 6基团，其中R 5和R 6等于或不同于每个基团其他，代表氢原子; 或C 1 -C 20烷基，优选C 1 -C 15直链或支链; 或任选取代的二价芳族基团; R 1和R 2彼此相同或不同，表示氢原子; 或它们选自C 1 -C 20烷基，优选C 1 -C 15烷基，直链或支链支链的，任选卤代的，任选取代的环烷基; 或者R 1和R 2可以任选地彼此结合以便与它们所结合的其它原子一起形成包含4至6 碳原子，饱和的，不饱和的或芳族的，任选被C 1 -C 20烷基取代，优选C 1 -C 12烷基，所述环任选含有杂原子，例如氧，硫，氮，硅，磷，硒; R 3和R 4彼此相同或不同，表示氢原子; 或它们选自C 1 -C 20烷基，优选C 1 -C 15烷基，直链或支链支链的，任选卤代的，任选取代的环烷基，任选取代的芳基; 或者R 2和R 4可以任选地彼此结合以便与它们所结合的其它原子一起形成含有3至6个碳原子，饱和的，不饱和的或芳族的，任选被C 1 -C 20烷基取代，优选C 1 -C 12烷基，所述环任选地含有其他杂原子，例如氧，硫，氮，硅，磷，硒; 或者R 1和R 3可以任选地彼此结合以便与它们所结合的其它原子一起形成含有3至6个碳的环原子，饱和的，不饱和的或芳族的，任选被C 1 -C 20烷基取代，优选C 1 -C 1 所述环任选地含有其他杂原子如氧，硫，氮，硅，磷，硒; X 1，X 2和X 3彼此相同或不同，表示卤原子，例如氯，溴，碘，优选氯; 或它们选自C 1 -C 20烷基，优选C 1 -C 15烷基，直链或支链支链，-OCOR7基团或-OR7基团，其中R7选自C1-C12烷基，优选C 1 -C 15烷基，直链或支链;优选C 1 -C 20烷基，优选C 1 -C 15烷基。 Y选自醚例如二乙醚，四氢呋喃（THF），二甲氧基乙烷，优选四氢呋喃（THF）; n是0或1。

4. 发明申请

WO2011088990A1 ETHYLENE POLYMERISATION 审中-公开
标题翻译：乙烯聚合
公开(公告)号：WO2011088990A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/000197
申请日：2011-01-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , ALT, Helmut , ELAGAB, Hamdi Ali , AL-HUMYDI, Abdulaziz Hamad
发明人： ALT, Helmut , ELAGAB, Hamdi Ali , AL-HUMYDI, Abdulaziz Hamad
IPC分类号： C08F10/00 , C08F4/64 , C08F4/649 , C08F10/02
CPC分类号： C08F10/00 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F110/02 , C08F4/64013 , C08F4/68034 , C08F4/68224 , C08F2500/04
摘要： The invention is directed to a process for the polymerization of ethylene in the presence of a catalyst comprising a Ti, Zr, Hf or V metal centre; and a ligand according to Formula (I), in which B = -CH 2 -, -CH 2 CH 2 -, -CH=CH-, 1,2-phenylene or 2,6-pyridyl, R 1, R 2 , R 3 ,R 4 may be independently of one other the same or different H, C 1 -C 4 alkyl radical, Br or Cl and X =NH, O or S; or a ligand containing a pyridine moiety or a N-allyl-2-benzimidazolyl ligand.
摘要翻译：本发明涉及在含有Ti，Zr，Hf或V金属中心的催化剂存在下聚合乙烯的方法; 和式（I）的配体，其中B = -CH 2 - ， - CH 2 CH 2 - ， - CH = CH-，1,2-亚苯基或2,6-吡啶基，R 1，R 2，R 3，R 4可以独立地另一个相同或不同的H，C 1 -C 4烷基，Br或Cl和X = NH，O或S; 或含有吡啶部分或N-烯丙基-2-苯并咪唑基配体的配体。

5. 发明申请

WO2005111099A1 ETHYLENE COPOLYMERS 审中-公开
标题翻译：乙烯共聚物
公开(公告)号：WO2005111099A1
公开(公告)日：2005-11-24
申请号：PCT/GB2005/001734
申请日：2005-05-06
申请人： INNOVENE EUROPE LIMITED , GIBSON, Vernon, Charles , TOMOV, Atanas, Kostadinov
发明人： GIBSON, Vernon, Charles , TOMOV, Atanas, Kostadinov
IPC分类号： C08F210/02
CPC分类号： C08F210/16 , C08F10/00 , C08F210/18 , C08F232/04 , C08F4/68 , C08F210/14 , C08F236/20 , C08F2500/25 , C08F2500/03 , C08F4/68034 , C08F4/68284 , C08F4/68215 , C08F4/69224 , C08F4/68224 , C08F4/69431 , C08F4/6925 , C08F4/69284 , C08F4/64089 , C08F4/69215 , C08F4/64148
摘要： Polymerisation of (a) ethylene, (b) an acyclic 1-olefin containing 3 to 20 carbon atoms and (c) a cyclic olefin containing at least one endocyclic double bond, to provide a copolymer comprising 99.8 to 80 weight % of (a) units, 0.1 to 10 weight % of (b) and 0.1 to 10 weight % of (c), using as catalyst (1) transition metal compound Formula (A), and optionally (2) an activator, Z is a 5-membered heterocyclic containing at least C, at least one N and at least one of N, S or O. M is a metal from Group 3 to 11 or lanthanide. E 1 and E 2 are divalent hydrocarbon groups. D 1 and D 2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integers such that the number of X and L groups satisfy the valency and oxidation state of the metal M. The process provides good incorporation of the cyclic comonomer.
摘要翻译：（a）乙烯，（b）含有3-20个碳原子的非环状1-烯烃和（c）含有至少一个内环双键的环烯烃的聚合反应，得到包含99.8-80重量％（a）单元，0.1〜10重量％的（b）和0.1〜10重量％的（c），使用催化剂（1）过渡金属化合物式（A）和任选的（2）活化剂，Z是5元含有至少C，至少一个N和N，S或O中的至少一个的杂环.M是第3至11族或镧系元素的金属。 E 1和E 2是二价烃基。 D 1和D 2是供体原子或基团; X是阴离子基团，L是中性给体基团; n = m =零或1; y和z为零或整数，使得X和L基团的数量满足金属M的化合价和氧化态。该方法提供了环状共聚单体的良好掺入。

6. 发明申请

WO9623010A3 ALPHA -OLEFINS AND OLEFIN POLYMERS AND PROCESSES TALPHA -OLEFINS AND OLEFIN POLYMERS AND PROCESSES THEREFOR HEREFOR 审中-公开
标题翻译： ALPHA-OLEFINS和OLEFIN聚合物和方法TALPHA-OLEFINS和OLEFIN聚合物及其制备方法
公开(公告)号：WO9623010A3
公开(公告)日：1996-12-05
申请号：PCT/US9601282
申请日：1996-01-24
申请人： DU PONT , UNIV NORTH CAROLINA
发明人： JOHNSON LYNDA KAYE , KILLIAN CHRISTOPHER MOORE , ARTHUR SAMUEL DAVID , FELDMAN JERALD , MCCORD ELIZABETH FORRESTER , MCLAIN STEPHAN JAMES , KREUTZER KRISTINA ANN , BENNETT MARGARET ANNE , COUGHLIN EDWARD BRYAN , ITTEL STEVEN DALE , PARTHASARATHY ANJU , TEMPEL DANIEL JOSEPH , BROOKHART MAURICE S
IPC分类号： C07C251/08 , C07C251/00 , C07F5/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C08F20060101 , C08F4/04 , C08F4/42 , C08F4/52 , C08F4/60 , C08F4/622 , C08F4/639 , C08F4/70 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F232/00 , C08F232/04 , C08G61/04 , C08J5/18 , C08L23/02 , C08L23/16 , C09D123/00 , C09J123/00 , C09J123/02 , C10M107/02 , C10M119/00 , C10M143/04
CPC分类号： C09J123/06 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , C09J123/20 , C08F4/7006 , C08F4/64013 , C08F4/80 , C08F4/76 , C08F4/68034 , C08F4/69034
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalysed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear alpha -olefins by the oligomerization of ethylene using as a catalyst system a combination of a nickel compound having a selected alpha -diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected DOLLAR (a)-diimine nickel complexes with ethylene.
摘要翻译：本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。聚合反应由选择的过渡金属化合物，有时是其他助催化剂催化。由于一些聚合表现出活性聚合的一些特征，因此可以容易地制备嵌段共聚物。所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。公开了许多新颖的催化剂，以及一些制备它们的新方法。制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚合成线性α-烯烃，该组合具有选择的α-二亚胺配体或选择的Lewis或Bronsted酸，或通过使选择的DOLLAR（a） - 二亚镍络合物与乙烯接触。

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