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1. 发明申请

WO2011088990A1 ETHYLENE POLYMERISATION 审中-公开
标题翻译：乙烯聚合
公开(公告)号：WO2011088990A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/000197
申请日：2011-01-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , ALT, Helmut , ELAGAB, Hamdi Ali , AL-HUMYDI, Abdulaziz Hamad
发明人： ALT, Helmut , ELAGAB, Hamdi Ali , AL-HUMYDI, Abdulaziz Hamad
IPC分类号： C08F10/00 , C08F4/64 , C08F4/649 , C08F10/02
CPC分类号： C08F10/00 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F110/02 , C08F4/64013 , C08F4/68034 , C08F4/68224 , C08F2500/04
摘要： The invention is directed to a process for the polymerization of ethylene in the presence of a catalyst comprising a Ti, Zr, Hf or V metal centre; and a ligand according to Formula (I), in which B = -CH 2 -, -CH 2 CH 2 -, -CH=CH-, 1,2-phenylene or 2,6-pyridyl, R 1, R 2 , R 3 ,R 4 may be independently of one other the same or different H, C 1 -C 4 alkyl radical, Br or Cl and X =NH, O or S; or a ligand containing a pyridine moiety or a N-allyl-2-benzimidazolyl ligand.
摘要翻译：本发明涉及在含有Ti，Zr，Hf或V金属中心的催化剂存在下聚合乙烯的方法; 和式（I）的配体，其中B = -CH 2 - ， - CH 2 CH 2 - ， - CH = CH-，1,2-亚苯基或2,6-吡啶基，R 1，R 2，R 3，R 4可以独立地另一个相同或不同的H，C 1 -C 4烷基，Br或Cl和X = NH，O或S; 或含有吡啶部分或N-烯丙基-2-苯并咪唑基配体的配体。

2. 发明申请

WO2013091837A1 PROCESS FOR THE PREPARATION OF METALLOCENE COMPLEXES 审中-公开
标题翻译：制备金属络合物的方法
公开(公告)号：WO2013091837A1
公开(公告)日：2013-06-27
申请号：PCT/EP2012/005232
申请日：2012-12-13
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , AL-HUMYDI, Abdulaziz Hamad , ABURAQABAH, Atieh , GÖRL, Christian , ALT, Helmut
发明人： AL-HUMYDI, Abdulaziz Hamad , ABURAQABAH, Atieh , GÖRL, Christian , ALT, Helmut
IPC分类号： C07F17/00 , C07C1/32 , C08F10/00
CPC分类号： C07F7/00 , C07C1/321 , C07C2102/08 , C07C2602/08 , C07F17/00 , C08F4/65912 , C08F110/02 , C07C13/465 , C08F4/65927
摘要： The invention relates to a process comprising the step of reacting a 2-indenylpinacolyl borane compound with a bromosubstituted compound in the presence of a Pd catalyst and a base to form the corresponding bridged bis(indenyl) ligand. This process step is very efficient and leads to less (homocoupled) byproducts than other known processes. The process of the invention may further comprise the step of reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base, to form the corresponding 2-indenylpinacolylborane compound. With this, the invention provides an improved and easy two-step process to prepared bridged bis(indenyl)ligands. These bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2'-bis(2-indenyl)biphenyl ZrCI 2 and 1,2-bis(2-indenyl)benzene ZrCI 2 . These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more a-olefins, preferably for the polymerization of ethylene. In a preferred embodiment, the Pd catalyst is preferably is(triphenylphosphin)palladium dichloride (PPh 3 ) 2 PdCI 2 ).
摘要翻译：本发明涉及包括在Pd催化剂和碱的存在下使2-茚基茚基甲硼烷化合物与溴取代的化合物反应以形成相应的桥连双（茚基）配体的步骤的方法。该工艺步骤非常有效，并且导致比其他已知方法更少的（同相偶联的）副产物。本发明的方法还可以包括在Pd催化剂和碱的存在下使2-溴茚化合物与频哪醇硼烷反应的步骤，以形成相应的2-茚基茚基苯基硼烷化合物。由此，本发明提供了制备桥连双（茚基）配体的改进和简便的两步法。这些桥连的双（茚基）配体可以适用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯基ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。这些茂金属配合物可以用于聚合，任选地在助催化剂存在下的一种或多种α-烯烃，优选用于乙烯的聚合。在优选的实施方案中，Pd催化剂优选为（三苯基膦）二氯化钯（PPh 3）2 PdCl 2）。

3. 发明申请

WO2013091836A1 PROCESS FOR THE PREPARATION OF METALLOCENE COMPLEXES 审中-公开
标题翻译：制备金属络合物的方法
公开(公告)号：WO2013091836A1
公开(公告)日：2013-06-27
申请号：PCT/EP2012/005231
申请日：2012-12-13
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , AL-HUMYDI, Abdulaziz Hamad , ABURAQABAH, Atieh , GÖRL, Christian , ALT, Helmut
发明人： AL-HUMYDI, Abdulaziz Hamad , ABURAQABAH, Atieh , GÖRL, Christian , ALT, Helmut
IPC分类号： C07F17/00 , C08F10/00
CPC分类号： C08F4/76 , C07C1/321 , C07C2/66 , C07C13/32 , C07C13/36 , C07C13/38 , C07F17/00 , C08F4/65927 , C08F110/02 , C08F4/65912
摘要： The invention relates to a process comprising the step of (a) reacting a 2- indenylboranic acid (ester) with a bromosubstituted compound in the presence of the Pd catalyst bis(triphenylphosphin)palladium dichloride (PPh 3 ) 2 PdCI 2 ) and a base to form the corresponding bridged bis(indenyl) ligand. In case the 2-indenylboranic acid (ester) is the pinacolester of 2-indenylboranic acid, the process of the invention may further comprise the step of reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base, to form the corresponding 2- indenylpinacolylborane compound. With this, the invention provides an improved and easy two-step process to prepared bridged bis(indenyl)ligands, which is commercially very attractive when the Pd catalyst bis(triphenylphosphin)palladium dichloride (PPh 3 ) 2 PdCI 2 ) is used. Bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2'-bis(2-indenyl)biphenyl ZrCI 2 and 1,2-bis(2-indenyl)benzene ZrCI 2 . These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more a-olefins, preferably for the polymerization of ethylene.
摘要翻译：本发明涉及包括以下步骤的方法：（a）在Pd催化剂双（三苯基膦）二氯化钯（PPh 3）2 PdCl 2）和碱的存在下使2-茚基硼酸（酯）与溴取代的化合物反应，形成对应的桥连双（茚基）配体。在2-茚基硼烷酸（酯）是2-茚基硼烷酸的频哪醇酯的情况下，本发明的方法还可以包括在Pd催化剂和碱的存在下使2-溴茚化合物与频哪醇硼烷反应的步骤，以形成相应的2-茚基茚基苯甲酰基硼烷化合物。因此，本发明提供了一种改进和简便的制备桥联双（茚基）配体的两步法，当使用Pd催化剂双（三苯基膦）二氯化钯（PPh 3）2 PdCl 2）时，这种配体在商业上非常有吸引力。桥连双（茚基）配体可适当地用于制备茂金属络合物，例如2,2'-双（2-茚基）联苯ZrCl 2和1,2-双（2-茚基）苯ZrCl 2。这些茂金属配合物可以用于聚合，任选地在助催化剂存在下的一种或多种α-烯烃，优选用于乙烯的聚合。

4. 发明申请

WO2013064235A1 MULTINUCLEAR METALLOCENE CATALYST COMPOUND FOR OLEFIN POLYMERISATION AND COPOLYMERISATION AND METHOD FOR MAKING THEREOF 审中-公开
标题翻译：用于烯烃聚合和共聚的金属茂金属催化剂化合物及其制备方法
公开(公告)号：WO2013064235A1
公开(公告)日：2013-05-10
申请号：PCT/EP2012/004516
申请日：2012-10-29
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , SABIC PETROCHEMICALS B.V.
发明人： AL-SHAMMARI, Haif , ALT, Helmut
IPC分类号： B01J31/18 , C07F17/00 , C08F4/76 , C08F10/02
CPC分类号： C08F110/02 , B01J31/1815 , B01J31/2295 , B01J2531/0205 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/847 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/65904 , C08F4/64013 , C08F4/7006 , C08F2500/04
摘要： The invention relates to a multinuclear metallocene catalyst compound according to Formula (1), wherein Y and Y' are the same or different and independently selected from the group consisting of C 1-20 linear, branched or cyclic hydrocarbyl groups, C 1-30 aryl and substituted aryl groups; L and L' are the same or different and are electron-donating groups independently selected from the elements of Group 15 of the Periodic Table; Q and Q' are the same or different and independently selected from the group consisting of C 1-30 alkylene groups; M" is a metal selected from Groups 3, 4, 5, 6, 7, 8, 9 and 10 or from lanthanide series elements of the Periodic Table; Z is selected from the group consisting of hydrogen, a halogen and C 1-20 hydrocarbyl, C 1-20 alkoxy and C 1-20 aryloxy groups; z is an integer from 1 to 4; n and n' are independently 0 or 1, with 1≤(n+n')≤2; B and B' are the same or different and each is a metallocene compound, with B being represented by the compound of Formula (2) and B' being represented by the compound of Formula (3), wherein Si is silicon; R and R' are the same or different and independently a hydrogen or a C 1-20 alkyl or aryl group; D, D', E and E' are independently ligand compounds having a cyclopentadienyl skeleton selected from cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl and substituted fluorenyl; M and M' are the same or different and each is independently selected from the group consisting of scandium, yttrium, lanthanoid series elements, titanium, zirconium, hafnium, vanadium, niobium, and tantalum; X and X' are the same or different and each is selected from the group consisting of hydrogen, a halogen, a C 1-20 hydrocarbyl group, C 1-20 alkoxy group; and C 1-20 aryloxy group; x and x' are independently integers from 1 to 3. This invention also relates to a catalyst system comprising said multinuclear metallocene catalyst compound and a co-catalyst, to a method of making the multinuclear metallocene catalyst compound and to a process for the polymerisation and copolymerisation of an olefin in the presence of said catalyst system. The invention relates to a multinuclear metallocene catalyst compound according to Formula 1, wherein: Y and Y' are the same or different and independently selected from the group consisting of C 1-20 linear, branched or cyclic hydrocarbyl groups, C 1-30 aryl and substituted aryl groups; L and U are the same or different and are electron-donating groups independently selected from the elements of Group 15 of the Periodic Table; Q and Q' are the same or different and independently selected from the group consisting of Ci-3o alkylene groups; M" is a metal selected from Groups 3, 4, 5, 6, 7, 8, 9 and 10 or from lanthanide series elements of the Periodic Table; Z is selected from the group consisting of hydrogen, a halogen and C 1-20 hydrocarbyl, C 1-20 alkoxy and C 1-20 aryloxy groups; z is an integer from 1 to 4; n and n' are independently 0 or 1, with 1
摘要翻译：本发明涉及式（1）的多核金属茂催化剂化合物，其中Y和Y'相同或不同并且独立地选自C1-20直链，支链或环状烃基，C1-30芳基和取代的芳基; L和L'相同或不同，是独立地选自元素周期表第15族的元素的给电子基团; Q和Q'相同或不同，独立地选自C1-30亚烷基; M“是选自第3,4,5,6,7,8,9和10族的金属或周期表的镧系元素; Z选自氢，卤素和C 1-20烃基，C 1-20烷氧基和C 1-20芳氧基; z是1至4的整数; n和n'独立地为0或1，其中1≤（n + n'）= 2; B和B' 相同或不同，各自为茂金属化合物，其中B由式（2）的化合物表示，B'由式（3）的化合物表示，其中Si是硅; R和R'相同或不同且独立地是氢或C 1-20烷基或芳基; D，D'，E和E'独立地是具有选自环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基和取代的芴基的环戊二烯基骨架的配体化合物; M 和M'相同或不同，并且各自独立地选自钪，钇，镧系元素，钛，锆，铪，钒，铌和钽; X和X'相同或不同，各自选自氢，卤素，C 1-20烃基，C 1-20烷氧基; 和C 1-20芳氧基; x和x'独立地为1至3的整数。本发明还涉及包含所述多核金属茂催化剂化合物和助催化剂的催化剂体系，制备多核金属茂催化剂化合物的方法和聚合方法在所述催化剂体系的存在下烯烃的共聚合。本发明涉及式1的多核金属茂催化剂化合物，其中：Y和Y'相同或不同，独立地选自C 1-20直链，支链或环状烃基，C 1-3芳基和被取代的芳基; L和U相同或不同，是独立地选自元素周期表第15族的元素的给电子基团; Q和Q'相同或不同，并且独立地选自C 1-10亚烷基; M“是选自第3,4,5,6,7,8,9和10族的金属或周期表的镧系元素; Z选自氢，卤素和C 1-20烃基，C 1-20烷氧基和C 1-20芳氧基; z是1至4的整数; n和n'独立地为0或1，其中1 <（n + n'）<2; B和B'相同本发明还涉及一种包含所述多核金属茂催化剂化合物和助催化剂的催化剂体系，涉及一种制备多核金属茂催化剂化合物的方法和一种用于聚合和共聚合的方法烯烃在所述催化剂体系的存在下进行。

5. 发明申请

WO2012110227A1 MULTINUCLEAR METALLOCENE CATALYST COMPLEXES FOR OLEFIN POLYMERISATION AND COPOLYMERISATION AND METHOD OF PREPARING THEREOF 审中-公开
标题翻译：用于烯烃聚合和共聚合的金属茂金属催化剂复合物及其制备方法
公开(公告)号：WO2012110227A1
公开(公告)日：2012-08-23
申请号：PCT/EP2012/000639
申请日：2012-02-14
申请人： SAUDI BASIC INDUSTRIES CORPORATION , AL-SHAMMARI, Haif , ALT, Helmut
发明人： AL-SHAMMARI, Haif , ALT, Helmut
IPC分类号： C08F110/02 , C08F4/6592
CPC分类号： C07F17/00 , B01J31/143 , B01J31/1805 , B01J31/2295 , B01J2531/0205 , B01J2531/35 , B01J2531/36 , B01J2531/37 , B01J2531/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , B01J2531/57 , B01J2531/58 , C08F4/62013 , C08F4/6423 , C08F4/65912 , C08F4/6592 , C08F110/02 , C08F2410/03 , C08F4/64013 , C08F2500/04
摘要： The invention relates to a multinuclear metallocene catalyst of general formula (1); wherein Y and Y' are the same or different and independently selected from a C 1-20 linear hydrocarbyl group; C 1-20 branched hydrocarbyl group; C 1-20 cyclic hydrocarbyl group; a C 1-30 aryl group and a C 1-30 substituted aryl group; L and L' are the same or different and each is an electron-donating group independently selected from the elements of Group 15 of the Periodic Table; Q and Q' are the same or different and independently selected from hydrogen, a C 1-30 alkyl group and a C 1-30 aryl group; M" is a metal selected from Group 3, 4, 5, 6, 7, 8, 9 and 10 elements and from lanthanide series elements of the Periodic Table; Z is selected from the group consisting of hydrogen; a halogen element; a C 1-20 hydrocarbyl group; C 1-20 alkoxy group and a C 1-20 aryloxy group; B and B' are the same or different and each is a half sandwich metallocene compound, with B being represented by Formula 2 and B' being represented by Formula 3: W-M-X x (Formula 2), W'-M'-X' x' (Formula 3) wherein: W and W' are the same or different and independently a ligand compound having a cyclopentadienyl skeleton selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl and substituted fluorenyl; M and M' are the same and each is independently selected from the group consisting of scandium; yttrium; lanthanoid series elements; titanium; zirconium; hafnium; vanadium; niobium; and tantalum; X and X' are the same or different and each is selected from the group consisting of hydrogen; a halogen element; a C 1-20 hydrocarbyl group, C 1-20 alkoxy group; and C 1-20 aryloxy group; x and x' are independently integers from 0 to 3; z is an integer from 1 to 5; n, n' are independently 0 or 1, with 1 (n+n') 2. The invention further relates to a method to prepare said multinuclear metallocene catalyst compound. The invention further relates to a catalyst system and to a process for the polymerisation of olefins.
摘要翻译：本发明涉及通式（1）的多核金属茂催化剂; 其中Y和Y'相同或不同并且独立地选自C 1-20直链烃基; C 1-20支链烃基; C 1-20环烃基; C1-30芳基和C1-30取代的芳基; L和L'相同或不同，各自为独立地选自周期表第15族的元素的给电子基团; Q和Q'相同或不同，独立地选自氢，C1-30烷基和C1-30芳基; M“是选自组3,4,5,6,7,8,9和10元素的金属，以及选自元素周期表的镧系元素; Z选自氢，卤素元素，C1 -20烃基; C 1-20烷氧基和C 1-20芳氧基; B和B'相同或不同，分别为半夹心茂金属化合物，B由式2表示，B'由式 3：WM-Xx（式2），W'-M'-X'x'（式3）其中：W和W'相同或不同，独立地是具有选自以下的环戊二烯基骨架的配体化合物：环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基和取代的芴基; M和M'相同，各自独立地选自钪;钇;镧系元素;钛;锆;铪;钒;铌; 和钽; X和X'相同或不同，并且各自选择f 由氢组成的组; 卤素元素 C 1-20烃基，C 1-20烷氧基; 和C 1-20芳氧基; x和x'独立地为0至3的整数; z为1〜5的整数; n，n'独立地为0或1，与1（n + n'）2。本发明还涉及一种制备所述多核金属茂催化剂化合物的方法。本发明还涉及催化剂体系和烯烃聚合方法。

6. 发明申请

WO2011003044A1 SELECTIVE OLEFIN DIMERIZATION WITH SUPPORTED METAL COMPLEXES ACTIVATED BY ALKYLALUMINUM COMPOUNDS OR IONIC LIQUIDS 审中-公开
标题翻译：具有支持的金属络合物的选择性烯化二烯化合物由ALKYLALUMINUM化合物或离子液体
公开(公告)号：WO2011003044A1
公开(公告)日：2011-01-06
申请号：PCT/US2010/040848
申请日：2010-07-01
申请人： CONOCOPHILLIPS COMPANY - IP SERVICES GROUP , DOTTERL, Matthias , SCHMIDT, Roland , ENGLMANN, Tanja , DENNER, Christine , ALT, Helmut
发明人： DOTTERL, Matthias , SCHMIDT, Roland , ENGLMANN, Tanja , DENNER, Christine , ALT, Helmut
IPC分类号： C07C2/08
CPC分类号： C07C2/34 , B01J21/08 , B01J31/0231 , B01J31/0272 , B01J31/0275 , B01J31/0295 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/842 , C07C2/32 , C07C2521/08 , C07C2531/14 , C07C2531/22
摘要： Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein the catalytic component is of the form where X is a halogen, n = 2 or 3, M = Ti, V, Cr, Mn, Fe, Co and Ni and R1, R2, R3 and R4 are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkinyl, alkyloxy, substituted aryl, and X are provided. A method for dimerizing alpha-olefins utilizing the immobilized buffered catalysts and a co-catalyst is also provided.
摘要翻译：使用固定化缓冲催化剂二聚α-烯烃的方法，其中催化组分为其中X为卤素，n = 2或3，M = Ti，V，Cr，Mn，Fe，Co和Ni以及R1，R2， R3和R4选自氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和X。还提供了利用固定化缓冲催化剂和助催化剂二聚α-烯烃的方法。

7. 发明申请

WO2011003046A1 ORGANOMETALLIC COMPLEXES AS CATALYST PRECURSORS FOR SELECTIVE OLEFIN DIMERIZATION AND PROCESSES THEREFOR 审中-公开
标题翻译：有机金属络合物作为催化剂前体，用于选择性烯烃二元化及其工艺
公开(公告)号：WO2011003046A1
公开(公告)日：2011-01-06
申请号：PCT/US2010/040850
申请日：2010-07-01
申请人： CONOCOPHILLIPS COMPANY - IP SERVICES GROUP , ALT, Helmut , DENNER, Christine , DOTTERL, Matthias , ENGLMANN, Tanja , SCHMIDT, Roland
发明人： ALT, Helmut , DENNER, Christine , DOTTERL, Matthias , ENGLMANN, Tanja , SCHMIDT, Roland
IPC分类号： C07C2/02
CPC分类号： C07C2/32 , B01J21/08 , B01J31/0284 , B01J31/0288 , B01J31/0289 , B01J31/143 , B01J31/2217 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/847 , C07C2531/14 , C07C2531/22
摘要： Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts, wherein the catalytic component is of the formula (I) where M is selected from the group of Ti, Zr, Hg, Ni, and V and R and R' are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkinyl, alkyloxy, substituted aryl, and halogens, are provided.
摘要翻译：使用固定化缓冲催化剂二聚α-烯烃的方法，其中催化组分为式（I），其中M选自Ti，Zr，Hg，Ni和V组，R和R'选自由氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和卤素组成。

8. 发明申请

WO2008119431A1 CATALYST COMPLEX AND PROCESS FOR PRODUCING MULTIMODAL MOLECULAR WEIGHT POLYOLEFINS 审中-公开
标题翻译：催化复合物和生产多组分重量聚烯烃的方法
公开(公告)号：WO2008119431A1
公开(公告)日：2008-10-09
申请号：PCT/EP2008/001769
申请日：2008-03-05
申请人： SAUDI BASIC INDUSTRIES CORPORATION , PALACKAL, Syriac , ABURAQABAH, Atieh , ALT, Helmut , GOERL, Christian
发明人： PALACKAL, Syriac , ABURAQABAH, Atieh , ALT, Helmut , GOERL, Christian
IPC分类号： B01J31/18 , B01J31/22 , C08F4/659 , C08F10/00 , C07F17/00
CPC分类号： B01J31/1805 , B01J31/143 , B01J31/146 , B01J31/2243 , B01J31/2295 , B01J2231/122 , B01J2231/20 , B01J2531/0205 , B01J2531/0286 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F4/65927 , C08F2500/05 , C08F2500/04 , C08F4/64048
摘要： Multinuclear catalyst complex comprising two or more active metal centres and at least one phenoxyimine compound and at least one substituted cyclopentadienyl, indenyl or fluorenyl derivative, each phenoxyimine compound being bonded to a cyclopentadienyl, indenyl or fluorenyl derivative forming a ligand framework, the cyclopentadienyl, indenyl or fluorenyl derivative being coordinated with one of the metal centres and the phenoxyimine compound being coordinated with an active metal centre other than the metal centre the cyclopentadienyl, indenyl or fluorenyl derivative is coordinated with, and wherein the phenoxyimine compound has the formula (I) wherein R 1 is hydrogen, alkyl, cycloalkyl, aryl or aralkyl; R 2 is hydrogen, halogen, alkyl, cycloalkyl, aryl, O-alkyl or aralkyl; and R 3 is alkyl, cycloalkyl, aryl or aralkyl, process for preparing a multinuclear catalyst composition comprising the steps of bonding a substituted phenoxyimine compound to a substituted cyclopentadienyl, indenyl or fluorenyl derivative to obtain a ligand framework and reacting at least one ligand framework with an active metal component and process for the polymerization of olefins, in particular of ethylene and optionally one or more other a-olefins, wherein said multinuclear catalyst is applied.
摘要翻译：包含两个或更多个活性金属中心和至少一个苯亚胺亚胺化合物和至少一个取代的环戊二烯基，茚基或芴基衍生物的多核催化剂络合物，每个苯亚胺亚胺化合物与形成配体骨架的环戊二烯基，茚基或芴基衍生物结合，环戊二烯基，茚基或芴基衍生物与金属中心之一配位，苯氧亚胺化合物与除金属中心以外的活性金属中心配位，环戊二烯基，茚基或芴基衍生物配位，其中苯氧亚胺化合物具有式（I），其中式 R 1是氢，烷基，环烷基，芳基或芳烷基; R 2是氢，卤素，烷基，环烷基，芳基，O-烷基或芳烷基; R 3是烷基，环烷基，芳基或芳烷基，用于制备多核催化剂组合物的方法包括以下步骤：将取代的苯氧亚胺化合物与取代的环戊二烯基，茚基或芴基衍生物键合以获得配体框架，使至少一种配体骨架与活性金属组分反应，以及用于烯烃聚合的方法，特别是乙烯和任选的一种或多种其它α-烯烃的聚合方法，其中应用所述多核催化剂。

9. 发明申请

WO2011005868A1 HOMOGENEOUS DIMERIZATION CATALYSTS BASED ON VANADIUM 审中-公开
标题翻译：基于VANADIUM的均相二元催化剂
公开(公告)号：WO2011005868A1
公开(公告)日：2011-01-13
申请号：PCT/US2010/041223
申请日：2010-07-07
申请人： CONOCOPHILLIPS COMPANY - IP SERVICES GROUP , LANG, Julian, R., V. , ALT, Helmut , SCHMIDT, Roland
发明人： LANG, Julian, R., V. , ALT, Helmut , SCHMIDT, Roland
IPC分类号： C08F4/26 , C07D213/50 , C07F15/02
CPC分类号： C07F9/005 , C08F10/00
摘要： A series of new bis(imino)pyridine vanadium(III) complexes was synthesized according to formula. They were tested for the homogeneous catalytic dimerization of propylene after activation with MAO and showed excellent selectivity for dimerization. The catalysts can be used with or without PPh 3 as an additive to produce ≥ 80% dimerized alkenes.
摘要翻译：根据公式合成了一系列新的双（亚氨基）吡啶钒（III）络合物。在用MAO活化后测试丙烯的均相催化二聚化并显示出优异的二聚选择性。催化剂可以使用或不使用PPh 3作为添加剂来生产= 80％的二聚烯烃。

10. 发明申请

WO2011003047A1 HETEROGENEOUS DIMERIZATION OF ALPHA-OLEFINS WITH ACTIVATED METALLOCENE COMPLEXES 审中-公开
标题翻译：具有活性金属茂复合物的ALPHA-烯烃的异构二维
公开(公告)号：WO2011003047A1
公开(公告)日：2011-01-06
申请号：PCT/US2010/040851
申请日：2010-07-01
申请人： CONOCOPHILLIPS COMPANY - IP SERVICES GROUP , ENGLMANN, Tanja , DENNER, Christine , ALT, Helmut , SCHMIDT, Roland
发明人： ENGLMANN, Tanja , DENNER, Christine , ALT, Helmut , SCHMIDT, Roland
IPC分类号： B01J31/00 , C08F4/42
CPC分类号： C07C2/34 , B01J21/08 , B01J21/12 , B01J31/2295 , B01J37/0209 , B01J2231/20 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C2521/08 , C07C2527/126 , C07C2531/14 , C07C2531/22 , C07C11/02
摘要： Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein the catalytic component is of the form (ligand) 2 -M-X 2 where X is a halogen, M is selected from the group of Ti, Zr, and Hf and ligand is selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, and substituted indenyl, wherein the two ligands may be the same or different compound are provided.
摘要翻译：使用固定化缓冲催化剂二聚α-烯烃的方法，其中催化组分为（配体）2-M-X2形式，其中X为卤素，M选自Ti，Zr和Hf族，配体选自由环戊二烯基，取代的环戊二烯基，茚基和取代的茚基组成的组，其中两个配体可以是相同或不同的化合物。

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