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    • 6. 发明申请
    • ASYMMETRIC MONOMETALLIC NANOROD NANOPARTICLE DIMER AND RELATED COMPOSITIONS AND METHODS
    • 不对称单核纳米粒子纳米粒子二聚体及相关成分及方法
    • WO2016046645A1
    • 2016-03-31
    • PCT/IB2015/002077
    • 2015-09-25
    • KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY
    • HAN, YuHUANG, JianfengZHU, Yihan
    • C30B7/14B82Y30/00B82Y40/00C30B29/02C30B29/60G01N21/65
    • C30B7/14B82Y30/00B82Y40/00C03B29/02C30B29/02C30B29/60G01N21/658
    • The fabrication of asymmetric monometallic nanocrystals with novel properties for plasmonics, nanophotonics and nanoelectronics. Asymmetric monometallic plasmonic nanocrystals are of both fundamental synthetic challenge and practical significance. In an example, a thiol-ligand mediated growth strategy that enables the synthesis of unprecedented Au Nanorod-Au Nanoparticle (AuNR-AuNP) dimers from pre-synthesized AuNR seeds. Using high-resolution electron microscopy and tomography, crystal structure and three-dimensional morphology of the dimer, as well as the growth pathway of the AuNP on the AuNR seed, was investigated for this example. The dimer exhibits an extraordinary broadband optical extinction spectrum spanning the UV, visible, and near infrared regions (300 - 1300 nm). This unexpected property makes the AuNR-AuNP dimer example useful for many nanophotonic applications. In two experiments, the dimer example was tested as a surface- enhanced Raman scattering (SERS) substrate and a solar light harvester for photothermal conversion, in comparison with the mixture of AuNR and AuNP. In the SERS experiment, the dimer example showed an enhancement factor about 10 times higher than that of the mixture, when the excitation wavelength (660 nm) was off the two surface plasmon resonance (SPR) bands of the mixture. In the photothermal conversion experiment under simulated sunlight illumination, the dimer example exhibited an energy conversion efficiency about 1.4 times as high as that of the mixture.
    • 制备具有等离子体激元,纳米光子学和纳米电子学新特性的不对称单金属纳米晶体。 不对称单金属等离子体纳米晶体是基本的综合挑战和实践意义。 在一个实例中,硫醇 - 配体介导的生长策略使得能够从预合成的AuNR种子合成前所未有的Au Nanorod-Au纳米粒子(AuNR-AuNP)二聚体。 在这个例子中,使用高分辨率电子显微镜和断层扫描,研究了二者的晶体结构和三维形貌,以及AuNP在AuNR种子上的生长途径。 二聚体表现出跨越UV,可见光和近红外区域(300 - 1300 nm)的非凡宽带光学消光光谱。 这种意想不到的性质使得AuNR-AuNP二聚体实例对于许多纳米光子应用是有用的。 在两个实验中,与AuNR和AuNP的混合物相比,将二聚体实例作为表面增强拉曼散射(SERS)衬底和用于光热转换的太阳光收集器进行了测试。 在SERS实验中,当激发波长(660nm)离开混合物的两个表面等离子体共振(SPR)条带时,二聚体实例显示比混合物高约10倍的增强因子。 在模拟阳光照射下的光热转化实验中,二聚体实例显示出能量转换效率约为混合物的1.4倍。